南海中央海盆之东部次海盆后扩张期地层特征与影响因素

海底扩张形成的边缘海盆构造演化可划分为前扩张期、同扩张期与后扩张期等阶段。南海中央海盆巨厚的沉积地层大部分是扩张结束之后形成的,尤以东部次海盆地层厚度为最大。因受到不同因素的影响,在该次海盆不同的区域后扩张期发育的地层特征差别较大。这些现象反映海底扩张结束之后所发育的厚层地层中蕴含了大量南海构造演化的信息,因此深入分析该次海盆后扩张期的地层特征与影响因素是南海构造演化研究中不容忽略的环节。利用若干大洋钻孔年代地层资料,在过井剖面上进行合成地震记录标定、划分层序地层并确定其年代属性,并以此为依据分析讨论了本区的地层特征和相关的影响因素。结果表明,东部次海盆北部持续均衡的基底沉降和充足的陆缘物质形成厚度稳定的地层沉积;东部以微板块向马尼拉海沟俯冲为主要影响因素,使不同年代的地层各具特征;中部和西部岩浆活动是主要的影响因素,形成以火山碎屑物质为主的地层沉积;南部因当时的陆坡沉积环境和浊流活动的影响形成具有沉积物波特征的地层沉积。     

Mineralogical and geochemical alteration of Hitura sulphide mine tailings with emphasis on nickel mobility and retention

Weathering of Hitura (W Finland) nickel sulphide mine tailings and release of heavy metals into pore water was studied with mineralogical (optical and electron microscopy, X-ray diffraction) and geochemical methods (selective extractions). Tailings were composed largely of serpentine, micas and amphiboles with only minor carbonates and sulphides. Sulphides, especially pyrrhotite, have oxidized intensively in the shallow tailings in 10–15 years, but a majority of the tailings have remained unchanged. Oxidation has resulted in depletion of carbonates, slightly decreased pH, and heavy metal (Ni, Zn) release in pore water as well as in the precipitation of secondary Fe precipitates. Nevertheless, in the middle of the tailings area, where the oxidation front moves primarily downward, released heavy metals have been adsorbed and immobilized with these precipitates deeper in the oxidation zone. In contrast to what was seen in pore water pH, but in accordance with static tests of the previous studies, the neutralisation potential ratio (NPR) calculated based on the mineralogical composition and the total sulphur content suggested that tailings are ‘not potentially acid mine drainage (AMD) generating’. However, the calculated buffering capacity of the tailings resulted largely from the abundant serpentine because of the low carbonate content. Despite its slow weathering rate, serpentine may buffer the acidity to some extent through ion exchange processes in fine ground tailings. Nevertheless, in practice, acid production capacity of the tailings depends primarily on the balance between Ca–Mg carbonates and iron sulphides. NPR calculation based on carbonate and sulphur contents suggested, that the Hitura tailings are ‘likely AMD generating’. The study shows that sulphide oxidation can be significant in mobilisation of heavy metals even in apparently non-acid producing, low sulphide tailings. Therefore, prevention of oxygen diffusion into tailings is also essential in this type of sulphide tailings.     

黄海南部黄鲫(Setipinna taty)资源利用分析

以2005-2006年江苏省帆式张网渔获资料为基础,分析研究了黄海南部黄鲫资源的时空分布、群体组成结构以及产卵群体生物学特征.结果表明,黄海南部黄鲫主要利用渔期为春季3-5月、冬季1月或12月.春季高产渔区主要分布在大沙渔场的西南部和吕泗渔场的东部,冬季和秋季高产渔区相对靠近或较春季高产渔区偏东.黄鲫高产渔区的分布无明显季节变化特征.黄鲫渔获群体主要由体长70-110mm、体重0-15g的个体组成,产卵群体的平均体重范围为8.7-12.0g.与1981-2000年的研究结果相比,黄鲫个体小型化越趋显著,当前利用个体偏小.     

