Genesis and evolution of hydrocarbons entrapped in the fluorite deposit of Koh-i-Maran, (North Kirthar Range, Pakistan)

The exceptional development of coeval hydrocarbon and aqueous fluid inclusions (FI) in fluorite from the MVT-type ore deposit of Koh-i-Maran, Baluchistan (North Kirthar range, Pakistan), provides samples which are representative of the ore-forming fluid and which support the hypothesis of petroleum migration in the province. Primary brines at 125°C (10 wt% equ. NaCl) and secondary CH₄-rich brines at 135°C (7 wt% equ. NaCl), are recognised to be associated with oil migration in the fluid inclusions. They support the model of a per ascensum MVT (Mississippi Valley Type) stratabound hydrothermal deposit. A pressure–temperature path of 120–125°C to 165–200 bars is calculated from microthermometric data and PVT modelling of hydrocarbon FI using the modified Peng–Robinson Equation of State (IFP software) from primary cogenetic inclusions (oil and brines).The composition of gas and oil fractions is obtained by a combination of Synchrotron FTIR microanalysis and gas chromatography performed on individual fluid inclusions. The oil entrapped as a coeval primary fluid phase is a light aliphatic normal oil in the range C₈–C₃₅ with a high CO₂ content. The brown solid phase found systematically in the oil is probably asphaltene resulting from precipitation after trapping of the heavy fraction, which commonly occurs by decreasing pressure and temperature and\or by CO₂ injection. Later CH₄-rich brine influx probably modified part of the oil in the primary fluid inclusions because degraded oil is observed within such inclusions. Biomarkers obtained by GC-MS analysis indicate a terpane distribution quite similar to the nearest oil seepage in the Gokurt area. This result and the high CO₂ content of organic fluid inclusions indicate a restricted/confined sedimentary environment for the source rock, which could correspond to the Eocene Carbonate formation with type-II organic matter. A possible additional input of gas from the Sambar formation is suggested as feasible. The link between the fluid inclusion data and the geodynamic evolution lead us to propose a circulation of basinal fluids driven mainly by the fault system during dewatering in the foredeep. In Pakistan, they are coeval to major compressional NW–SE Oligocene episode in the thrust belt. The origin of the fluorine may be found in the basin sediments as well as near the basement. The brines originated in salt structures recognized in eocambrian at the decollement level, the source rock was already mature.     

大兴安岭地区内生铜矿床的成因类型、成矿时代与成矿动力学背景

大兴安岭地区位于兴蒙造山带的东段,构造、岩浆活动强烈,蕴藏着丰富的内生有色金属、贵金属矿产资源。本文通过对该区内生铜矿床的地质特征、成因类型和年代学研究,初步将区内内生铜矿床划分为斑岩型、浅成热液高硫化型(铜银、铜锡)和接触交代型三种成因类型,除铜锡矿床外,它们的成矿作用均与高钾钙碱系列I型花岗质岩浆密切相关;其中斑岩型和浅成热液高硫化型(铜、银)的成矿分别发生在485Ma、180~170Ma和170~160Ma;而浅成热液高硫化型(铜锡)矿床与A型花岗质岩浆相关,成矿在150~135Ma之间;接触交代型与它们相伴生,主要发生在180~160Ma和150~135Ma。其成矿动力学背景分别与早古生代兴安地块与松嫩地块的拼合碰撞造山、中侏罗世的西伯利亚板块和华北板块的陆缘增生带碰撞缝合造山与早白垩世碰撞造山后的地壳伸展减薄作用过程相适应,矿床在不同阶段的造山挤压与伸展转换或造山期后的伸展阶段就位,这项研究为深入研究该区内生多金属成矿规律提供了科学依据。     

张广才岭五道岭组火山岩的锆石U——Pb 年代学及地球化学特征

对张广才岭五道岭组火山岩进行锆石U--Pb LA--ICP--MS 年代学和岩石地球化学研究,以确定该组火山岩形成的时代和构造背景。选取样品中的锆石均呈自形--半自形晶,具有清晰的振荡生长环带和较高的Th /U 比值( 0. 52 ～ 2. 28) ,暗示其岩浆成因。测年结果显示,五道岭组火山岩形成于289 ± 3 Ma,是早二叠世岩浆活动的产物。火山岩的岩石组合为玄武岩--流纹岩,显示双峰式火山岩的特点,属于高钾钙碱性--钾玄岩系列,玄武岩具有富集Ｒb、K 等大离子亲石元素( LILE) ,亏损Nb、Ta 等高场强元素( HFSE) 的特征; 流纹岩呈负铕异常,富集Ｒb、Th、U 和K 等大离子亲石元素( LILE) ,亏损Nb、Ta 和Ti 等高场强元素( HFSE) 及Sr、P 元素,并显示A 型流纹岩的特点。结合该时期区域构造演化史,火山岩地球化学特征揭示了五道岭组火山岩的形成与岛弧环境下的局部伸展作用有关,这种构造背景是古亚洲洋板块俯冲于松嫩-张广才岭-佳木斯陆块之下造成的。     

