Specific vulnerability assessment using the<Emphasis Type="Italic"> MLPI</Emphasis> model in Datong city,Shanxi province,China

This study outlines an improved method, MLPI (modified leaching potential index) model, for delineating and mapping groundwater vulnerability and assessing groundwater vulnerability to contaminants, including degradable contaminants, radioactive elements and nondegradable pollutants. The primary objective is to produce specific sensitivity maps at city or county scale that can be used for recognition of aquifer sensitivity and for protection of groundwater quality. Groundwater vulnerability assessment using the MLPI method is applied to Datong city, Shanxi Province, with the following conclusions: (1) specific vulnerability was differentiated and ; (2) groundwater vulnerability is of temporal variation.     

Assessment of groundwater residence times in the pore aquifers of the River Elbe Basin

An area covering assessment of the groundwater residence times for the upper pore aquifers in the River Elbe Basin was performed. Residence times were determined by combining groundwater velocities and flow distances along each flow-path to the surface waters using a two-dimensional model approach. Groundwater velocity was calculated as a function of hydraulic conductivity, hydraulic gradient and effective yield of pore space. Flow paths were obtained by an analysis of the morphology of the groundwater table. The mean groundwater residence time in the pore aquifers of the River Elbe Basin was quantified to about 25 years. A strong temporal blurring in the different regions between less than one year and more than 250 years was obtained. For the regional groundwater management in the Elbe Basin the groundwater residence times are an important parameter, which helps to take into account the temporal dimension in the assessment of the impact of political measures aiming at the improvement of groundwater quality with regard to diffuse pollutants (e.g. nitrate).     

A temporary sampling technique for investigating groundwater quality near the ground surface

Improved knowledge of processes determining groundwater quality is an important precondition for the solution of various ecological and water management problems. In areas with highly fluctuating groundwater levels, time-limited access, local pollution sources or temporary interactions between surface water and groundwater, a temporary groundwater sampling technique could be of advantage. Furthermore, depth-specific sampling is of high value for investigating groundwater pollution related to seepage or surface water infiltration. A stainless steel core probe has been developed to obtain groundwater samples and to measure the hydraulic head distribution at various defined depths. The sampling technique is applicable only for non-volatile water constituents. An advantage of the core probe is that it can be driven into soil or sediments using ordinary low cost percussion equipment. The probe enables hydraulic head measurements and water sampling over vertical intervals of 0.3 m. Results from field experiments using the stainless steel core probe were in good correspondence with results from groundwater sampling at nearby observation wells. In the upper layer of the aquifer, the intrinsic spatial change in concentrations of sulphate, chloride and other water constituents is a function of distance between observation points and groundwater surface. Results indicate strong effects of a fluctuating groundwater level on groundwater quality at certain depths.     

The impacts of pasture- and manure-spreading on microbial groundwater quality in carbonate aquifers

Hydrogeological and microbiological research is in progress to analyze the interaction between groundwater and microbial pollutants, produced by pasture and/or manure spreading, in the areas of different carbonate aquifers of southern Italy. Several springs and wells were studied, and the precipitation, the discharge, the groundwater level and the classic microbial indicators of pollution were monitored weekly or daily. The experimental results show that the pasture and the manure spreading produced microbial contamination of the groundwater, even if runoff infiltration in swallow holes does not exist. The time dependence of microbial contamination shows a series of peaks irregularly distributed, related to the precipitation that produce effective infiltration.     

Changes in groundwater chemistry due to metallurgical activities in an alluvial aquifer in the Moa area (Cuba)

The aim of this work is to evaluate the changes in groundwater chemistry in an alluvial aquifer in the Moa area. Surface and ground water, metallurgical waste and various geological material samples were collected in order to evaluate groundwater composition. The results show that the alluvial aquifer is polluted with SO₄^2-, Mg²⁺and heavy metals. According to its major components in the alluvial aquifer, two types of groundwater are identified: magnesi-bicarbonated and sulphate-magnesic. Maximum SO₄^2– and Mg²⁺ contents are more than 1000 mg/L, and are four times higher than the acceptable levels for human consumption of water. The high values of Cr(VI), Ni(II), Mn(II) Fe_(total), SO₄^2– and Mg²⁺ in alluvial aquifers are due to polluted recharge from metallurgical waste from the tailing dam. This recharge is favoured by the preferential flow due to desiccation cracks in metallurgical waste. Geochemical modelling showed that potentially toxic heavy metals might exist largely in the forms of MSO₄^2– and M²⁺ in pore water of SAL metallurgical waste. All samples were supersaturated in goethite and hematite. Results from batch testing indicate that the heavy metals have two origins: natural, due to the existing ultramaphic rocks and laterites, and anthropogenic, by metallurgical waste rich in sulphate and (oxy)hydroxide minerals. These results highlight the need to locate and evaluate a new water source to supply the population of the city of Moa.     