A novel method to estimate mineral compositions of mudrocks: A case study for the Canadian unconventional petroleum systems

The mineral composition of mudrocks is an essential attribute in controlling the reservoir quality of unconventional petroleum systems. The present study introduces a semi-quantitative method to estimate mineral phases of mudrocks in various Canadian unconventional hydrocarbon systems using total elemental analysis (inductively coupled plasma-mass spectrometry (ICP-MS)) and Rock-Eval data (total organic carbon (TOC) and mineral carbon (MinC)).This method involves statistical analysis based on a sound knowledge of hydrocarbon source rock inorganic geochemistry. The workflow can be divided into four steps: (i) converting major elements (Si, Al, Fe, K, Na, Ca, Mg, Ti, and P) to their oxides, (ii) inferring modes of occurrence of elements using statistical analysis of geochemical data (major elements, TOC, and MinC), (iii) identifying the mineral types (oxide, aluminosilicates, carbonates, sulfide, and phosphate) according to elemental occurrences and calculating mineral phase concentrations, and (iv) verifying the results by comparing to XRD data on selected samples. The results, especially for brittle minerals such as quartz, carbonates (e.g. calcite, dolomite, and ankerite), and pyrite, show that the estimated mineral compositions correspond closely and consistently with measured mineralogy obtained from XRD. This method takes advantage of bulk geochemical data already available for hydrocarbon potential and chemostratigraphic studies, without devoting additional samples and cost for XRD analysis.     

Mineralogical characteristics of polymetallic sulfides from the Deyin-1 hydrothermal field near 15°S,southern Mid-Atlantic Ridge

A seafloor hydrothermal field, named Deyin-1 later, near 15°S southern Mid-Atlantic Ridge(SMAR) was newly found during the 22 nd cruise carried out by the China Ocean Mineral Resources Research Development Association(COMRA). Sulfide samples were collected at three stations from the hydrothermal field during the26 th cruise in 2012. In this paper, mineralogical characteristics of the sulfides were analyzed with optical microscope, X-ray diffractometer, scanning electron microscope and electron microprobe to study the crystallization sequence of minerals and the process of hydrothermal mineralization. According to the difference of the ore-forming metal elements, the sulfide samples can be divided into three types:(1) the Ferich sulfide, which contains mainly pyrite and chalcopyrite;(2) the Fe-Cu-rich sulfide consisting predominantly of pyrite, chalcopyrite and isocubanite, with lesser amount of sphalerite, marmatite and pyrrhotine; and(3) the Fe-Zn-rich sulfide dominated by pyrite, sphalerite and marmatite, with variable amounts of chalcopyrite, isocubanite, pyrrhotine, marcasite, galena and gratonite. Mineral precipitations in these sulfides are in the sequence of chalcopyrite(isocubanite and possible coarse pyrite), fine pyrite,sphalerite(marmatite), galena, gratonite and then the minerals out of the dissolution. Two morphologically distinct generations(Py-I and Py-II) of pyrite are identified in each of the samples; inclusions of marmatite tend to exist in the coarse pyrite crystals(Py-I). Sphalerite in the Fe-Zn-rich sulfide is characterized by a"chalcopyrite disease" phenomenon. Mineral paragenetic relationships and a wide range of chemical compositions suggest that the environment of hydrothermal mineralization was largely changing. By comparison, the Fe-rich sulfide was formed in a relatively stable environment with a high temperature, but the conditions for the formation of the Fe-Cu-rich sulfide were variable. The Fe-Zn-rich sulfide was precipitated during the hydrothermal venting at relatively low temperature.     