大兴安岭巴雅尔吐胡硕地区碎斑熔岩锆石U-Pb年龄、地球化学特征及其地质意义

在大兴安岭中南段巴雅尔吐胡硕地区发现一套碎斑熔岩。根据野外调查,可分为中心相的细微粒斑状石英二长岩(-石英二长斑岩)和边缘相的英安流纹质碎斑熔岩。通过SHRIMP锆石U-Pb测年,获得细微粒斑状石英二长岩的年龄加权平均值为137.4±0.9Ma(MSWD=1.13),英安流纹质碎斑熔岩的年龄加权平均值为135.2±0.8Ma(MSWD=1.17),二者的形成时代均属于早白垩世早期。由元素地球化学分析可知,6件样品均属于过铝质的高钾钙碱性A型花岗岩,且具有完全一致的微量元素蛛网图和稀土元素配分曲线,均具有明显的负Eu异常,均富集大离子亲石元素Rb、Pb和轻稀土元素,亏损高场强元素Nb,Th较富集,Ba、Sr、Eu具有一定亏损,Pb强烈富集,表明岩石来源于地壳部分熔融。在构造环境判别分析的基础上,提出研究区碎斑熔岩属于碰撞后或造山期后的张性构造环境花岗岩(A2型花岗岩),形成于拉张环境,代表了伸展的大地构造背景。结合大兴安岭地区的大地构造演化特征,其形成与蒙古-鄂霍茨克闭合造山后的岩石圈伸展作用有关。     

Discriminating characters of ore-forming intrusions in the super-large Chalukou porphyry Mo deposit,NE China

The Chalukou porphyry Mo deposit, located in the Great Hinggan Range, is the largest Mo deposit in northeast China, although the age and genesis of the associated magmatic intrusions remain debated.Here we report zircon U-Pb ages and trace elements, whole rock geochemistry and Sre Nd isotope data with a view to understand the relationship between the magmatism and molybdenum mineralization.Zircon U-Pb analysis yield an age of 475 Ma for rhyolite in the older strata, 168 Ma for the premineralization monzogranite, and 154 Ma for the syn-mineralization granite porphyry. The granite porphyry and quartz porphyry are considered as the ore-forming intrusions. These rocks are peraluminous, alkali-calcic, and belong to high-K to shoshonitic series with a strong depletion of Eu. They also display characteristics of I-type granites. The rocks exhibit wide variations of(87 Sr/86 Sr)iin the range of 0.705426 -0.707363, and ε_(Nd)(t) of -3.7 to 0.93. Zircon REE distribution patterns show characteristics between crust and the mantle, implying magma genesis through crust-mantle interaction. The Fe_2O_3/FeO values(average 1) for the whole rock and EuN/Eu*Nvalues(average 0.45), Ce~(4+)/Ce~(3+) values(average 301)for zircon grains from the granite porphyry are higher than those from other lithologies. These features suggest that the ore-forming intrusions(syn-mineralization porphyry) had higher oxygen fugacity conditions than those of the pre-mineralization and post-mineralization rocks. The Chalukou Mo deposit formed in relation to the southward subduction of the Mongol-Okhotsk Ocean. Our study suggests that the subduction-related setting, crust-mantle interaction, and the large-scale magmatic intrusion were favorable factors to generate the super-large Mo deposits in this area.     

大兴安岭中段木瑞组的发现及其地质意义

在内蒙古1：5万蘑菇山幅、柴河源幅、苏河屯幅、兴安幅四幅区域地质调查中,研究人员通过详细的野外地质调查,首次在中侏罗统满克头鄂博组下部发现木瑞组,二者为整合接触关系。该组岩石类型为紫红色泥质粉砂岩夹灰白色砾岩,出露不完整,从而证明大兴安岭中段在中侏罗世历经陆相山间盆地堆积,具快速堆积特点。该组可作为一个区域性的标志层,对研究大兴安岭中段在中侏罗世期间地质演化史具有重要意义。     

关于南岭中生代花岗岩侵位年龄与锆石U-Pb年龄的时差问题:与章邦桐教授等讨论

从南岭中生代花岗岩的显微结构特征、花岗岩液相线和固相线的已有实验成果、锆饱和温度信息、花岗岩体几何形态以及它们与围岩的接触关系等角度,提出这些花岗岩中锆石结晶温度较高,其结晶年龄与花岗岩岩浆侵位年龄之间的时差较小,很可能在锆石U-Pb年龄测定的误差范围内,因此,花岗岩中锆石的U-Pb年龄,能近似地代表花岗岩岩浆的侵位年龄。     

