红层（盆）与金矿化关系的探讨

红层（盆）内外存在着工业金矿化现象，与红层（盆）有关的金矿化包括：次火山岩型、卡林型、穆龙套型、不整合脉型、风化壳型、热泉型以及砂金等众多类型。它们的形成过程及分布与红层（盆）关系密切。本文总结了与红层（盆）有关金矿化的成矿模式及找矿方向。     

横江韧性剪切带基本特征

横江韧性剪切带与金矿关系密切。该带中央为揉流褶皱带,往两侧至边缘依次出现鞘褶皱、a型褶皱、b型褶皱。带内发育的拉伸线理方向与剪切带走向近于垂直,旋转石香肠指示剪切运动方向为北西一南东向右型剪切,表明本带为韧性推覆剪切带。     

载金石英的阳离子效应及其对含矿性的指示意义

石英的阳离子效应指石英结构中Al~(3+)与Si~(4+)的置换作用.在分析海南戈枕断裂金成矿带石英中普遍存在的这一作用,以及由此造成的石英粉末红外谱(IR)、顺磁共振谱(EPR)及热释光曲线(TL)特征,进而讨论了这些特征与金成矿的关系.     

八卦庙金矿床石英脉的控矿作用初探

八卦庙金矿床的矿石品位与其石英脉发育程度和破碎程度、共生硫化物的含量成正比,与脉体的厚度、共生硫化物的粒度成反比;节理脉的含金量比顺层脉的含金量高;石英细脉的含金量高于脉旁围岩的含金量数倍至十多倍,但含金石英脉不能单独构成工业矿体.据此,作者首次提出金矿化类型属于细脉浸染型金矿,揉皱石英细(网)脉破碎带是此类金矿的一种重要而直观的找矿标志.     

陕、甘、川“金三角”地区砂金富集规律及成因类型

区内砂金矿大都分布在嘉陵江、涪江、白龙江和汉水的河床、河漫滩及Ⅰ级阶地内。在河道由开阔趋向狭窄或由狭窄突变为开阔地段、河流转弯的凸岸（堆积岸）弧形拐弯偏向上游地段、支沟与主河道文汇处靠下游等地段砂金相对富集。砂金主要富集在松散沉积层近底部的含泥砂砾层中。区内砂金矿的成因类型分为冲积型河床砂金矿、冲积型河漫滩砂金矿和冲积型阶地砂金矿三种。成矿时代为全新世早期。形成砂金矿必须具备两个条件：一是必须有砂金矿质来源，即必须有含金地质体的存在；二是有适宜的外营力作用、良好的地貌条件和有利的新构造运动，两者缺一不可。据此划出琵琶寺一河口和刘家坪-椒园里两个找矿远景区。     

东坪式与正长岩类有关的金矿床成矿机理的同位素地球化学制约

东坪式金矿床产于华北地台北缘金矿成矿带的冀西北金矿集中区,构造上位于华北克拉通北缘深大断裂-尚义-赤城断裂的南侧。金矿床产于泥盆纪早期(386～410Ma)水泉沟正长岩杂岩体内及接触带附近,矿体分布受脆-韧性剪切断裂构造的制约。金矿成矿作用具有多期次的特点,成矿时代为燕山期(156～203Ma)。矿石类型主要为石英脉型、石英网脉 脉旁钾硅化蚀变岩型和钾硅化蚀变岩型,具有典型的碱性岩金矿的金-碲组合,(含)金矿物主要为自然金、碲金矿和碲金银矿。流体包裹体的 H、O 及 He 同位素研究表明,成矿流体为以大气降水主的混合热液流体并可能存在深源流体的参与。矿床的 S、Pb、Sr 和 Si 同位素组成表明,金矿成矿物质主要来源于正长岩杂岩体,部分源于太古宙桑干群变质岩和燕山期花岗岩。因此,东坪式金矿是由燕山期伸展构造环境下热液流体在上涌地幔及岩浆活动的热驱动下对泥盆纪早期形成的正长岩交代改造的产物。     

海南定安富文金矿床矿石特征

从不同标高、不同品位的矿石选矿试验研究入手，论述了富文金矿矿石的物质组成、矿物成分、结构构造、金的赋存状态等。研究表明，该金矿为中型特高硫化物含金石英脉型金矿床，矿体严格受断裂裂隙控制。矿石的有用组分多样，有害杂质少，金矿物主要为自然金。主要金属矿物为黄铁矿、毒砂，同时也是主要的载金矿物；非金属矿物为石英、碳酸盐矿物。矿石多具自形、半自形、他形粒状结构，以脉状、浸染状构造为主。自然金形态为尖角粒状、角粒状、长角粒状，赋存状态以裂隙金为主，其次为粒间金，包裹金占16．9％，自然金为细粒金。矿石类型为富金银多金属硫化物含金石英脉型。     

