大兴安岭成矿带北段区域地球化学背景与成矿带划分

大兴安岭成矿带是中国最重要的有色金属成矿带之一,资源潜力巨大,其北段是中国除新疆以外唯一存在地质空白的地区,矿产勘查与研究程度低。笔者通过对其区域地球化学场特征、大中型内生金属矿床分布规律、区域控矿地质条件的研究,初步认为本区优势内生金属矿产是钼矿、银铅锌矿,其次是金矿和铜矿,潜力矿种是铀矿;以德尔布干、鄂伦春-伊尔施两条深断裂为界,其两侧地球化学背景、成矿环境、矿种及成矿类型差异很大,并将大兴安岭成矿带北段划分为：德尔布干Ⅲ1、大兴安岭西坡Ⅲ2、嫩江Ⅲ3等3个Ⅲ级成矿亚带10个Ⅳ级成矿区。     

http://www.sciencedirect.com/science/article/pii/S1674987111000855

During the last decades, several integrated studies of Tethyan Jurassic/Cretaceous boundary sections from different countries were published with the objective to indicate problems for the selection of biological, chemical or physical markers suitable for identification of the Jurassic/Cretaceous boundary e the only system boundary within the Phanerozoic still not fixed by GSSP. Drawing the boundary between the Jurassic and Cretaceous systems is a matter of global scale discussions. The problem of proposing possible J/K boundary stratotypes results from lack of a global index fossils, global sea level drop, paleogeographic changes causing development of isolated facies areas, as well as from the effect of Late Cimmerian Orogeny. This contribution summarizes and comments data on J/K boundary interval obtained from several important Tethyan sections and shows still existing problems and discrepancies in its determination.     

北山泥盆纪碰撞造山火山－磨拉石地质构造及地球化学特征

本区早泥盆世旱山微大陆与塔里木板块的北山地体间发生对接，原洋区变为残留滨浅海区。中泥盆世该区形成中央断块山，相应南带的断陷山间洼地内形成陆相磨拉石堆积，北带与南蒙古洋毗邻，形成陆缘滨浅海火山－磨拉石沉积。经计算，中带造山隆起侵蚀速率为０．１５４ｍｍ／ａ。晚泥盆世火山岩显示弱碱性和深熔岩浆喷溢特点，表明陆壳演化尚未达到完全稳定的阶段。     

白龙江中上游地区金矿控矿因素及成矿模式探讨

白龙江中上游地区微细浸染型金矿,是受地层和构造双重控制的金矿床。在阐述矿床空间分布规律、控矿因素、区域矿化和地球化学特征等基础上,初步建立了地质地球化学成矿模式。     

水系沉积物地球化学测量在内蒙古凉城地区找矿应用

凉城地区1∶5万水系沉积物地球化学测量中,发现并圈定了43个以Au、Ag、Pb、Cu、Zn等为特征组合元素的综合异常,优选5处找矿远景区,经过异常查证和地质评价,优选找矿靶区,发现多处银、金、铅多金属矿（化）点及有进一步工作价值的矿产地,其中有3处被列为内蒙古地质勘查基金项目,获得了较好的找矿效果。     

天水第三系泥岩地球化学特性研究——以梁家山隧道开挖岩样为例

天水地区第三系地层属于西秦岭甘肃群,梁家山隧道洞身穿越天水盆地第三系泥岩,为确定隧道围岩的地质特性,进行了泥岩样品的地球化学成分与矿物成分测试。将梁家山隧道泥岩的测试结果与天水秦安县下山剖面泥岩的结果进行对比分析和相关分析。结果表明:二者之间存在较好的相关性,能够描述梁家山隧道泥岩的地层岩性、区域地质背景及其演化等工程地质特性,为进一步研究天水盆地的物质组成、风化特征、沉积环境和构造背景提供依据。同时也为利用隧道工程修建研究相关地学问题提供范例和基础数据。     

非负矩阵分解基向量分析及其在矿产预测中的应用

针对矿产预测数据具有复杂性以及矿质异常信息具有稀疏性的问题,基于非负矩阵分解的非负性和降维的特点,结合稀疏性,提出一种基于NMF基向量分析的矿产预测数据处理方法,并对基向量和原变量以及基向量之间的关系进行分析。广东新寮岽铜多金属矿区数据实验结果表明,NMF方法在不同特征值和相似稀疏度的条件下的基向量形态基本稳定,在保留找矿信息的同时可有效地实现对矿产预测数据的稀疏化。NMF方法对于矿产预测具有重要的实际意义。     

