The recharge of glacial meltwater and its influence on the geochemical evolution of groundwater in the Ordovician-Cambrian aquifer system,northern part of the Baltic Artesian Basin

The geochemical evolution of groundwater in the Ordovician-Cambrian aquifer system in the northern part of the Baltic Artesian Basin (BAB) illustrates how continental glaciations have influenced groundwater systems in proglacial areas. The aquifer system contains water that has originated from various end-members: recent meteoric water, glacial meltwater and relict Na-Cl brine. The saline formation water that occupied the aquifer system prior to the glacial meltwater intrusion has been diluted by meltwaters of advancing-retreating ice sheets. The diversity in the origin of groundwater in the aquifer system is illustrated by a wide variety in δ¹⁸O values that range from −11‰ to −22.5‰. These values are mostly depleted with respect to values found in modern precipitation in the area. The chemical and isotopic composition of groundwater has been influenced by mixing between waters originating from different end-members. In addition, the freshening of a previously saline water aquifer due to glacial meltwater intrusion has initiated various types of water-rock interaction (e.g. ion exchange, carbonate mineral dissolution).     

A 180,000-year pollen record from Owens Lake, CA: terrestrial vegetation change on orbital scales

Pollen from the upper 90 m of core OL-92 from Owens Lake is a climatically sensitive record of vegetation change that indicates shifts in the plant associations representing warm and cold desertscrub, pinyon–juniper woodland, and pine–fir forest during the past 180,000 years. These changes are synchronized with glacial–interglacial cycles. During glacial and stadial climates, juniper woodland expanded downslope and replaced warm desert shrubs while upper montane and subalpine forests in the arid Inyo Mountains also expanded, and those in the Sierra Nevada were displaced by the ice cap and periglacial conditions. Conversely, during interglacial and interstadial climates, warm desert plants expanded their range in the lowlands, juniper and sagebrush retreated upslope, and montane and subalpine forests expanded in the Sierra Nevada. The reconstructed vegetation history demonstrates a regional climatic response, and the congruence of the pollen sequence with marine and ice cap oxygen isotope stratigraphies suggests a link between regional vegetation and global climate change at orbital scales.     

Fate and transport of volatile organic compounds in glacial till and groundwater at an industrial site in Northern Ireland

Volatile organic compound (VOC) contamination of subsurface geological material and groundwater was discovered on the Nortel Monkstown industrial site, Belfast, Northern Ireland. The objectives of this study were to (1) investigate the characteristics of the geological material and its influences on contaminated groundwater flow across the site using borehole logs and hydrological evaluations, and (2) identify the contaminants and examine their distribution in the subsurface geological material and groundwater using chemical analysis. This report focuses on the eastern car park (ECP) which was a former storage area associated with trichloroethene (TCE) degreasing operations. This is where the greatest amount of volatile organic compounds (VOCs), particularly TCE, were detected. The study site is on a complex deposit of clayey glacial till with discontinuous coarser grained lenses, mainly silts, sands and gravel, which occur at 0.45–7.82 m below ground level (bgl). The lenses overall form an elongated formation that acts as a small unconfined shallow aquifer. There is a continuous low permeable stiff clayey till layer beneath the lenses that performs as an aquitard to the groundwater. Highest concentrations of VOCs, mainly TCE, in the geological material and groundwater are in these coarser lenses at ∼4.5–7 m bgl. Highest TCE measurements at 390,000 μg L⁻¹ for groundwater and at 39,000 μg kg⁻¹ at 5.7 m for geological material were in borehole GA19 in the coarse lens zone. It is assumed that TCE gained entrance to the subsurface near this borehole where the clayey till was thin to absent above coarse lenses which provided little retardation to the vertical migration of this dense non-aqueous phase liquid (DNAPL) into the groundwater. However, TCE is present in low concentrations in the geological material overlying the coarse lens zone. Additionally, VOCs appear to be associated with poorly drained layers and in peat <3.0 m bgl in the ECP. Some indication of natural attenuation as VOCs degradation products vinyl chloride (VC) and dichloromethane (DCM) also occur on the site.     

