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121.
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【研究目的】川滇黔地区铅锌矿成因具有多样性,特别是与峨眉山玄武岩的关系存在较大的争议,本文从前人关注较少的二叠系碳酸盐岩中的铅锌矿入手,研究成矿物质来源。【研究方法】以云南寻甸县太平子铅锌矿为研究对象,运用S、Pb、C、H、O同位素实验数据及流体包裹体测温等方法,对成矿物质来源及成矿流体特征进行探讨。【研究结果】矿石铅同位素组成比较均一,分布集中,206Pb/204Pb、207Pb/204Pb、208Pb/204Pb的变化范围分别为18.543~18.584、15.646~15.694、38.799~38.958,属于正常普通铅,具壳源特征,主要来源于基底岩石,水岩反应可能使赋矿围岩贡献少量的成矿物质。矿石硫化物δ34S变化范围为-13.6‰~-7.3‰,方铅矿的δ34S高于闪锌矿,硫同位素分馏并未达到平衡,生物成因硫酸盐还原作用(BSR)是还原硫的主要来源。热液方解石δ13CV-PDB范围为3.8‰~4.7‰,δ18OV-SMOW范围为12.0‰~16.7‰,相较于滇东北其他重要的铅锌矿床,具有明显的低δD、高δ18Ofluid特点,成矿流体中的水主要来源于岩浆水和有机水的混合,具有中—高温、低盐度特征。【结论】太平子铅锌矿在成矿物质、流体、成矿温度等均与区域上其他典型铅锌矿有较明显差别,具有典型的岩浆-热液成因特点。 相似文献
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盆地形成及成矿与地幔流体间的成因联系 总被引:11,自引:0,他引:11
文中共讨论以下5个问题:(1)盆地起源于幔壳溃变和膨隆,后者是地幔流体(超临界态(>375℃)HACONS流体,简称幔汁)上涌、渗入、交代、富化、致熔的产物。地幔流体造成油气盆地深部的高热流、异常超高压、伊利水云母化、硅化和地层有机碳的加氢成油作用。(2)盆地成矿可分两大阶段,先是沉积时的同生成矿;地层沉积后还有众多的后生成矿。两者组成“盆地矿套”(杜乐天,2002)。成矿无论同生还是后生,其分布均受断裂控制,都和地幔流体活动有关。(3)黑色页岩的实质是碳-硅-泥三元岩系,和热液成矿中的碳酸盐-硅质-泥质蚀变三元完全相当。此类岩系中总是有几十种亲壳亲幔亲气元素的特殊富集。奇异的是,石油、油页岩、沥青及砂岩型铀矿彼此有完全类似的继承性元素特殊富集。此等元素群不可能都是来自盆地之外蚀源区岩体的风化。研究证明,相当多的元素是地幔流体携带上来的。(4)盆地地层中广泛发育由地幔流体衍生的热液作用。(5)盆地实质上是气盆,全盆地排气。许多气田是地幔流体排气形成的。沙漠(原地型)和天然气田的共生很值得注意,两者皆源于地球强烈排气,导致地下和大气增温,过度蒸发,不易降雨,长期干旱而形成沙漠。 相似文献
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Wang Siyuan Xiao Qibing Zeng Jianguo Faculty of Earth Resources China University of Geosciences Wuhan 《中国地质大学学报(英文版)》2001,12(1)
-,The well-known Suichang silvengold field is located inZhejiang Province of SOutheast China. It is the largest silver-gold deposit associated with copper and zinc in the Cathaysianmetallogenic province.There are a series of silver-gold dePOsits in the shear zonesof Proterozoic gneiss terrene, Suichang region. The volcanicapparatus at Mesozoic has complicated rpineralization. Respectively, there are two pieces of understanding on the origin ofore-formigg nuid: (l ) metamorphic fluid (Lia… 相似文献
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Ayşen Davraz M. Tahir Nalbantçılar Simge Varol İsmail Önden 《Chemie der Erde / Geochemistry》2022,82(2):125867
A conceptual model with water samples from ten geothermal fields (?smil, Ilg?n (Çavu?cugöl), Tuzlukçu-Ak?ehir, Seydi?ehir and Kavakköy, Hüyük, Ere?li-Akhüyük, Kad?nhan?, Cihanbeyli, Karap?nar and Bey?ehir) in the province of Konya defined the geothermal system. Carbonates, quartzite and marbles of Paleozoic metamorphics are the reservoir rocks and the heating sources are igneous rock intrusions and geothermal gradient. The variable thermal water (CaMgHCO3, CaSO4, NaSO4, CaHCO3, CaNaHCO3, NaCl and CaNaClHCO3) had EC and temperature between 177.8 and 56,100 μS/cm and between 18.3 and 44 °C, respectively. Ca2+ in geothermal fluids are associated with marble and carbonate rocks and the high chloride shows direct connection with deep geothermal system, and prolonged contact with evaporite rocks. Sulphate originates from dissolution of and oxidation of sulphate and sulphur-bearing minerals. The high As, B, F and Mn concentration in some thermal water samples were determined as 85 μg/l, 148.56 mg/l, 3.01 mg/l and 208.13 mg/l, respectively. Reservoir temperatures computed by Na/K geothermometers were between 85.37–158.89 °C for Ak?ehir thermal waters and 58.78–90.45 °C for Ere?li thermal waters. The maximum reservoir temperature of other geothermal waters was 75 °C by the silica geothermometers. 相似文献
129.