Influences of agricultural practices on water quality of Tumbling Creek cave stream in Taney County,Missouri

Influences of agricultural practices on water quality of the Tumbling Creek cave stream are of particular interest because of the karst nature of the area and the recent implementation of a Better Management Practice (BMP). Water quality parameters, measured bi-weekly during one year, consisted of pH, turbidity, water temperature, specific conductivity, total dissolved solids, alkalinity, and chloride. Heavy metals, nutrient and bacteria levels were also monitored during the study. Effects of land use were most obvious in turbidity, nitrate, chloride, and bacteria levels. Sites within the recharge area that pose a major threat to its water quality were identified. Results provide a baseline for these water quality parameters and their seasonal variability that can be used in future studies to address the effects of water quality and stream sediment contamination on the caves ecosystem and to determine the effectiveness of the BMP implemented in this karst area.     

Geochemical assessment of groundwater contamination with special emphasis on fluoride concentration, North Jordan

The concentrations of fluorine in groundwater of North Jordan range from 0.009 to 0.055 mg/l. Other chemical parameters, e.g. pH, EC, TDS, Cl, TH, HCO₃, PO₄, SO₄, NO₃, NH₄, K, Ca, Mg, and NO₃ have been studied and showed higher concentrations in HCO₃⁻ and NO₃⁻ of 307 and 51 mg/l, respectively. Thermodynamic considerations show that almost all the analyzed samples are undersaturated with respect to calcite and fluorite. This undersaturation is probably due to their low availability in the locations. Fluoride concentration shows a positive relation to pH and HCO₃, whereas Cl, Mg, Ca, and Na initially increase and then decrease with increasing fluoride in the water. Saturation indexes of fluorite and calcite are estimated. The chemistry of the groundwater is controlled by the fluorite and calcite solubility. The topography of the area has exerted control on the aerial extent of fluoride concentration.     

Inputs of dissolved and particulate 226Ra to lakes and implications for 210Pb dating recent sediments

Gamma spectroscopy was used to measure radioisotope (²¹⁰Pb, ²²⁶Ra, ¹³⁷Cs) activities in sediment cores from 20 lakes and a wetland in Florida, USA. Nine profiles display relatively low (<5 dpm g^–1) and constant ²²⁶Ra activities, whereas 12 show high (>5 dpm g^–1) and variable ²²⁶Ra activities. In the latter group, most display up-core increases in activity. Upper sediments from two lakes (Round and Rowell) possess very high (>20 dpm g^–1) ²²⁶Ra activities that exceed total ²¹⁰Pb activities, clearly illustrating disequlibrium between ²²⁶Ra and supported ²¹⁰Pb. Supported ²¹⁰Pb activity is generally thought to come from in situ, ²²⁶Ra-containing detrital mineral particles, and is typically assumed to be in secular equilibrium with ²²⁶Ra activity. Since 1966, Round Lake has been augmented hydrologically with ²²⁶Ra-rich (6.2 dpm L^–1) groundwater pumped from the local deep aquifer. Adsorption of dissolved ²²⁶Ra to recent Round Lake sediments probably accounts for the high measured ²²⁶Ra activities and the pronounced disequilibrium between ²²⁶Ra and supported ²¹⁰Pb in topmost deposits. We suspect that many Florida waterbodies receive some ²²⁶Ra-rich runoff and seepage from groundwater pumped for irrigation, residential use, industrial applications, and mining. This may account for up-core increases in ²²⁶Ra activity measured in sediment cores from some Florida lakes. Significant groundwater pumping began within the last century, and there has been insufficient time for supported ²¹⁰Pb to come into equilibrium with adsorbed ²²⁶Ra in uppermost deposits. Input of ²²⁶Ra-rich groundwater to lakes may occur in any geographic region where local bedrock contains ²³⁸U and its daughters. When dissolved ²²⁶Ra adsorbs to recent sediments, it complicates accurate estimation of supported ²¹⁰Pb activity, and confounds calculation of unsupported ²¹⁰Pb activity that is used in dating models.     

