广东中山晚更新世最早海侵层与水动型海平面变化

中山市珠海格力商业大厦场址钻孔表明，距今（４５１２０±９１０）ａ海水已经侵入珠江三角洲地区，当时海平面约在－３４．７ｍ。沉积剖面及其比较研究表明，场区从晚更新世海侵以来是连续的滨海相沉积；场区还是晚更新世海侵以来差异构造运动显著的珠江三角洲（乃至东南沿海）地区地壳的一块“稳定小岛”。其晚更新世以来的滨海相沉积反映了渐进上升的实际水动型海平面变化     

First-Order Chemistry in the Surface-Flux Layer

We have discussed the behavior of a non-conserved scalar in the stationary, horizontally homogeneous, neutral surface-flux layer and, on the basis of conventional second-order closure, derived analytic expressions for flux and for mean concentration of a gas, subjected to a first-order removal process. The analytic flux solution showed a clear deviation from the constant flux, characterizing a conserved scalar in the surface-flux layer. It decreases with height and is reduced by an order of magnitude of the surface flux at a height equal to about the typical mean distance a molecule can travel before destruction. The predicted mean concentration profile, however, shows only a small deviation from the logarithmic behavior of a conserved scalar. The solution is consistent with assuming a flux-gradient relationship with a turbulent diffusivity corrected by the Damköhler ratio, the ratio of a characteristic turbulent time scale and the scalar mean lifetime. We show that if we use only first-order closure and neglect the effect of the Damköhler ratio on the turbulent diffusivity we obtain another analytic solution for the profiles of the flux and the mean concentration which, from an experimental point of view, is indistinguishable from the first analytic solution. We have discussed two cases where the model should apply, namely NO which, by night, is irreversibly destroyed by interaction with mainly O₃ and the radioactive ²²⁰Rn. Only in the last case was it possible to find data to shed light on the validity of our predictions. The agreement seemed such that a falsification of our model was impossible. It is shown how the model can be used to predict the surface flux of ²²⁰Rn from measured concentration profiles.     

AN EVALUATION OF SEVERAL TURBULENCE SCHEMES FOR THE PREDICTION OF MEAN AND TURBULENT FIELDS IN COMPLEX TERRAIN

A prognostic three-dimensional mesoscale model has been developed andused in one- and two-dimensional modes to evaluate ten local turbulenceclosure schemes. The schemes ranged from first-order to the two-equationprognostic schemes. Predictions by the models were compared for aone-dimensional convective boundary layer using mixed layer scaling andmeasurements to interpret the results. Two-dimensional simulations were alsoperformed for a sea-breeze flow and for flow over a hill. The results showedthat for all of the models considered, minor differences were produced in themean meteorological fields and in the vertical scalar fluxes, but majordifferences were apparent in the velocity variances and dissipation rate.Predicted tracer concentrations were very sensitive to the turbulence modelformulation for dispersion from a point source in the convective boundarylayer, particularly for the prediction of maximum concentrations. Predictedtracer concentrations from a surface volume source for the two-dimensionalsimulations were similar for all models, although the degree of mixing in themorning growth period produced some differences. Generally, good results forthe mean meteorological fields can be obtained with first-order schemes, evenif they underpredict the magnitude of turbulence in the convective boundarylayer, and reasonable tracer concentrations can also be obtained with thesemodels provided near-source effects are not important. The two-equationprognostic models performed best for the prediction of turbulence in theconvective boundary layer.     

On the Spatial Distribution and Seasonal Variation of Lower-Troposphere Ozone over Europe

Surface ozone data from 25 Europeanlow-altitude sites and mountain sites located between79°N and 28°N were studied. The analysiscovered the time period March 1989–February 1993.Average summer and winter O₃ concentrations inthe boundary layer over the continent gave rise togradients that were strongest in the north-west tosouth-east direction and west-east direction, respectively. WintertimeO₃ ranged from 19 to 27 ppbover the continent, compared to about 32 ppb at thewestern border, while for summer the continentalO₃ values ranged between 39 and 56 ppb and theoceanic mixing ratios were around 37 ppb. In the lowerfree troposphere average wintertime O₃ mixingratios were around 38 ppb, with only an 8 ppbdifference between 28°N and 79°N. For summerthe average O₃ levels decreased from about 55 ppbover Central Europe to 32 ppb at 79°N. Inaddition, O₃ and O_x(= O₃ + NO₂)in polluted and clean air were compared. Theamplitudes of the seasonal ozone variations increasedin the north-west to south-east direction, while thetime of the annual maximum was shifted from spring (atthe northerly sites) to late summer (at sites inAustria and Hungary), which reflected the contributionof photochemical ozone production in the lower partsof the troposphere.     

