Using tephrostratigraphy and cryptotephrostratigraphy to re-evaluate and improve the Middle Pleistocene age model for marine sequences in northeast Japan (Chikyu C9001C)

We refine the tephrostratigraphy and cryptotephrostratigraphy of the Middle Pleistocene deep-sea sediments in the C9001C cores and reconstruct the age model of the cores to provide a standard stratigraphy for the NW Pacific Ocean area. In the lower half of the cores (corresponding to marine isotopic stages [MISs] 9–18), we newly identify nine concentrations (spikes) of glass shards (numbered G17–G25 from top to bottom) below sixteen previously reported spikes (numbered G1–G16) in the upper half of the cores (MISs 1–9). We correlated two spikes (both cryptotephras) with known widespread tephras: G18 with Naruohama-IV (MIS 10d; 357 ka) and G19 with Kasamori 5 (MIS 12b–c; 434–458 ka). Although the two cryptotephra spikes cannot be distinguished by the major- and trace-element compositions of glass shards, these correlations are based upon their stratigraphic occurrence within separate glacial periods (MISs 10 and 12) as indicated by the δ¹⁸O stratigraphy of the C9001C sequence. Based on the stratigraphic positions of the Naruohama-IV and Kasamori 5 tephras, we assign the sediment units corresponding to MISs 10, 11, and 12, and revise the previous assignment of core segments corresponding to MISs 7, 8, and 9. The resulting tephra-based age model is consistent with the last occurrence of Proboscia curvirostris, but it is inconsistent with the first occurrence of Emiliania huxleyi. According to the new age model, the sedimentation rate during MISs 18–2 has ranged from 0.21 m/ky (during MIS 17) to 0.74 m/ky (during MISs 8 and 9), however, the sedimentation rate was never as high as the rate of 1.1 m/ky indicated by an earlier age model.     

Compositions of glass in proximal tephras from eruptions in the Azores archipelago and their links with distal sites in Ireland

The Azores archipelago is one of the most active volcanic areas in the North Atlantic region, with approximately 30 eruptions during the last 600 years. The geochemical composition of associated tephra-derived glass is, however, not well characterized. This study presents major element compositions of glass shards from five major eruptives on the Azores: a trachybasaltic eruptive on the island of Faial (Capelinhos AD, 1957) and four explosive trachytic eruptives on the island of São Miguel (Fogo A c. 5600 cal yrs. BP, Sete Cidades c. AD 1440, Fogo AD 1563 and Furnas AD 1630). The major element compositions suggest that tephras from three active stratovolcanoes on São Miguel, Sete Cidades, Fogo and Furnas, can be distinguished from one another using bi-plots of FeO_tot vs. TiO₂ and FeO_tot vs. CaO. Late Holocene tephras found on Ireland have previously been attributed to eruptions occurring on Jan Mayen but possess a strong geochemical similarity to proximal tephras from the Azores, especially those from the Furnas volcano. The similarity of the proximal tephras on São Miguel, especially Furnas AD 1563 and Furnas AD 1630 and distal tephras in Ireland is demonstrated by strong similarity coefficients (>0.95) and the closeness of major element composition. The dominant wind direction over the Azores is favourable for tephra dispersal to western Europe and we suggest that at least three tephras found in Ireland were erupted from the Furnas volcano, and that trachytic tephras erupted from explosive eruptions on São Miguel have a potential to contribute to the construction of a European-wide tephrostratigraphic framework.     

Reprint of Glass compositions and tempo of post-17 ka eruptions from the Afar Triangle recorded in sediments from lakes Ashenge and Hayk,Ethiopia

Numerous volcanoes in the Afar Triangle and adjacent Ethiopian Rift Valley have erupted during the Quaternary, depositing volcanic ash (tephra) horizons that have provided crucial chronology for archaeological sites in eastern Africa. However, late Pleistocene and Holocene tephras have hitherto been largely unstudied and the more recent volcanic history of Ethiopia remains poorly constrained. Here, we use sediments from lakes Ashenge and Hayk (Ethiopian Highlands) to construct the first <17 cal ka BP tephrostratigraphy for the Afar Triangle. The tephra record reveals 21 visible and crypto-tephra layers, and our new database of major and trace element glass compositions will aid the future identification of these tephra layers from proximal to distal locations. Tephra compositions include comendites, pantellerites and minor peraluminous and metaluminous rhyolites. Variable and distinct glass compositions of the tephra layers indicate they may have been erupted from as many as seven volcanoes, most likely located in the Afar Triangle. Between 15.3−1.6 cal. ka BP, explosive eruptions occurred at a return period of <1000 years. The majority of tephras are dated at 7.5−1.6 cal. ka BP, possibly reflecting a peak in regional volcanic activity. These findings demonstrate the potential and necessity for further study to construct a comprehensive tephra framework. Such tephrostratigraphic work will support the understanding of volcanic hazards in this rapidly developing region.     

