Hydrochemical characteristics and the effects of irrigation on groundwater quality in Harran Plain,GAP Project,Turkey

Improper design, faulty planning, mismanagement and incorrect operation of irrigation schemes are the principle reasons for the deterioration of groundwater quality in a large number of countries, in particular in semi-arid and arid regions. The aim of this study is to determine the dimensions of groundwater quality after surface irrigation was begun in the semi-arid Harran Plain. Physical and chemical parameters of the groundwater including pH, temperature, electrical conductivity (EC), sodium, potassium, calcium, magnesium, chloride, bicarbonate, sulphate, nitrate, nitrite, ammonium, total phosphorus, total organic carbon and turbidity were determined monthly during the 2006 water year. The quality of the groundwater in the study area was assessed hydrochemically in order to determine its suitability for human consumption and agricultural purposes. In the general plain, the EC values measured were considerably above the guide level of 650 μS/cm, while nitrate in particular was found in almost all groundwater samples to be significantly above the maximum admissible concentration of 50 mg/l for the quality of water intended for human consumption as per the international and national standards. Total hardness reveals that a majority of the groundwater samples fall in the very hard water category. Interpretation of analytical data shows that Ca–HCO₃ and Ca–SO₄ are the dominant hydrochemical facies in the study area.     

马兰煤矿矿井水水质变化特征及成因

通过对山西省马兰煤矿2号煤层采掘面在开采和封闭时期的矿井水和沉积物的研究,揭示采掘面封闭前后对矿井水水质和沉积物的影响机理。研究结果表明：马兰煤矿矿井水均为SO₄-Ca型水质,矿井水均富含SO₄^2-和Fe离子;随着上部煤层的不断开采,3处矿井水呈现相同的变化规律,矿井水的pH值升高,Eh值降低,SO₄^2-、Fe、Mn和Zn离子浓度随之下降,其中北一暗斜井处的矿井水水质变化最显著;矿井水水质指标和流速变化能够控制其沉积物的矿物组成和结晶程度,北一暗斜井处的沉积物在两次采样中由斯沃特曼铁矿变为针铁矿,而其他两处的矿井水沉积物矿物组分没有发生变化,主要由针铁矿组成。研究结果能够提高对老空区积水水质的预测精度,并对煤矿突水水源判识具有重要意义。     

冷冻固定化优势菌群处理含甲醛苯酚废水

包气带土壤中氨氮污染迁移规律已成为近年来国内外学者研究的重点,目前在氨氮污染迁移规律研究中采用柱实验模拟以及软件模拟的方法较多,土壤生物技术则广泛应用于污染物降解领域,而在污染物迁移规律研究中应用较少。本文采用变性梯度凝胶电泳(DGGE)技术、16S rRNA序列分析技术以及典范对应分析相结合,对华北平原3个典型氨氮污染区土壤表层至包气带剖面微环境的细菌垂直分布特征及群落结构进行研究。结合污染区土壤理化性质分析,认为包气带土壤剖面的细菌群落中存在着与氮循环、硫酸盐代谢等过程偶联的优势细菌类群,说明土壤微环境中细菌群落分布明显受氨态氮、硝态氮、亚硝态氮和硫酸盐的分布影响,进一步表明污染土壤优势菌群的群落结构信息是描述包气带土壤环境氨氮污染物迁移规律的重要参数。     

长春市城市土壤中重金属元素的积累及其微生物特性研究

由于人为活动的影响,长春市城市土壤中重金属Cu、Zn、Pb、Cd已有了显著积累。在重金属的胁迫下,土壤微生物特征发生了明显变化,微生物代谢活动明显增强,但微生物生物量却有较大的降低。微生物生理生态参数土壤微生物量碳与总有机碳的比值(Cmic/Corg)和代谢商QCO2(微生物呼吸作用强度与微生物量碳的比值)变化异常。研究表明,微生物特性可作为城市土壤环境中重金属含量变异的有效指标。     