热液中二氧化硅与成矿元素锡络合作用的实验标定

热液中二氧化硅与成矿元素锡络合作用的实验标定＊樊文苓陈紫新王声远田弋夫（中国科学院矿床地球化学开放研究实验室，贵阳５５０００２）关键词锡石溶解度二氧化硅的络合作用迁移形式前人对锡在流体中迁移形式的实验研究和热力学计算表明，锡（Ⅱ）的多种氯络合物是高温...     

CLIMATIC RECORDS FROM ANNUAL LAYERS AND STABLE ISOTOPES OF A STALAGMITE IN BEIJING OVER THE LAST 2300 YEARS

Ｉ.ＩｎｔｒｏｄｕｃｔｉｏｎＳｔａｌａｇｍｉｔｅｓｈａｖｅｂｅｅｎａｐｐｌｉｅｄｔｏｕｓｅａｓｈｉｇｈｒｅｓｏｌｕｔｉｏｎｐａｌｅｏｃｌｉｍａｔｉｃｉｎｄｉｃａｔｏｒｓｓｉｎｃｅｔｈｅａｎｎｕａｌｇｒｏｗｔｈｂａｎｄｉｎｇｗａｓｒｅｃｏｇｎｉｚｅｄｉｎｓｔａｌａｇｍｉｔｅｓ[1,2].Ａｎｎｕａｌｇｒｏｗｔｈｂａｎｄｉｎｇｃａｎｂｅｍａｎｉｆｅｓｔｅｄｉｎｓｅｖｅｒａｌｍａｎｎｅｒｓｄｅｆｉｎｅｄｂｙ1)ａｌｔｅｒｎａｔｉｎｇｆｌｕｏｒｅｓｃｅｎｔａｎｄｎｏｎ-ｆｌｕｏｒｅｓｃｅｎｔｃａｌｃｉｔｅ[3,4];2)…     

天山地震活动区的深部构造特征

以地壳介质的Ｐ波速度分布和导电性为基础，描述了天山地区几个主要地震活动区域深部构造特征，地震大都发生在地壳内不同速度块体之间的过渡带附近；沿着天山的南缘和毗邻塔里木盆地的西昆仑、阿尔金等山前地带，壳内高导层由北向南、由东向西逐渐加深并增厚，它们与所在地区震源深度的分相相吻合。这种不稳定的地壳结构有长期受力情况下非常容易发生形变甚至破裂而引发地震。     

四川呷村黑矿型矿床硅质岩的硅、氧同位素组成及其与现代海底硅质烟囱比较研究

本文首次报道了川西呷村黑矿型矿床硅质岩的硅、氧同位素组成,其δ~(18)O为12.8‰-18.3‰纵,形成温度约99-120℃,δ~(30)Si为0.0‰-1.5‰,与Mariana和GalaPagos热液硅质烟囱的δ~(30)Si值范围基本相当,揭示两者具相似的形成机制。硅质岩和硅质烟囱δ~(30)Si最大值与相伴火山岩δ~(30)Si值一致,反映硅质来自被热液淋滤交代的火山岩系。根据SiO_2溶解度-温度关系提出,来自海底之下1-2km处的水-岩反应带、温度高于320℃的初始流体,通过绝热上升或传导冷     

大陆层控构造论盆－山系与造山带成因及演化新模式

大陆构造以受中地壳塑性层控制的盆－山系和冲叠造山带厚皮构造为主要构造类型，而与中生代以来才出现的受软流层控制的大洋岩石圈板块构造截然不同。由上地壳正断层上盘断陷盆地和下盘断隆山所组成的盆－山系，与地球自转速度逐渐变慢派生不同性质水平力和重力的共同作用有关。当地球自转速度突然变化时，将派生强烈的侧压力，使升降幅度较大、具有侧向应变空间的断陷盆地与断隆山之间的上地壳发生冲叠运动，盆－山系由此演变成冲叠造山带。后者对前者存在着严格的继承关系，服从于“升降－冲叠律”。中生代以来的盆－山系和冲叠造山带有的是板块活动产物     

气相色谱和薄层色谱法在形态分析中的应用

评述了气相色谱和薄层色谱法用于氯、溴、碘、硫、硒、碲、铬、氮、磷、砷、钒、碳、锡、铅、铁和汞１６种元素的不同形态分析的进展。这些形态包括不同价态、有机态、无机态、阳离子和阴离子态等。由于气相色谱和薄层色谱法都具有分离和检测两种功能结合的特点，因此它们是用于元素形态分析的有效和方便的方法。引用１９８０～１９９４年文献９２篇