Hirnantian (Late Ordovician) δ13C HICE excursion in a North Gondwanan (NE Spain) periglacial setting and its relationship to glacioeustatic fluctuations

In the Iberian Chains of northeastern Spain, the Hirnantian Orea Shale comprises three erosive glaciogenic unconformities punctuating two transgressive glaciomarine sequences. These sequences represent ice retreat episodes of grounded ice on a North Gondwanan region of 50–60°S of estimated palaeolatitude. In contrast, the same formation recorded in the Hesperian Chains repeated episodes of extensional tectonic activity: diamictites were associated with slope-related debris flows and slumps commonly interrupted by truncating discontinuities.An analysis of δ¹³C_org in the Orea Shale has revealed that the lower Orea sequence displays isotopically light baseline values (∼ −27‰) punctuated by minor (2–3‰) shifts. In distal parts, the upper sequence is characterised by a rapid rise in δ¹³C_org values, which mark a positive excursion, in the range of 2.5‰ to 7‰ over 40 cm of thickness. The stratigraphic gap involved in the intra-Orea erosive unconformity appears to be greater both in proximal exposures and slope-related (Hesperian) areas, where the chemostratigraphic shift was not recorded. Upsection in the three studied sections, the δ¹³C values display upsection a sharp return to baseline values of −26‰ to −28‰.The Hirnantian strata of the Iberian and Hesperian Chains have recorded three major correlatable events: (i) a the karstic surface that caps upper Katian limestones and reflects the maximum glacial extension; (ii) a single δ¹³C_org positive peak of ∼6‰ that is recognisable in distal ramp settings, marking the beginning of the second ice retreat episode and probably representing the late Hirnantian HICE shift; and (iii) the erosive unconformity marked by the progradation of the Los Puertos shoreline complexes.     

A high-resolution speleothem proxy record of the Late Glacial in the European Alps: extending the NALPS19 record until the beginning of the Holocene

Previous research has shown that speleothems from the northern rim of the European Alps captured submillennial-scale climate change during the last glacial period with exceptional sensitivity and resolution, mimicking Greenland ice-core records. Here we extend this so-called NALPS19 record across the Late Glacial using two stalagmites which grew continuously into the Holocene. Both specimens show the same high-amplitude δ¹⁸O signal as Greenland ice cores down to decadal resolution. The start of the warming at the onset of the equivalent of Greenland Interstadial (GI) GI-1e at 14.66 ± 0.18 ka agrees with the North Greenland Ice Core Project (NGRIP) (14.64 ± 0.28 ka) and comprised a temperature rise of about 5–6 °C. The transition from the equivalent of GI-1a into the equivalent of Greenland Stadial (GS) GS-1 (broadly equivalent to the Younger Dryas) commenced at 13.02 ± 0.13 ka which is consistent with NGRIP (12.80 ± 0.26 ka) within errors. The onset of the Holocene started at 11.78 ± 0.14 ka (11.65 ± 0.10 ka at NGRIP) and involved a warming of about 4–5 °C. In contrast to δ¹⁸O, δ¹³C values show no response to (sub)millennial climate shifts due to strong rock-buffering and only record a long-term trend of soil development starting with the rapid warming at 14.7 ka.     

Mineral magnetic and geochemical records of late Glacial climatic change from two northwest European carbonate lakes

We present the results of mineral magnetic measurements and geochemical analyses of late Glacial sediments from two marl-precipitating lakes in the Northwest of England. Mineral magnetic assemblages dominated by detrital and/or authigenic ferrimagnetic minerals, and enhanced delivery of metal elements, characterise a lower (Oldest Dryas) and an upper (Younger Dryas) phase of catchment instability, with detrital clay and silt sedimentation. Magnetic mineral assemblages with lower concentrations of finer ferrimagnetic grains characterise the authigenic carbonate sediments (marls). The marls indicate both enhanced lake productivity and catchment stability in response to prevailing warm conditions during the Bølling - Allerød Interstadial. The Bølling - Allerød marl phase contains two short-term, low amplitude shifts characterised by changes in the concentration and the size of ferrimagnetic grains. These shifts may represent the Older Dryas and the Amphi-Atlantic Oscillation, short-lived Northern hemisphere climatic deteriorations. Overall, the results suggest that marl lakes are sensitive indicators of Lateglacial climatic change, and that these changes are readily identifiable through the use of mineral magnetic measurements.     