Natural tracers in recent groundwaters from different Alpine aquifers

Groundwater with underground residence times between days and a few years have been investigated over more than 20 years from 487 remote sites located in different aquifer types in the Alpine belt. Analysis of the data reveals that groundwaters evolved in crystalline, evaporite, carbonate, molasse, and flysch aquifers can be clearly distinguished based on their major and trace element composition and degree of mineralisation. A further subdivision can be made even within one aquifer type based on the trace element compositions, which are characteristic for the lithologic environment. Major and trace element concentrations can be quantitatively described by interaction of the groundwater with the aquifer-specific mineralogy along the flow path. Because all investigated sites show minimal anthropogenic influences, the observed concentration ranges represent the natural background concentrations and can thus serve as a geo-reference for recent groundwaters from these five aquifer types. This geo-reference is particularly useful for the identification of groundwater contamination. It further shows that drinking water standards can be grossly exceeded for critical elements by purely natural processes.

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Resumen Durnate más de 20 años se ha investigado aguas subterráneas con una residencia subterránea con una duración de días a varios años en 487 puntos remotos localizados en diferentes tipos de acuíferos en la cadena alpina. El análisis de los datos revela que las aguas subterráneas que han evolucionado dentro de acuíferos cristalinos, evaporíticos, carbonatos, flysch, y molasse se pueden distignuir claramente en base a la composición de sus elementos mayores y marcadores y al grado de minerlización. Asimismo es posible hacer una subdivisión más específica incluso dentro de un tipo de acuífero en base a las composiciones de los elementos marcadores los cuales soncaracterísticos del ambiente litológico. Las concentraciones de los elementos marcadores se pueden describir cuantitativamente por la interacción de las aguas subterráneas con la mineralogía específica del acuífero a lo largo del trayecto del flujo. Puesto qze todos los puntos investigados muestran mínimas influencias antropogénicas, los rangos deconcentraciones observados representan las concentraciones delescenario natural y, por tanto, pueden servir como georeferencia para aguas subterráneas recientes que forman parte de estos cinco tipos de acuíferos. Esta georeferencia es particularmente útil para la identificcación de contaminación de aguas subterráneas. Asimismo muestra que los estándares de agua potable pueden mostrar excesos en elementos críticos por procesos puramente naturales.

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Résumé Leau souterraine ayant résidé sous la surface du sol entre quelques jours et quelques années a été étudiée sur une période de plus de 20 ans à partir de 487 sites éloignés situés dans différents types daquifères de la ceinture alpine. Lanalyse des données révèle que leau qui a évoluée dans des aquifères cristallins, évaporitiques, carbonatés, molassiques et composés de flysch, peut être facilement différenciée sur la base de sa composition en éléments majeurs et traces, ainsi que par son degré de minéralisation. Une subdivision supplémentaire peut être apportée à lintérieur même dun type daquifère en se basant sur la composition des éléments traces, lesquels sont caractéristiques de lenvironnement lithologique. La concentration en éléments majeurs et traces peut être expliquée quantitativement par linteraction de leau souterraine avec la composition minéralogique spécifique de laquifère le long des lignes découlement. Puisque la majorité des sites étudiés ne montrent que très peu dinfluences anthropogéniques, le registre de concentrations observées représente la concentration de fond naturelle et peut ainsi servir comme géo-référence pour les eaux souterraines récentes dans ces cinq types daquifères. Ces géo-références sont particulièrement utiles pour lidentification de la contamination des eaux souterraines. Par ailleurs, cela démontre que les standards deau potable peuvent être excédés pour certains éléments en raison de processus purement naturels.

