H~+对Cu~(2+)—Me~(2+)二元体系吸附的影响规律研究

土壤对重金属离子的吸附容量严格受H~+浓度的控制。本文通过试验探讨了H~+ 对Cu~(2+)——Pb~(2+),Cn~(2+)——Zu~(2+),Cu~(2+)——Hg~(2+)系统中Cu~(2+)吸附量的影响规律。当pHpH时,Cu~(2+)吸附量随pH值增大而减小。对于酸性土,pH=6.5(初始值)或7.0(平衡值),对碱性土,pH=5.5(初始值)或7.8(平衡值)。在pHpH_(ZPC)时,吸附模式具有完全不同的形式。     

AbnormalSq behaviour

It is well-known that the amplitude and phase of theSq(H) variation show considerable variability from day to day. In this paper we consider one aspect of the phase variability—that associated with AQDs. AQDs (or abnormal quiet days) are defined as magnetically quiet days where the maximum excursion ofH at a mid-latitude station on the poleward side of the focus occurs outside the normal time range 0830–1330 LST. Such days exhibit properties, many of which appear quite distinct from the properties of the normalSq(H) variation. The properties of AQDs, and the proposals that have been made to explain them, are considered in detail. The consequences of these proposals and some problems which need to be addressed in order to obtain a fuller understanding of the dynamics of the ionosphere on AQDs are also discussed.     

Charge distribution on the atmospheric aerosol over the North Atlantic and the Indian Ocean

The distribution of electric charge on the marine aerosol was determined near the sea surface of the Indian Ocean and the North Atlantic during the final stage of the Snellius II-expedition. Mean values for small ion concentrationsn ⁺=455 cm^–3 andn ^–=340 cm^–3 were found over the Atlantic, whilen ⁺=310 andn ^–=250 cm^–3 were the mean values over the Indian Ocean. The ration ⁺/n^– increased from 1.2 to 2.0 with decreasing wind velocity. At wind velocities below 5 m/s 75% of the net space charge near the ocean surface was found to be carried by small ions.     

配位滴定法同时测定金属离子浓度的研究

将多元校正分析法应用于配位滴定中，以ＥＤＴＡ为滴定剂，玻璃电极为指示电极，饱和甘汞电极为参比电极。依据电位滴定原理，对混合三组分：Ｃｕ￣（２＋）、Ｃｄ￣（２＋）、Ｚｎ￣（２＋）、及Ｃｕ￣（２＋）、ＣＯ￣（２＋）、Ｎｉ￣（２＋）进行测定，各金属离子之间的△ｌｏｇＫ在０．０４～２．３４之间，计算误差一般小于土１０％。     

离子质谱计测定地质样品中镁同位素组成方法学研究

应用信通公司研制的离子质谱计（ＳＴ－ＩＭＳ），建立了地质样品镁同位素分析的实验流程和误差分析方法，为进一步分析微量地质样品中镁同位素组成和分布奠定了基础。     

地球弓激波前的低频磁流体波

一、引言 在地球弓激波前存在着低频磁流体波。这种低频磁流体波是太阳风在地球弓激波上的反射粒子和太阳风粒子之间相互作用产生的。根据人造卫星的观测资料可以得到,在地球弓激波前,Pc3-4脉动频率范围内的低频磁流体波的主频率和行星际磁场强度     

Variability of theS q focus position in the South American continent

The daily variation of the H component at Pilar (31.7°S, 63–9°W) and Trelew (43.3°S, 65.3°W) in the South American continent indicates a great variability in amplitude from season to season and even from day to day. However, Pilar always remains equatorward of the southern S_q, focus. On the other hand, Trelew is in most cases slightly poleward of the S_q, focus; but the focus has large latitudinal excursions above and near Trelew. A cause of this variability could be the encroachment of polar ionospheric current systems into the low latitude ionospheric S_q, current system.     

碳棒涂膜式PVC膜铯离子选择电极的研制和应用

本文作者研制成功以四苯硼铯为活性物质的碳棒涂膜式PVC膜铯离子选择性电极。电极最佳膜组成:四苯硼铯5mg,邻苯二甲酸二丁酯0.4ml,硝基苯0.2ml,PVC粉0.2g。电极性能优良,制作简单,操作方便。结合大粒度磷钼酸铵和结晶形锑酸分离K~+,Na~+,巳将此电极用于卤水样中铯的测定,结果令人满意。     

金在表生条件下溶解,迁移和沉淀的探讨

金矿物在表生条件下溶解为离子金.离子金与表生络合剂结合成金络离子团迁移.在物化条件改变时,由于有机炭、粘土矿物及带异性电荷胶体吸附,使金络离子团分解成原子金沉淀.     

离子色谱—双电导法同时测定水样中多种阴离子的研究

本文在Dionex2020i离子色谱仪上,选用0.61×10~(-3)mol/L NaHCO_3-1.61×10~(-3)mol/LNa_2CO_3水溶液作淋洗液,在HPIC-AS4A阴离子分离柱上分离痕量F~-、NO_2~-、Br~-和较高浓度的Cl~-、NO_3~-、SO_4~(2-);选用2.0×10~(-3)mol/L TBAOH-6％CH_3CN水溶液作淋洗液,在MPIC-NS1分离柱上分离痕量F~-、Br~-和较高浓度的Cl~-,然后用串联双电导检测器的不同输出范围分别同时定量测定。本法特别适用于相邻两种离子浓度相差较大,前面高含量的离子对后面痕量离子测定有干扰的样品。用本文拟定的HPIC方法测定除铬后的地下水样中多种阴离子的结果与文献值吻合。