海洋热流数据是开展海洋地球动力学研究和油气资源评价的基础数据.为深入认识琼东南盆地的地热特征,本文首先利用耦合沉积作用与岩石圈张裂过程的数值模型分析了张裂型盆地主要地热参数的垂向变化特征;并通过钻孔资料的详细分析,获得了琼东南盆地44口钻孔的热流数据;结合海底地热探针获取的热流数据,对琼东南盆地地热特征及其主要影响因素进行了简要分析.结果表明:沉积作用的热披覆效应对表层热流有较明显的抑制作用,由于沉积物生热效应与披覆效应的共同作用,同一钻孔处海底表层热流与钻孔深度3000~4000 m处热流或与海底间的平均热流差异很小,可以一起用于分析琼东南盆地的热流分布特征;莺歌海组、乐东组热导率随深度变化小于黄流组及其下地层热导率的变化,钻孔沉积层平均热导率约为1.7 W·(m·K)-1,钻孔地层生热率一般低于2.5 μW·m-3,平均生热率为1.34 μW·m-3,平均地温梯度主要介于30~45 ℃/km,热流介于50~99 mW·m-2,陆架区热流主要集中于60~70 mW·m-2,深水区钻孔具有较高的地温梯度和热流值;从北部陆架与上陆坡区往中央坳陷带,热流值从50~70 mW·m-2,增高为65~85 mW·m-2,并且往东有升高趋势,在盆地东部宝岛凹陷、长昌凹陷与西沙海槽北部斜坡带构成一条热流值高于85 mW·m-2的高热流带.进一步分析认为,琼东南盆地现今热流分布特征是深部热异常、强烈减薄岩石圈的裂后冷却作用、晚期岩浆热事件、地壳与沉积层的生热贡献以及沉积作用的热披覆效应等多种主要因素综合作用的结果. 相似文献
130.
The Ernest Henry Cu–Au deposit was formed within a zoned, post-peak metamorphic hydrothermal system that overprinted metamorphosed dacite, andesite and diorite (ca 1740–1660 Ma). The Ernest Henry hydrothermal system was formed by two cycles of sodic and potassic alteration where biotite–magnetite alteration produced in the first cycle formed ca 1514±24 Ma, whereas paragenetically later Na–Ca veining formed ca 1529 +11/−8 Ma. These new U–Pbtitanite age dates support textural evidence for incursion of hydrothermal fluids after the metamorphic peak, and overlap with earlier estimates for the timing of Cu–Au mineralization (ca 1540–1500 Ma). A distal to proximal potassic alteration zone correlates with a large (up to 1.5 km) K–Fe–Mn–Ba enriched alteration zone that overprints earlier sodic alteration. Mass balance analysis indicates that K–Fe–Mn–Ba alteration—largely produced during pre-ore biotite- and magnetite-rich alteration—is associated with K–Rb–Cl–Ba–Fe–Mn and As enrichment and Na, Ca and Sr depletion. The aforementioned chemical exchange almost precisely counterbalances the mass changes associated with regional Na–Ca alteration. This initial transition from sodic to potassic alteration may have been formed during the evolution of a single fluid that evolved via alkali exchange during progressive fluid-rock interaction. Cu–Au ore, dominated by co-precipitated magnetite, minor specular hematite, and chalcopyrite as breccia matrix, forms a pipe-like body at the core of a proximal alteration zone dominated by K-feldspar alteration. Both the core and K-feldspar alteration overprint Na–Ca alteration and biotite–magnetite (K–Fe) alteration. Ore was associated with the concentration of a diverse range of elements (e.g. Cu, Au, Fe, Mo, U, Sb, W, Sn, Bi, Ag, F, REE, K, S, As, Co, Ba and Ca). Mineralization also involved the deposition of significant barite, K(–Ba)–feldspar, calcite, fluorite and complexly zoned pyrite. The complexly zoned pyrite and variable K–(Ba)–feldspar versus barite associations are interpreted to indicate fluctuating sulphur and/or barium supply. Together with the alteration zonation geochemistry and overprinting criteria, these data are interpreted to indicate that Cu–Au mineralization occurred as a result of fluid mixing during dilation and brecciation, in the location of the most intense initial potassic alteration. A link between early alteration (Na–Ca and K–Fe) and the later K-feldspathization and the Cu–Au ore is possible. However, the ore-related enrichments in particular elements (especially Ba, Mn, As, Mo, Ag, U, Sb and Bi) are so extreme compared with earlier alteration that another fluid, possibly magmatic in origin, contributed the diverse element suite geochemically independently of the earlier stages. Structural focussing of successive stages produced the distinctive alteration zoning, providing a basis both for exploration for similar deposits, and for an understanding of ore genesis. 相似文献