大地测量观测和相对海平面联合约束的冰川均衡调整模型

利用大地测量和历史相对海平面变化数据,结合地震剪切波层析模型,联合确定了新的末次冰期冰川均衡调整（GIA）模型,其中地幔黏滞度不仅沿径向而且沿横向变化.研究思路是,先尝试性地选择比例系数β,利用与地震剪切波速异常的线性关系,计算地幔黏滞度横向扰动,并与横向均匀的黏滞度参考模型叠加给出3D地幔黏滞度模型;再利用耦合拉普拉斯方程的有限元法算法进行GIA预测;然后,重复该过程,直到预测与观测之间的吻合满意为止.主要结论有：（1）给出了横向非均匀的地幔黏滞度模型（RF3L20(β=0.4)）,发现了黏滞度显著的横向非均匀性和其对GIA预测的显著影响,指出横向非均匀不完全是由热效应引起的,可能还与化学组分等其他因素有关,该模型可用于地幔动力学研究.（2）给出了全球现今多种GIA预测速率,可为板块运动、陆地水储量、海水质量变化和冰川冰雪质量非平衡监测提供重要的改正.     

Glacial isostatic adjustment at the Laurentide ice sheet margin: Models and observations in the Great Lakes region

Glacial Isostatic Adjustment (GIA) modelling in North America relies on relative sea level information which is primarily obtained from areas far away from the uplift region. The lack of accurate geodetic observations in the Great Lakes region, which is located in the transition zone between uplift and subsidence due to the deglaciation of the Laurentide ice sheet, has prevented more detailed studies of this former margin of the ice sheet. Recently, observations of vertical crustal motion from improved GPS network solutions and combined tide gauge and satellite altimetry solutions have become available. This study compares these vertical motion observations with predictions obtained from 70 different GIA models. The ice sheet margin is distinct from the centre and far field of the uplift because the sensitivity of the GIA process towards Earth parameters such as mantle viscosity is very different. Specifically, the margin area is most sensitive to the uppermost mantle viscosity and allows for better constraints of this parameter. The 70 GIA models compared herein have different ice loading histories (ICE-3/4/5G) and Earth parameters including lateral heterogeneities. The root-mean-square differences between the 6 best models and the two sets of observations (tide gauge/altimetry and GPS) are 0.66 and 1.57 mm/yr, respectively. Both sets of independent observations are highly correlated and show a very similar fit to the models, which indicates their consistent quality. Therefore, both data sets can be considered as a means for constraining and assessing the quality of GIA models in the Great Lakes region and the former margin of the Laurentide ice sheet.     

An accurate strength amplification factor for the design of SDOF systems with P–Δ effects

The response of structures subjected to seismic actions is always influenced by P–Δ effects. The importance of this effect is generally modest for structures experiencing an elastic response but often relevant for structures responding well within the inelastic range of behaviour. Seismic codes indicate that P–Δ effects may be counterbalanced through an increase in the structural strength required by a first order analysis. This increase is calculated by means of a strength amplification factor. The expressions suggested in codes for this factor are simplistic and often criticized by researchers. In this paper, the effectiveness of some of the provisions reported in the literature or suggested in seismic codes is evaluated on single degree of freedom systems with different periods of vibration. As suggested by past studies, attention is focused on the influence of the interstorey drift sensitivity coefficient, significant duration of the ground motion, class of the site soil, displacement ductility and equivalent viscous damping ratio of the system. Finally, an accurate expression of the strength amplification factor is proposed. Copyright © 2013 John Wiley & Sons, Ltd.     

西北干旱区石羊河流域末次冰期晚期气候不稳定性记录

通过对我国西北干旱区石羊河流域三角城末次冰期最盛期晚期-晚冰期地层剖面沉积物中有机质碳同位素分析,表明在季风边缘带的沉积地层中较详细地记录了这一时期气候快速颤动,发生千年至百年尺度的冷干-温湿变化,高分辨的有机质碳同位素组成与GRIP氧同位素组成有较好的可比性,表明与全球古气候变化有明显的联系,也反映在末次冰期最盛期与晚冰期过渡期气候温湿,陆地植被比较发育,可能与东亚季风有关。有机质碳同位素这一指标对气候记录较敏感,是重建干旱区高分辨古气候演化模式十分有效的手段,在季风交汇带能灵敏地记录到气候快速变化。