Very high-frequency and seasonal cave atmosphere PCO2 variability: Implications for stalagmite growth and oxygen isotope-based paleoclimate records

Cave air P_CO2 at two Irish sites varied dramatically on daily to seasonal timescales, potentially affecting the timing of calcite deposition and consequently climate proxy records derived from stalagmites collected at the same sites. Temperature-dependent biochemical processes in the soil control CO₂ production, resulting in high summer P_CO2 values and low winter values at both sites. Large Large-amplitude, high-frequency variations superimposed on this seasonal cycle reflect cave air circulation. Here we model stalagmite growth rates, which are controlled partly by CO₂ degassing rates from drip water, by considering both the seasonal and high-frequency cave air P_CO2 variations. Modeled hourly growth rates for stalagmite CC-Bil from Crag Cave in SW Ireland reach maxima in late December (0.063 μm h^− 1) and minima in late June/early July (0.033 μm h^− 1). For well-mixed ‘diffuse flow’ cave drips such as those that feed CC-Bil, high summer cave air P_CO2 depresses summer calcite deposition, while low winter P_CO2 promotes degassing and enhances deposition rates. In stalagmites fed by well-mixed drips lacking seasonal variations in δ¹⁸O, integrated annual stalagmite calcite δ¹⁸O is unaffected; however, seasonality in cave air P_CO2 may influence non-conservative geochemical climate proxies (e.g., δ¹³C, Sr/Ca). Stalagmites fed by ‘seasonal’ drips whose hydrochemical properties vary in response to seasonality may have higher growth rates in summer because soil air P_CO2 may increase relative to cave air P_CO2 due to higher soil temperatures. This in turn may bias stalagmite calcite δ¹⁸O records towards isotopically heavier summer drip water δ¹⁸O values, resulting in elevated calcite δ¹⁸O values compared to the ‘equilibrium’ values predicted by calcite–water isotope fractionation equations. Interpretations of stalagmite-based paleoclimate proxies should therefore consider the consequences of cave air P_CO2 variability and the resulting intra-annual variability in calcite deposition rates.     

Reactive transport in unsaturated soil: Comprehensive modelling of the dynamic spatial and temporal mass balance of water and chemical components

By implementing the moisture-based form of Richards’ equation into the geochemical modelling framework PHREEQC, a generic tool for the simulation of one-dimensional flow and solute transport in the vadose zone undergoing complex geochemical reactions was developed. A second-order, cell-centred, explicit finite difference scheme was employed for the numerical solution of the partial differential equations of flow and transport. In this scheme, the charge-balanced soil solution is treated as an assembly of elements, where changes in water and solute contents result from fluxes of elements across cell boundaries. Therefore, water flow is considered in terms of oxygen and hydrogen transport.     

Geochemical changes across the Ordovician-Silurian transition on the Yangtze Platform,South China

The trace element and rare earth element (REE) variations across the Ordovician-Silurian succession are presented from two outcrop sections on the Yangtze Platform: the Nanbazi section, Guizhou Province, deposited in a shallow platform interior setting, and the Wangjiawan section, Hubei Province, deposited in a deeper basinal environment. Geochemical analysis of closely spaced samples through three intervals, the Wufeng, Guanyinqiao and Longmaxi, revealed vast palaeoceanographic changes. Some geochemical proxies, including Th/U, Ni/Co, V/Cr, and V/(V+Ni) ratios, together with sedimentary facies and biotic data, indicate that an anoxic condition on the most of the Yangtze Platform during the Wufeng and Longmaxi intervals, but an oxic condition during the Guanyinqiao time. The shift of the anoxic to the oxic environment during the Guanyinqiao time coincided with a global sea-level lowstand, in parallel with the global glaciation. The Longmaxian anoxic environment was a result of a global sea-level rise, which may be synchronized with a mainly catastrophic event in the latest Ordovician. Although the two sections generally show similar variation patterns of trace and REE concentrations and some element ratios, a minor difference occurs between the Wangjiawan and Nanbazi sections, likely reflecting a difference in depositional setting during the accumulation. Such an oceanic oxygen-level variation may add a useful constraint to the current arguments on the cause and consequence of the latest Ordovician mass extinction. Supported by National Basic Research Program of China (Grant No. 2005CB422101)