Investigation of vertical distribution and morphology of indigenous organic matter at Sleeping Bear site,Michigan

This study evaluates the nature and origin of particulate organic carbon and organic coatings on aquifer sands upgradient from a fuel spill site near the Sleeping Bear Dunes National Lakeshore in Michigan. The distribution of carbon was found to be highly complex due to the occurrence of high organic carbon horizons, bounded above and below by high carbonate sediments. The organic coatings on the sands were examined using white light and fluorescence microscopy and by scanning electron microscopy. Core samples were analyzed for organic and inorganic carbon, solution pH, humic/fulvic acid ratios, and insoluble organic matter content (that is, humin) as a function of depth from the ground surface. The organic geochemistry of the soil profile at this site was found to be significantly influenced by the carbonates producing a sharp boundary of precipitated organic matter. This boundary was followed by coatings of predominantly fulvic acid salts on mineral grains deeper in the soil column. The coatings extended into the aquifer. The existence of native organic films on sand grains is well documented in the soils literature. The study reported here was greatly aided by this information and provides the framework for future studies concerning the influence of carbon distribution, chemical identity, and morphology on contaminant fate and transport processes.     

Ostracode-based reconstruction from 23,300 to about 20,250 cal yr BP of climate, and paleohydrology of a groundwater-fed pond near St. Louis, Missouri

The water chemistry of a groundwater-fed sinkhole-pond near St. Louis, Missouri, and its associated climate during the last glaciation are reconstructed by comparison with autecological data of modern ostracodes from about 5,500 sites in Canada. A 4.8-m succession of fossiliferous sediment yielded ostracode assemblages that collectively are generally found today in ponds in North America including the species Cyclocypris ampla, C. laevis, Cypridopsis vidua, Candona crogmaniana, C. distincta, and C. ohioensis. Fossils of Picea needles and the ostracode Cyclocypris sharpei imply that best analog sites for the succession are in central to south-central Canada. The pond formed 23,300 ± 400 cal yr BP when a sinkhole became plugged by a clay bed about 1 m thick. By about 20,250 cal yr BP, the pond had desiccated and was buried by loess. The sediment accumulation rate was about 0.18 cm/yr, and each sample interval (6 cm) represents a time slice of 33 years. Data from this record provides the first fairly high resolution proxy record of the glacial paleoclimate of the mid-latitude of North America. The analog data indicate the water in the hydrologically-open spring-fed pond was less than 1 m deep. The paleoclimatic reconstructions imply gradually drier conditions and uniform, cool temperatures. The shallow water depth indicates that the temperature reconstruction is robust with mean annual temperatures (MATs) that ranged between 0.8 and 3.9°C, and mean July temperatures that ranged from 16.8 and 18.1°C. Other estimated climatic parameters include mean annual precipitation (MAP; 430 to 840 mm/yr), and moisture balance (P-E; –111 to 298 mm/yr). Compared to values measured today at St. Louis, the MAP was about 400 mm less, MAT about 10°C cooler, and P-E, about the same. These values are consistent with other published reconstructions based on modern analog analysis of fossil beetles and pollen, and paleothermometry based on amino acid racemization. The total dissolved solids (TDS) progressively increased from about 87 to 431 mg/L. Changes in TDS reflect either the balance between the relative inputs of karst groundwater and overland flow, or changes in the duration of water-rock interaction associated with the groundwater. The postulated long-term 900 ± 200 year cyclicity of growing-season moisture and temperature, attributed to El Niño-Southern Oscillation cycles, is not expressed in the reconstructed hydrologic or climatic data. This is attributed, in part, to the mediating effect on temperature by monothermic groundwater input to this flow-through system.     

Wetter or colder during the Last Glacial Maximum? Revisiting the pluvial lake question in southwestern North America

Well-preserved shorelines in Estancia basin and a relatively simple hydrologic setting have prompted several inquiries into the basin's hydrologic balance for the purpose of estimating regional precipitation during the late Pleistocene. Estimates have ranged from 86% to 150% of modern, the disparity largely the result of assumptions about past temperatures. In this study, we use an array of models for surface-water runoff, groundwater flow, and lake energy balance to examine previously proposed scenarios for late Pleistocene climate. Constraints imposed by geologic evidence of past lake levels indicate that precipitation for the Last Glacial Maximum (LGM) may have doubled relative to modern values during brief episodes of colder and wetter climate and that annual runoff was as much as 15% of annual precipitation during these episodes.     

Cosmogenic nuclide chronology of pre-last glacial maximum moraines at Lago Buenos Aires, 46°S, Argentina

At Lago Buenos Aires, Argentina, ¹⁰Be, ²⁶Al, and ⁴⁰Ar/³⁹Ar ages range from 190,000 to 109,000 yr for two moraines deposited prior to the last glaciation, 23,000–16,000 yr ago. Two approaches, maximum boulder ages assuming no erosion, and the average age of all boulders and an erosion rate of 1.4 mm/10³ yr, both yield a common estimate age of 150,000–140,000 yr for the two moraines. The erosion rate estimate derives from ¹⁰Be and ²⁶Al concentrations in old erratics, deposited on moraines that are >760,000 yr old on the basis of interbedded ⁴⁰Ar/³⁹Ar dated lavas. The new cosmogenic ages indicate that a major glaciation during marine oxygen isotope stage 6 occurred in the mid-latitude Andes. The next five youngest moraines correspond to stage 2. There is no preserved record of a glacial advance during stage 4. The distribution of dated boulders and their ages suggest that at least one major glaciation occurred between 760,000 and >200,000 yr ago. The mid-latitude Patagonian glacial record, which is well preserved because of low erosion rates, indicates that during the last two glacial cycles major glaciations in the southern Andes have been in phase with growth and decay of Northern Hemisphere ice sheets, especially at the 100,000 yr periodicity. Thus, glacial maxima are global in nature and are ultimately paced by small changes in Northern Hemisphere insolation.     