Effect of hematite on thiosulphate leaching of gold

Hematite, as a typical iron oxide slime in sulphide ore slurries, was artificially added into the leaching systems of pure gold and a sulphide ore respectively, in an attempt to investigate the effect of iron oxide slimes on the ammoniacal thiosulphate leaching of gold. The presence of hematite significantly reduced the dissolution of gold and this detrimental effect became more pronounced with increasing hematite concentration. Hematite formed coatings on gold surfaces, which could prevent leach solution from diffusing to the gold surfaces and hence, inhibit gold dissolution. Hematite catalysed the oxidative decomposition of thiosulphate to polythionates with oxygen present. XPS studies indicated a thin layer of iron oxide coating as well as the deposition of some copper and sulphur species on gold surfaces. SEM images revealed a lesser extent of corrosion for gold after leaching in the presence of hematite. The gold extraction from the sulphide ore was reduced with the addition of hematite and this effect became more noticeable with an addition of hematite at a higher concentration. A natural guar type surfactant (Gempolym M47) reduced the detrimental effect of hematite on gold extraction likely due to the prevention of hematite coating on gold and mineral particles and the dispersion of the mineral slurry. Gempolym M47 stabilised thiosulphate by weakening the interaction between cupric ions and thiosulphate and by minimising the catalytic effect of hematite on thiosulphate decomposition.     

Biomediation of calcrete at the gold anomaly of the Barns prospect,Gawler Craton,South Australia

Anomalously high Au concentrations (2.5 to 50 ppb) in regolith carbonate accumulations, such as calcrete and calcareous sands in aeolian sand dunes overlying Au mineralisation of the Gawler Craton, South Australia, show a marked covariance of Au with K, Mg and most notably Ca. This relationship appears to be linked to the authigenic formation of smectites and carbonates within the aeolian dunes in the region. However, little is known about the processes involved in the formation of carbonates under semi-arid and arid conditions. In this study the geochemical properties of aeolian dunes along several depth profiles of 2 to 4 m are investigated in order to assess the relationship between Au mobility and calcrete formation. In the profiles a strongly systematic relationship between Au and the increasing Ca–Mg contents at depth highlights the close association between the enrichment of Au in the calcrete and the underlying hydrothermal mineralisation. Intense calcrete formation and concurrent Au enrichment also occurs in the vicinity of roots penetrating the dune. Thin section petrography and cathodoluminescence show that most of the calcrete in the regolith profiles is micritic; some sparic crystallites have also been identified. To demonstrate the presence of microbial processes that may mediate the formation of calcrete, samples from a depth profile in the dune were taken under sterile conditions. After amendment with urea and incubation of up to 24 h, up to 18 mg/l of NH₄⁺ were detected in near surface samples. At depth of 2.3 m 1 mg/l NH₄⁺ were detected compared to a control that contained below 0.05 mg/l NH₄⁺. These results suggest that the genesis of calcrete and pedogenic carbonate in the area may be partly biologically mediated via processes such as the metabolic breakdown of urea by resident microbiota which generates a pH and pCO₂ environment conducive to the precipitation of carbonate. In the process of urea breakdown organic Au complexes such as Au-amino acid complexes may become destabilised in solution and Au may be co-precipitated, resulting in the fine, non-particulate distribution of Au throughout the micritic calcrete carbonate. In conclusion, this study suggests a coupled mechanism of biologically mediated and inorganic mechanisms that lead to the formation of Au-in-calcrete anomalies.     

陕西八卦庙金矿成矿流体初步研究

流体包裹体可以探讨金属矿床的形成机理和矿化规律,含金石英脉是研究成矿流体的重要载体。八卦庙金矿包裹体比较发育,主要为液体包裹体、含 CO_2包裹体,其次是气体包裹体。成矿流体温度变化范围是146℃～467℃,成矿早阶段的温度为370℃～400℃;主成矿阶段的温度集中在190℃～280℃,平均约250℃;成矿晚阶段的温度集中在130℃～160℃。成矿流体包裹体类型主要为 Na~ -Cl~-型,少数属于 Ca~(2 )-Na~ -Cl~-(-SO_4~(2-)-F~-)型。计算得到流体体系的酸碱度为弱酸性(pH值=5.6～5.8),硫逸度分布范围是-9.551～-19.265(平均-15.430),氧逸度分布范围是-46.011～-40.303。金主要以[Au(HS)_2]~-的形式迁移,其次以[AuS]~-形式迁移,在成矿活动过程,随温度的下降和压力的降低,伴有沸腾-减压过程,是成矿溶液发生卸载的重要机制。