Thermodynamics of mixing in diopside–jadeite,CaMgSi<Subscript>2</Subscript>O<Subscript>6</Subscript>–NaAlSi<Subscript>2</Subscript>O<Subscript>6</Subscript>, solid solution from static lattice energy calculations

Static lattice energy calculations (SLEC), based on empirical interatomic potentials, have been performed for a set of 800 different structures in a 2 × 2 × 4 supercell of C2/c diopside with compositions between diopside and jadeite, and with different states of order of the exchangeable Na/Ca and Mg/Al cations. Excess static energies of these structures have been cluster expanded in a basis set of 37 pair-interaction parameters. These parameters have been used to constrain Monte Carlo simulations of temperature-dependent properties in the range of 273–2,023 K and to calculate a temperature–composition phase diagram. The simulations predict the order–disorder transition in omphacite at 1,150 ± 20°C in good agreement with the experimental data of Carpenter (Mineral Petrol 78:433–440, 1981). The stronger ordering of Mg/Al within the M1 site than of Ca/Na in the M2 site is attributed to the shorter M1–M1 nearest-neighbor distance, and, consequently, the stronger ordering force. The comparison of the simulated relationship between the order parameters corresponding to M1 and M2 sites with the X-ray refinement data on natural omphacites (Boffa Ballaran et al. in Am Mineral 83:419–433, 1998) suggests that the cation ordering becomes kinetically ineffective at about 600°C.     

大别造山带毛屋超镁铁岩的铂族元素研究

采用镍锍火试金法结合ICP-MS分析了毛屋斜方辉石岩和石榴二辉岩样品中的Ir、Ru、Rh、Pt和Pd的含量,结果显示其铂族元素(PGE)的含量随岩石类型无规律性的变化,原始地幔标准化后的铂族元素分布模式呈负斜率,Pd、Ir发生了分异。毛屋超镁铁岩铂族元素特征的形成受岩石中铂族元素的存在相制约,PPGE富集在富Cu硫化物,而IPGE以类似残留相、不熔的单硫化物固熔体形式存在,其中地壳混染也起了一定的作用;同时,成岩过程中流体的存在造成了Pt和Pd的活化。因此,单硫化物固熔体和流体的共同作用形成了毛屋超镁铁岩类似残留地幔岩的铂族元素分布特征。     

Influence of Tide Models on the Use of Altimetry Data to Research Sea Level Anomaly

A tide model (named DN1.0), which contains 12 principal constituents over China seas and the Northwest Pacific is estimated by along-track harmonic analysis with TOPEX/Poseidon altimetry data taken from 1993 to 2002. CSR3.0, FES95.2 and DN1.0 are used respectively to detide the data for the time series of sea level anomaly (SLA) in the Yellow Sea, East China Sea, South China Sea and Northwest Pacific. The SLA curves and the power spectral density show that the major components that exist in SLA in China seas arise from the error of the tide models.     

Comparison of gravimetric and seismic constraints on the structure of the Aegean lithosphere in the forearc of the Hellenic subduction zone in the area of Crete

The island of Crete is located in the forearc of the Hellenic subduction zone, where the African lithospheric plate is subducting beneath the Eurasian one. The depth of the plate contact as well as the internal structure of the Aegean plate in the area of Crete have been a matter of debate. In this study, seismic constrains obtained by wide-angle seismic, receiver function and surface wave studies are discussed and compared to a 3D density model of the region.The interface between the Aegean continental lithosphere and the African one is located at a depth of about 50 km below Crete. According to seismic studies, the Aegean lithosphere in the area of Crete is characterised by strong lateral, arc–parallel heterogeneity. An about 30 km thick Aegean crust is found in central Crete with a density of about 2850 kg/m³ for the lower Aegean continental crust and a density of about 3300 kg/m³ for the mantle wedge between the Aegean crust and the African lithosphere. For the deeper crust in the area of western Crete two alternative models have been proposed by seismic studies. One with an about 35 km thick crust and another one with crustal velocities down to the plate contact. A grid search is performed to test the consistency of these models with gravimetric constraints. For western Crete a model with a thick lower Aegean crust and a density of about 2950 kg/m³ is favoured. The inferred density of the lower Aegean crust in the area of Crete correlates well with S-wave velocities obtained by surface wave studies.Based on the 3D density model, the weight of the Aegean lithosphere is estimated along an E–W oriented profile in the area of Crete. Low weights are found for the region of western Crete.     