鄂尔多斯盆地北部塔巴庙地区下石盒子组盒3段储层特征及有利区块预测

根据野外剖面、钻井岩芯和测井等资料,系统地对塔巴庙地区下石盒子组盒3段储集砂体的岩石学特征、孔隙类型、成岩作用以及物性进行了详细的分析。研究表明,储集层的成分和结构成熟度低;主要孔隙类型有粒间孔、粒内溶孔、晶间溶孔、铸模孔和粒缘缝;孔隙度为0.7%~18.69%,平均值为7.82%;渗透率为0.008×10^-3μm²~23.01×10^-3μm²,平均值为1.111×10^-3μm²,属于物性中-偏低的微孔-溶孔型组合型储集岩。影响储集层的主控因素包括:(1)河道控制了优质储层的分布范围和规模;(2)成岩期早期环边绿泥石胶结、溶蚀等建设性成岩作用是形成储层的基础;(3)成岩相扩大了储层的分布范围,改善了储层的物性。在上述研究的基础上,结合储集砂体的沉积微相特征、物性平面展布特征、储集砂体成岩相特征,在研究区内圈定了Ⅱ、Ⅲ两类有利勘探区块,为研究区下一步的勘探、开发提供了科学依据。     

Distribution Characteristics of Effective Source Rocks and Their Control on Hydrocarbon Accumulation: A Case Study from the Dongying Sag, Eastern China

The exploration conducted in the Bohai Bay basin, eastern China has demonstrated that the abundant petroleum resources have close affinities to the hydrocarbon kitchen with rich organic matter. A number of oil-generating associations with various characteristics of organic geochemistry and assemblages of multiple reservoir facies are developed due to the multi-center sedimentation, multi-source supply and multi-cycle evolution of filling, which have resulted in the formation of multiple oil and gas accumulation zones of various layers and trap styles. Among them the Paleogene Shahejie Formation is the most important hydrocarbon accumulation combination in the Dongying sag. Heretofore, its proved reserve has reached nearly 1.8×109t, which accounts for more than 90% of the total proved reserves of the Dongying sag. Based on previous studies, more than 600 source rock samples and 186 crude oil samples of the Shahejie Formation, collected from 30 oilfields, have been treated with organic geochemical testing     

康滇地轴南段江川盆地澄江砂岩微量元素地球化学特征及其地质意义

主要阐述了江川盆地澄江砂岩（Zac）的紫色砂岩与灰色砂岩、铀矿化蚀变岩微量元素及稀土元素地球化学特征。通过判别与对比,澄江砂岩（Zac）物质来源于活动大陆边缘,虽然铀矿化主要分布在灰色砂岩中,但灰色砂岩并不是控制铀矿化的主要因素,在铀矿化时有深部流体物质的影响。微量元素地球化学特征对探索该区砂岩型铀矿化以及寻找不整合面型铀矿床提供了可能,具有重要的指示意义。     

西湖凹陷平北地区泥岩地球化学特征及其地质意义

为了研究西湖凹陷平北地区泥岩微量及稀土元素的分布特征及其地质意义,采用ICP—MS对研究区25个泥岩样品进行了稀土元素和微量元素分析,研究表明：（1）研究区泥岩稀土元素主要来自陆源碎屑矿物,源岩主要为沉积岩及碱性玄武岩;（2）始新世末构造运动揭示的构造沉积界线在研究区留下了证据,微量元素比值、稀土总量等参数在此界面上存在明显的突变,界线十分明显,并且此界线亦是研究区平湖组与花港组的沉积界面,界面以下以三角洲沉积为主,界面之上主要为河流相沉积,这一沉积相转换面在研究区P1井尤为明显;（3）利用Sr／Cu比值推测平北地区始新世中晚期．早渐新世经历了较为明显的气候变化,总体上有逐渐变温湿趋势,并且研究区北部要温湿于南部。     

吉林海沟金矿地质特征及应力场分析

海沟金矿是大型石英脉型金矿床,矿体严格受NE向断裂构造控制,成矿时代为晚侏罗世-早白垩世.矿石中金属矿物以黄铁矿、自然金、方铅矿和黄铜矿为主.28号主矿脉中,Au平均品位20.59×10-6.成矿物质来自地层和岩体.对构造应力场研究表明,矿区有3期构造应力场,分别是早期近S-N向挤压、中期NW向挤压和晚期NE向挤压.成矿期应力场最大主压应力方向为NE向.