C chronology for ice retreat and inception of Champlain Sea in the St. Lawrence Lowlands, Canada

AMS radiocarbon cross-dating of plant debris and marine shells trapped in a lake basin on Mount St. Hilaire (Québec, Canada) provides a direct assessment of a reservoir effect totaling ca. 1800 ¹⁴C years during the early stage of Champlain Sea. Pollen-based extrapolation of bottommost ages on terrestrial plant macrofossils in sediments of this lake, and of another lake nearby support an estimate of 11,100 ± 100 ¹⁴C yr B.P. for marine invasion in the Central St. Lawrence River Lowlands. Results indicate a 400–1000 years younger regional chronology of ice retreat, now congruent with the one inferred from the New England varve chronology. This is a summary of a longer paper to be published in French.     

Découverte de structures périglaciaires (sand-wedges et composite-wedges) sur le site de stockage de déchets radioactifs de l'Aube (France)

Since 1990, a dense network of subvertical cracks has been observed at the upper part of the Albian sands of the site of radioactive waste storage operated by ANDRA. New studies carried out in 1999 during enlargement of the site of Soulaines and in 2003 on the nearby TFA site highlighted an especially well-developed network of periglacial features that are mainly of the sand-wedge type (subvertical stratified infill). These observations demonstrate the periglacial origin of these cracks, which are mainly superimposed on a dense network of former tectonic extension joints, and that rapidly disappear at the top of the underlying clays. In addition, these observations currently represent the only example of a large sand-wedge network developed during the Last Glacial in northern France. To cite this article: P. Antoine et al., C. R. Geoscience 337 (2005).     

The last British Ice Sheet: A review of the evidence utilised in the compilation of the Glacial Map of Britain

This paper reviews the evidence presently available (as at December 2003) for the compilation of the Glacial Map of Britain (see [Clark C.D., Evans D.J.A., Khatwa A., Bradwell T., Jordan C.J., Marsh S.H., Mitchell W.A., Bateman, M.D. , 2004. Map and GIS database of glacial landforms and features related to the last British Ice Sheet. Boreas 33, 359–375] and http://www.shef.ac.uk/geography/staff/clark_chris/britice.html) in an effort to stimulate further research on the last British Ice Sheet and promote a reconstruction of ice sheet behaviour based on glacial geology and geomorphology. The wide range of evidence that has been scrutinized for inclusion on the glacial map is assessed with respect to the variability of its quality and quantity and the existing controversies in ice sheet reconstructions. Landforms interpreted as being of unequivocal ice-marginal origin (moraines, ice-contact glacifluvial landforms and lateral meltwater channels) and till sheet margins are used in conjunction with available chronological control to locate former glacier and ice-sheet margins throughout the last glacial cycle. Subglacial landforms (drumlins, flutings and eskers) have been used to demarcate former flow patterns within the ice sheet. The compilation of evidence in a regional map is crucial to any future reconstructions of palaeo-ice sheet dynamics and will provide a clearer understanding of ice sheet configuration, ice divide migration and ice thickness and coverage for the British Ice Sheet as it evolved through the last glacial cycle.     

Late Quaternary glacial and climate history of the Pamir Mountains derived from cosmogenic Be exposure ages

Moraines southwest of Lake Yashilkul, Pamir, Tajikistan, were dated using ¹⁰Be exposure ages of boulder surfaces. We found evidence for (1) an extensive glaciation ∼60,000 yr ago; (2) a less extensive glacial advance, which deposited a characteristic hummocky moraine lobe with exposure ages ranging from ∼11,000 to 47,000 yr, probably deposited at or before 47,000 yr ago; and (3) lateral moraines with exposure ages of ∼40,000 yr, 27,000 yr and 19,000 yr, respectively. Increasing aridity in the Pamir is most likely responsible for the progressively limited extent of the glaciers during the Late Pleistocene.     

Allometric development of glacial cirque form: Geological, relief and regional effects on the cirques of Wales

Headward and downward erosion near glacier sources, at rates exceeding fluvial erosion, is important in recent discussions of orogen development and the limits to relief. This relates to a long history of debate on how the form of glacial cirques develops, which can be advanced by relating shape to size in large data sets. For 260 cirques in Wales, this confirms different rates of enlargement in the three dimensions: faster in length than in width, and slower in vertical dimension whether expressed as overall height range, axial height range or wall height. Maximum gradient, plan closure and number of cols increase with overall size. This allometric development applies over different cirque types, regions and rock types. Headwall retreat, often by collapse following glacial erosion at the base, is faster than downward erosion. Welsh cirques form a scale-specific population and, as in other regions, size variables follow Gaussian distributions on a logarithmic scale. As in England, width commonly exceeds length. Vertical dimensions correlate with length more than with width. Cirque form varies with geology, but also with relief as both vary between mountain groups. The main contrast is between larger, better-developed cirques and higher relief on volcanic rocks in the north-west, and smaller, less-developed cirques and lower relief on sedimentary rocks in the south.