Latitudinal and longitudinal variability of mesospheric winds and temperatures during stratospheric warming events

Continuous MF and meteor radar observations allow detailed studies of winds in the mesosphere and lower thermosphere (MLT) as well as temperatures around the mesopause. This height region is characterized by a strong variability in winter due to enhanced planetary wave activity and related stratospheric warming events, which are distinct coupling processes between lower, middle and upper atmosphere. Here the variability of mesospheric winds and temperatures is discussed in relation with major and minor stratospheric warmings as observed during winter 2005/06 in comparison with results during winter 1998/99.Our studies are based on MF radar wind measurements at Andenes (69°N, 16°E), Poker Flat (65°N, 147°W) and Juliusruh (55°N, 13°E) as well as on meteor radar observations of winds and temperatures at Resolute Bay (75°N, 95°W), Andenes (69°N, 16°E) and Kühlungsborn (54°N, 12°E). Additionally, energy dissipation rates have been estimated from spectral width measurements using a 3 MHz Doppler radar near Andenes. Particular attention is directed to the changes of winds, turbulence and the gravity wave activity in the mesosphere in relation to the planetary wave activity in the stratosphere.Observations indicate an enhancement of planetary wave 1 activity in the mesosphere at high latitudes during major stratospheric warmings. Daily mean temperatures derived from meteor decay times indicate that strong warming events are connected with a cooling of the 90 km region by about 10–20 K. The onset of these cooling processes and the reversals of the mesospheric circulation to easterly winds occur some days before the changes of the zonal circulation in the stratosphere start indicating a downward propagation of the circulation disturbances from the MLT region to the stratosphere and troposphere during the stratospheric warming events. The short-term reversal of the mesospheric winds is followed by a period of strong westerly winds connected with enhanced turbulence rates and an increase of gravity wave activity in the altitude range 70–85 km.     

The global distribution of gravity wave energy in the lower stratosphere derived from GPS data and gravity wave modelling: Attempt and challenges

Five years of global temperatures retrieved from radio occultations measured by Champ (Challenging Minisatellite Payload) and SAC-C (Satelite de Aplicaciones Cientificas-C) are analyzed for gravity waves (GWs). In order to separate GWs from other atmospheric variations, a high-pass filter was applied on the vertical profile. Resulting temperature fluctuations correspond to vertical wavelengths between 400 m (instrumental resolution) and 10 km (limit of the high-pass filter). The temperature fluctuations can be converted into GW potential energy, but for comparison with parameterization schemes GW momentum flux is required. We therefore used representative values for the vertical and horizontal wavelength to infer GW momentum flux from the GPS measurements. The vertical wavelength value is determined by high-pass filtering, the horizontal wavelength is adopted from a latitude-dependent climatology. The obtained momentum flux distributions agree well, both in global distribution and in absolute values, with simulations using the Warner and McIntyre parameterization (WM) scheme. However, discrepancies are found in the annual cycle. Online simulations, implementing the WM scheme in the mechanistic COMMA-LIM (Cologne Model of the Middle Atmosphere—Leipzig Institute for Meteorology) general circulation model (GCM), do not converge, demonstrating that a good representation of GWs in a GCM requires both a realistic launch distribution and an adequate representation of GW breaking and momentum transfer.     

广西固体矿产钻探工程技术与管理现状及其对策

从钻探设备、工艺技术、生产管理与人员素质等方面，简要分析了广西地矿局固体矿产钻探工程施工技术与管理现状，指出当前存在的突出问题以及解决这些问题的一些建议与对策。     

Contribution de la gravimétrie à l'étude de la structure du bassin de Tadla (Maroc) : Implications hydrogéologiques

This study is based on the analysis and the interpretation of the gravity data of the Tadla basin. Its purpose is to increase the knowledge of this basin structure. A residual anomaly map was first calculated from the Bouguer anomaly data witch are strongly affected by a regional gradient. The computed map provides information on the ground density variation but it does not bring enough of new elements. Data filtering allows us to emphasize the structures affecting the basin. We chose the horizontal gradient coupled to the upward continuation techniques that permit to highlight news structures and to give information on their dip. The elaborated structural map of the study area constitutes a useful document for rationalizing the future groundwater exploration in the Tadla basin. To cite this article: A. Najine et al., C. R. Geoscience 338 (2006).