观测仪器和百叶箱的变化对地面气温观测值的影响 及其原因分析

在未来的几年来,中国几十年以来一直使用的地面人工气象观测系统将全部被自动观测系统所取代,观测系统的变化(对气温观测而言,主要是感应器的变化和百叶箱的变化)导致气象要素观测值的系统偏差将是不可避免的。检测地面自动观测与人工观测的地面气温的差异,并分析产生这种差异的原因,对于分析我国气温时间序列的均一性,科学合理使用我国长期气候序列进行气候变化研究具有重要的科学意义,同时对于改进我国地面自动观测系统,减少观测值的系统误差,具有重要的业务应用价值。选取在同一观测场观测、具有同种防辐射百叶箱、不同感应仪器的人工和自动两种地面气温观测系统所获取的5个国家基准站的平行观测资料,分析了不同时间尺度(小时、日、月)的观测和统计值的差异,揭示了两种系统获得的气温测值的偏差,并分析了产生这种偏差的原因,近似估算了仪器精度、仪器灵敏度、太阳辐射和红外辐射等影响因子导致的偏差值。观测仪器的变化对气温测值有较明显的影响,日、月、年平均气温相差0.2左右,太阳辐射对不同仪器的影响不同是主要原因,同时,两种仪器存在0.1左右的系统观测误差,对环境温度变化的敏感性的差异也可引起一天中的不同时段存在0.1—0.15的差异。通过对3个台站不同百叶箱、相同仪器的对比观测试验资料的分析,表明从总体上看,百叶箱的变化对气温观测值的影响不大,但玻璃钢百叶箱内的气温对环境气温变化较木质百叶箱更灵敏。     

A combined glass dissolution/diffusion experiment in Boom Clay at 30 °C

At the appropriate times, silica diffusion in clay is possibly the rate determining process for the dissolution of vitrified waste disposed of in a clay layer. For testing this hypothesis, combined glass dissolution/silica diffusion experiment are performed. SON68 glass coupons doped with the radioactive tracer ³²Si are sandwiched between two cores of humid Boom Clay, heated to 30 °C. Due to glass dissolution, ³²Si is released and diffuses into the clay. At the end of an experiment, the mass loss of the glass coupon is measured and the clay core is sliced to determine the diffusion profile of the ³²Si released from the glass in the clay.Both mass loss and the ³²Si diffusion profile in the clay are described well by a model combining glass dissolution according to a linear rate law with silica diffusion in the clay. Fitting the experiments to this model leads to an apparent silica diffusion coefficient in the clay between 7 × 10⁻¹³ m²/s and 1.2 × 10⁻¹² m²/s. Previously determined values from diffusion experiments at 25 °C are around 6 × 10⁻¹³ m²/s (In-Diffusion experiments) and 2 × 10⁻¹³ m²/s (percolation experiments). The maximal glass dissolution rate for glass next to clay is around 1.6 × 10⁻⁷ g glass/m² s (i.e. 0.014 g glass/m² day). In undisturbed clay, the measured silica concentration is around 5 mg/L. Combining these values with the previously measured (In-Diffusion experiments) product of accessible porosity and retardation factor, leads in two ways to a silica glass saturation concentration in clay between 8 and 10 mg Si/L.Another candidate for the rate determining process of the dissolution of vitrified waste disposed in a clay layer is silica precipitation. Although silica precipitation due to glass dissolution has been shown experimentally at 90 °C, extending the model with silica precipitation does not lead to much better fits, nor could meaningful values of a possible precipitation rate be obtained.     

Viscosity of microlite-bearing rhyolitic obsidians: an experimental study

 To investigate the influence of microlites on lava flow rheology, the viscosity of natural microlite-bearing rhyolitic obsidians of calc-alkaline and peralkaline compositions containing 0.1–0.4 wt.% water was measured at volcanologically relevant temperatures (650–950  °C), stresses (10³–10⁵ Pa) and strain rates (10^–5 to 10^–7 s^–1). The glass transition temperatures (T _g ) were determined from scanning calorimetric measurements on the melts for a range of cooling/heating rates. Based on the equivalence of enthalpic (calorimetric) and shear (viscosity) relaxation, we calculated the viscosity of the melt in crystal-bearing samples from the T _g data. The difference between the calculated viscosity of the melt phase and the measured viscosity for the crystal-bearing samples is interpreted to be the physical effect of microlites on the measured viscosity. The effect of <5 vol.% rod-like microlites on the melt rheology is negligible. Microlite-rich and microlite-poor samples from the same lava flow and with identical bulk chemistry show a difference of 0.6 log₁₀ units viscosity (Pa s), interpreted to be due to differences in melt chemistry caused by the presence of microlites. The only major differences between measured and calculated viscosities were for two samples: a calc-alkaline rhyolite with 1 vol.% branching crystals, and a peralkaline rhyolite containing crystal-rich bands with >45 vol.% crystals. For both of these samples a connectivity factor is apparent, with, for the latter, a close packing framework of crystals which is interpreted to influence the apparent viscosity. Received: 14 March 1996 / Accepted: 30 May 1996     

Transport properties of high albite crystals,near-endmember feldspar and pyroxene glasses,and their melts to high temperature