     

Groundwater recharge in a sedimentary basin in semi-arid Mexico

Recharge mechanisms and the hydrochemical evolution of groundwater in a semi-arid, 6,840-km², intermountain basin in central Mexico were investigated using stable isotopes and major chemical constituents. Ionic ratio analysis helped to conceptualize and quantify in part the subsequent geochemical evolution in the aquifer system. Mass balance models (PHREEQC) were used to interpret and rectify the geochemical properties of the aquifer. The recharge conditions have not changed noticeably during the last several thousands of years. The recharge mechanisms are accompanied by leaching of meteoric salts on and near the ground surface during major rain events, which previously accumulated after minor rain events. Rapid and diffuse infiltration can be excluded. Indirect infiltration from wadis (arroyos) and depressions (playas) with little mixing in shallow groundwater contrasts with a high degree of mixing for water with deep circulation. The prevailing source of major cations (Ca²⁺, Mg²⁺, Na⁺, K⁺) is weathering of carbonates and albite, followed by exchange reactions on clays and hydroxides. Ca²⁺/Na⁺ exchange may interchange along the flow path with reverse (Na⁺/Ca²⁺) exchange, although the Ca²⁺/Na⁺ option is prevalent. Meteoric Ca and Mg inputs are relatively small; however, meteoric Na is insignificant. Irrigation return flow plays an important role in the western part of the study area, giving rise to elevated sulfate and chloride concentrations.

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Resumen Se han investigado los mecanismos de recarga y la evolución hidroquímica de las aguas subterráneas en una cuenca semiárida e intermontanosa de México central, de 6.840 km². Para ello, se han utilizado isótopos estables y los constituyentes químicos mayores. El análisis de las relaciones iónicas ha servido para conceptuar y cuantificar en parte su evolución geoquímica posterior dentro del sistema acuífero. Se ha recurrido a modelos de balance de masas (PHREEQC) para interpretar y rectificar las propiedades geoquímicas del acuífero. Las condiciones de recarga no han cambiado de forma apreciable durante los últimos miles de años. Los mecanismos de recarga se ven acompañados por el lixiviado de las sales meteóricas sobre y cerca de la superficie del terreno durante los episodios principales de lluvia, las cuales son acumuladas en episodios menores de lluvia. Se puede excluir la infiltración rápida y difusa. La infiltración indirecta desde arroyos ( wadis) y depresiones ( playas), que apenas se mezcla con las aguas subterráneas someras, contrasta con un elevado nivel de mezcla con el agua de circulación profunda. La fuente dominante de cationes mayores (calcio, magnesio, sodio, potasio) es la meteorización de los carbonatos y albita, mientras que las reacciones de intercambio en las arcillas e hidróxidos son menos importantes. El intercambio ión calcio-ión sodio puede ser reemplazado a lo largo de una línea de flujo por el intercambio opuesto (ión sodio-ión calcio), aunque la primera es prioritaria. Las aportaciones meteóricas de calcio y magnesio son relativamente pequeñas, mientras que la de sodio es insignificante. Los retornos de riego desempeñan un papel importante en la parte occidental del área de estudio, dando lugar a concentraciones elevadas de sulfato y cloruro.

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Résumé Les mécanismes de recharge et lévolution hydrochimique de leau souterraine dans un bassin de montagne de 6 840 km² en zone semi-aride, dans le centre du Mexique, ont été étudiés au moyen des isotopes stables et des composés chimiques majeurs. Lanalyse des rapports ioniques a aidé à conceptualiser et à quantifier en partie lévolution géochimique qui en résulte, dans le système aquifère. Des modèles de bilan de masse (PHREEQC) ont été utilisés pour interpréter et corriger les propriétés de laquifère. Les conditions de recharge nont pas changé notablement au cours des derniers millénaires. Les mécanismes de recharge sont accompagnés, durant les épisodes majeurs de précipitation, dun lessivage, à la surface du sol et à son voisinage, de sels météoriques accumulés auparavant pendant les petits épisodes de pluie. Linfiltration rapide et diffuse peut être exclue. Linfiltration indirecte à partir des oueds (arroyos) et des dépressions (playas) avec un faible mélange dans la nappe superficielle contraste avec le degré élevé de mélange de leau avec les circulations profondes. La source prépondérante des cations majeurs (Ca²⁺, Mg²⁺, Na⁺, K⁺) est laltération des carbonates et des feldspaths ; léchange de cations avec les argiles et les hydroxydes est moins important. Léchange de Ca²⁺ avec Na⁺ peut sinverser le long des axes découlements pour donner un échange de Na⁺ avec Ca²⁺, bien que le cas Ca²⁺/Na⁺ soit prépondérant. Les apports météoriques de Ca et de Mg sont relativement faibles, cependant que celui de Na météorique est insignifiant. Lécoulement par retour dirrigation joue un rôle important dans la partie occidentale de la région étudiée, produisant un accroissement des concentrations élevées en sulfate et en chlorure.