张广才岭燕山早期白石山岩体成因与壳幔相互作用

出露于东北地区张广才岭的白石山岩体,其全岩-矿物Rb-Sr等时线年龄为196士4 Ma,表明形成于中生代的燕山早期,而非传统认识上的印支期.岩体主岩和闪长质包体均具有低ISr(≈0.705)和正εNd(t)(+1.7～+2.2)值的特点,反映岩体成因与地幔具有密切的联系.地质学、岩石学和地球化学的详细研究表明该岩体具有壳幔混合成因,闪长质包体是较基性的地幔岩浆进入主岩浆中淬火结晶而成,花岗质岩浆的源区主要为新生的地壳物质.动力学分析表明,本区在华北板块和西伯利亚板块碰撞拼合后,由于东侧大洋板块的俯冲及后续的岩石圈拆沉效应,导致软流圈地幔上隆及幔源岩浆的板底垫托,并进而造成先存和新生地壳的部分熔融和不同源区岩浆的混合作用.底垫的新生地壳是兴蒙造山带造山后晚期形成的.因此,古生代-中生代是本区地壳生长的重要时期,且这种地壳生长是在垂向构造机制下进行的.     

大兴安岭北部主要金属矿床成矿系列和区域矿床成矿谱系

文章以大兴安岭北部内生金属矿床、海相火山岩型硫铁矿矿床和砂金矿床为研究对象,按照矿床成矿系列的学术思想将其划分为7个矿床成矿系列,即:多宝山地区与加里东期中酸性火山_侵入活动有关的铜、钼矿床成矿系列,呼玛地区与华力西期辉长岩和花岗岩有关的铁、钛、金矿床成矿系列,伊尔施_黑河地区与华力西期花岗岩和海相火山岩有关的铁、铜、锌、硫铁矿矿床成矿系列,牙克石地区与华力西期海相中基性火山岩有关的铁、锌、硫铁矿矿床成矿系列,得尔布干地区与印支期_燕山期中酸性火山_侵入活动有关的铅、锌、银、铜、钼、金矿床成矿系列,伊尔施_呼玛地区与燕山期中酸性火山_侵入活动有关的金、铁、锌、铜、钼、钨矿床成矿系列和黑龙江流域与第四纪冲积沉积作用有关的砂金矿床成矿系列。大兴安岭北部区域矿床成矿谱系表明,从奥陶纪到新生代该区不同构造单元经历了7个主要的构造演化及成矿时期,依次出现奥陶纪岛弧环境的斑岩型矿床、泥盆纪陆块边缘拉张环境的岩浆型和热液脉型矿床、泥盆纪—石炭纪俯冲_碰撞环境的海相火山岩型和矽卡岩型矿床、石炭纪弧后盆地环境的海相火山岩型矿床、晚三叠世—早白垩世俯冲_碰撞_后碰撞环境的斑岩型、热液脉型、浅成低温热液型和矽卡岩型矿床、早侏罗世—早白垩世俯冲环境的斑岩型、热液脉型、浅成低温热液型和矽卡岩型矿床和新生代地壳差异运动带砂金矿床。大兴安岭北部优势矿种为铜、钼、金、银、铅、锌,主攻矿床类型为斑岩型、热液脉型、低硫化浅成低温热液型、冲积型和海相火山岩型。     

黑龙江省三矿沟夕卡岩型铁铜矿床矿物学特征及成矿物理化学条件

黑龙江三矿沟铁铜矿床位于大兴安岭北段多宝山矿集区,矿体产于燕山期侵入岩与奥陶系多宝山组大理岩接触带的夕卡岩内。根据矿物共生组合及交代关系,确定热液成矿过程包括夕卡岩阶段、退夕卡岩阶段和石英硫化物阶段。铁矿化主要发生在退夕卡岩阶段,形成磁铁矿、镜铁矿等铁氧化物,呈浸染状、条带状、块状产于钙铁榴石夕卡岩中。铜矿化主要发生在石英硫化物阶段,形成黄铜矿、斑铜矿等硫化物,交代早期矿物。电子探针分析等研究表明,三矿沟铁铜矿床发育钙质夕卡岩矿物组合,其石榴子石主要为钙铝榴石和钙铁榴石,辉石为透辉石钙铁辉石系列,角闪石属于钙角闪石系列,绿泥石属于I型三八面体富铁绿泥石。石榴子石有3种类型：早期自形粗粒的钙铝榴石(Grt-Ia)和钙铁榴石(Grt-Ib),以及晚期呈脉状产出的钙铁榴石(Grt-Ⅱ)。夕卡岩阶段成矿流体具有高温、弱酸性、高氧逸度的特征;退夕卡岩阶段流体温度降低,pH升高,形成大量铁氧化物;石英硫化物阶段流体温度和氧逸度降低,金属硫化物沉淀。