化学与稳定同位素指纹示踪原油类污染:以广东南海两次小型溢油事件为例

化学和稳定同位素指纹是目前国际上用于示踪石油类污染来源及其环境命运的有效技术。通过气相色谱-质谱(GC—MS)分析可疑重油与被污染水体及植物表面污染物的饱和烃和芳烃分布以及生物标志化合物姥姣烷、植烷、“不可分辨的混合物”(UCM)等化学指纹特征,对比可疑重油与被污染水体表面漂浮重油的沥青质同位素组成,追踪了发生在广东省南海市的两次小型重油泄漏事件。结果揭示,2002年10月16日晚发生的污染事件源于某饲料公司锅炉房的重油泄漏;而2002年10月25日的泄漏事故则是某加油站重油渗漏所致。     

农业生态地质调查初探——以辽宁鞍山南部地区为例

以鞍山南部地区农业生态地质调查为例,阐述了通过测定主要元素在土壤中的分布,综合评价农业生态地质背景,从而研究土地种植适宜性及土壤环境安全性和治理对策,进而讨论在辽宁省开展农业生态地质调查研究的主要内容及意义.此外,对特种经济作物南果梨专项调查表明,土壤中铁、锰、镁、钾、钴元素含量决定了南果梨的独特品质,以变辉长岩或片岩和花岗岩混合岩为成土母岩地区是南果梨生长的最佳区域.     

内蒙古武川-四子王旗地区地下水中的NO-3污染

三氮对人体的危害已引起人们的关注，NO3^--N是三氮的主体。本文分析了武川一四子王旗地区NO3^-的污染现状及其在水平和垂向上的分布特征和规律，研究了污染原因和过程，提出了相应的防治对策。     

Atmospheric sulfur deposition and streamwater quality in Finland

The correlation between sulfate concentrations in Finnish headwater streams and atmospheric sulfate deposition has been studied by using data from the streamwater chemistry in August–September 1990 and computed S deposition from the anthropogenic emissions. The sulfate concentrations and acidity in water are interpolated and smoothed into a deposition model grid. These data are compared with geological and pedogeochemical (glacial till) background information. The areas where the streamwater SO₄ concentrations are mainly controlled by either anthropogenic S deposition or sulfur in till is estimated by applying the fuzzy Gustafsson-Kessel algorithm, which provides a soft clustering suitable for overlapping control factors. Residual areas can be well explained by the SO₄-rich Littorina clay deposits. The higher overall background SO₄ concentrations in streams in south Finland compared with central and northern Finland are an indisputable consequence of the heavier S deposition load in the south. However, anthropogenic sulfur deposition has a clear correlation with the sulfates in streamwaters only in northeastern Lapland impacted by the large industrial emissions in the Kola Peninsula. The secondary sulfide and sulfate minerals of marine Littorina sediments are dominating sources in the broad coastal belts, as are the primary sulfide minerals locally in the Pori-Vammala area, at the eastern end of the main sulfide ore belt between Lake Ladoga and the Gulf of Bothnia, in the Outokumpu area, and in the Peräpohja and central Lapland schist belts. Consequently, in addition to the anthropogenic deposition, there are natural sources of sulfur which cause acidity of streamwaters.     

基于多元统计方法的地下水水化学特征分析:以沈阳市李官堡傍河水源地为例

为研究沈阳市李官堡傍河水源地的水化学变化特征与污染来源,在对该水源地开展野外污染调查、水化学样品采集等工作的基础上,结合聚类分析和因子分析两种多元统计分析方法对研究区地下水环境进行系统分析。结果表明:研究区平水期和丰水期的地下水均可划分为Ⅰ、Ⅱ两类具有不同水化学特征的两个区域。Ⅰ区主要分布在浑河沿岸,主要特征为Eh值偏低,pH值偏高,处于还原环境中,NH4+污染主要来源于浑河下渗与农业活动;Ⅱ区主要分布在研究区西北部,主要特征为Eh值偏高,pH值偏低,处于氧化环境中,NO3-污染主要来源于居民日常生活和工业活动等地表污染的垂向入渗。     

修正的内梅罗指数法及其在城市地下饮用水源地水质评价中的应用

为了克服内梅罗指数法和平均指数法存在的不足,对内梅罗指数法进行了修正。将公式中的算术平均修改为加权平均,各评价指标的权重是根据污染因子的危害性与该污染因子的排放标准呈反比例关系来确定的。并将修正后的公式用于西安市地下饮用水源地的水质评价中。结果表明,改进后的方法更能客观地评价水质状况,既突出了最大污染因子,又增强了危害性较强因子的作用,是合理的。