Thermal diffusivity (D) was measured using laser-flash analysis (LFA) from oriented single-crystal albite and glasses near LiAlSi₃O₈, NaAlSi₃O₈, CaAl₂Si₂O₈, LiAlSi₂O₆ and CaMgSi₂O₆ compositions. Viscosity measurements of the supercooled liquids, over 2.6 × 10⁸ to 8.9 × 10¹² Pa s, confirm strongly non-Arrhenian behavior for CaAl₂Si₂O₈, and CaMgSi₂O₆, and near-Arrhenian behavior for the others. As T increases, D _glass decreases, approaching a constant near 1,000 K. Upon crossing the glass transition, D decreases rapidly. For feldspars, D for the melt is ~15% below D of the bulk crystal, whereas for pyroxenes, this difference is ~40%. Thermal conductivity (k _lat = ρC _P D) of crystals decreases with increasing T, but k _lat of glasses increases with T because heat capacity (C _P ) increases with T more strongly than density (ρ) and D decrease. For feldspars, k _lat for the melt is ~10% below that of the bulk crystal or glass, whereas this decrease for pyroxene is ~50%. Therefore, melting substantially impedes heat transport, providing positive thermal feedback that could promote further melting.     

谈谈建筑玻璃幕墙的防雷方法

对建筑玻璃幕墙的雷电危害及防雷措施进行分析，阐述玻璃幕墙防雷的有关做法。     

Influence of time, temperature, confining pressure and fluid content on the experimental compaction of spherical grains

Theoretical models of compaction processes, such as for example intergranular pressure-solution (IPS), focus on deformation occurring at the contacts between spherical grains that constitute an aggregate. In order to investigate the applicability of such models, and to quantify the deformation of particles within an aggregate, isostatic experiments were performed in cold-sealed vessels on glass sphere aggregates at 200 MPa confining pressure and 350 °C with varying amounts of fluid. Several runs were performed in order to investigate the effects of time, fluid content, pressure and temperature, by varying one of these parameters and holding the others fixed. In order to compare the aggregates with natural materials, similar experiments were also performed using quartz sand instead of glass spheres. Experiments with quartz show evidence of IPS, but the strain could not be quantified. Experiments with glass spheres show evidence of several types of deformation processes: both brittle (fracturing) and ductile (plastic flow and fluid-enhanced deformation, such as IPS). In experiments with a large amount of water (≥ 5 vol.%), dissolution and recrystallization of the glass spheres also occurred, coupled with crystallization of new material filling the initial porosity. Experiments performed with a fluid content of less than 1 vol.% indicate creep behavior that is typical of glass deformation, following an exponential law. These experiments can also be made to fit a power law for creep, with a stress exponent of n = 10.5 ± 2.2 in both dry and wet experiments. However, the pre-factor of the power law creep increases 5 times with the addition of water, showing the strong effect of water on the deformation rate. These simple and low-cost experiments provide new insights on the rheology of soda-lime glass, which is used in analogue experiments, and of glass-bearing rocks under mid-crustal P–T conditions. They also highlight the strong enhancement of plasticity of natural rocks in presence of fluid or of a glassy phase.     

Ignimbrites of basaltic andesite and andesite compositions from Tanna,New Hebrides Arc

Tanna island is part of a large volcanic complex mainly subsided below sea-level. On-land, two series of hydroclastic deposits and ignimbrites overlie the subaerial remains of a basal, mainly effusive volcano. The ‘Older’ Tanna Ignimbrite series (OTI), Late Pliocene or Pleistocene in age, consists of ash flows and ash- and scoria-flow deposits associated with fallout tephra layers, overlain by indurated pumice-flow deposits. Phreatomagmatic features are a constant characteristic of these tuffs. The ‘younger’ Late Pleistocene pyroclastics, the Siwi sequence, show basal phreatomagmatic deposits overlain by two successive flow units, each comprising a densely welded layer and a nonwelded ash-flow deposit. Whole-rock analyses of 17 juvenile clasts from the two sequences (vitric blocks from the phreatomagmatic deposits, welded blocks, scoriaceous bombs and pumices from the ignimbrites) show basaltic andesite and andesite compositions (SiO₂=53–60%). In addition, 296 microprobe analyses of glasses in these clasts show a wide compositional range from 51 to 69% SiO₂. Dominant compositions at ∼54, 56, 58.5 and 61–62% SiO₂ characterize the glass from the OTI. Glass compositions in the lower – phreatomagmatic – deposits from the Siwi sequence also show multimodal distribution, with peaks at SiO₂=55, 57.5, 61–62 and 64% whereas the upper ignimbrite has a predominant composition at 61–62% SiO₂. In both cases, mineralogical data and crystal fractionation models suggest that these compositions represent the magmatic signature of a voluminous layered chamber, the compositional gradient of which is the result of fractional crystallization. During two major eruptive stages, probably related to two caldera collapses, the OTI and Siwi ignimbrites represent large outpourings from these magmatic reservoirs. The successive eruptive dynamics, from phreatomagmatic to Plinian, emphasize the role of water in initiating the eruptions, without which the mafic and intermediate magmas probably would not have erupted. Received: February 19, 1993/Accepted October 10, 1993