全文获取类型
收费全文 | 661篇 |
免费 | 168篇 |
国内免费 | 137篇 |
专业分类
测绘学 | 4篇 |
大气科学 | 23篇 |
地球物理 | 227篇 |
地质学 | 461篇 |
海洋学 | 205篇 |
天文学 | 10篇 |
综合类 | 13篇 |
自然地理 | 23篇 |
出版年
2024年 | 2篇 |
2023年 | 2篇 |
2022年 | 16篇 |
2021年 | 12篇 |
2020年 | 16篇 |
2019年 | 21篇 |
2018年 | 24篇 |
2017年 | 51篇 |
2016年 | 48篇 |
2015年 | 31篇 |
2014年 | 56篇 |
2013年 | 36篇 |
2012年 | 47篇 |
2011年 | 94篇 |
2010年 | 33篇 |
2009年 | 57篇 |
2008年 | 44篇 |
2007年 | 46篇 |
2006年 | 52篇 |
2005年 | 31篇 |
2004年 | 36篇 |
2003年 | 30篇 |
2002年 | 19篇 |
2001年 | 18篇 |
2000年 | 16篇 |
1999年 | 17篇 |
1998年 | 16篇 |
1997年 | 13篇 |
1996年 | 16篇 |
1995年 | 18篇 |
1994年 | 8篇 |
1993年 | 6篇 |
1992年 | 5篇 |
1991年 | 1篇 |
1990年 | 5篇 |
1989年 | 6篇 |
1988年 | 3篇 |
1987年 | 1篇 |
1986年 | 4篇 |
1985年 | 4篇 |
1984年 | 3篇 |
1978年 | 1篇 |
1954年 | 1篇 |
排序方式: 共有966条查询结果,搜索用时 15 毫秒
121.
以副溶血性弧菌VP-X-3为试验对象,利用气相色谱技术分析了其细胞脂肪酸的组成和含量,以色谱峰的数量、色谱峰高及脂肪酸含量作为评价指标,探讨了不同的皂化和甲酯化条件对细菌细胞脂肪酸测定结果的影响。结果表明:皂化和甲酯化条件都对细胞脂肪酸的组成和含量产生一定的影响。较低温度皂化处理利于增加色谱峰数量和色谱峰高。甲酯化温度过高容易破坏脂肪酸,尤其是长链脂肪酸和不饱和脂肪酸的结构。高温甲酯化条件下,时间越长,甲酯化效果越差。试验得到较为理想的气相色谱前处理条件:2 mol/L NaOH-甲醇溶液2 mL,70℃水浴10 min;10%(V/V)H2SO4-甲醇溶液2 mL,70℃水浴15 min。此条件下的色谱峰的数量多达29种,色谱峰高明显高于其他处理条件下的峰高。 相似文献
122.
研究南海北部海底沉积物温度变化状态下声速性质,得出以下结论:(1) 南海北部海底沉积物具有声速温度正增长(STPIK)、声速温度负增长(STNIK)和声速温度波动(STWK)三种类型,后两种类型在世界其他范围内海域未见报道.(2) 声速温度正增长类型和声速温度负增长类型沉积物的温度变化对声速影响都具有十分显著的线性关系,但是原状样品由于组成不均匀性,增大了声速的非线性变化.(3)南海北部海底沉积物的孔隙度、密度等主要物理参数差异不明显,难以直接解释三类样品的温度-声速性质的不同.(4)对于STPIK类型沉积物,理论分析与实验结果的统一性,可以运用海底沉积物与海水声速比进行校正不同温度状态下的海底沉积物的声速.(5)对于STNIK和STWK类型沉积物,需要深入研究,从理论和实验角度揭开其机理和成因.海底沉积物声速-温度特性研究将为提高南海北部海域天然气水合物声学探测精度和准确度提供声速性质依据. 相似文献
123.
124.
An optimized analysis method based on headspace liquid phase microextraction (HS‐LPME) and gas chromatography coupled with mass spectrometry was proposed for the determination of trihalomethanes (THMs) in drinking water. The response surface method (RSM) was used to optimize the extraction of THMs for analysis by HS‐LPME. The temperature, extraction time and NaCl concentration were found to be important extraction parameters. The coefficient of determination (R2) for the model was 94.97%. A high probability value (P < 0.0001) for the regression indicated that the model had a high level of significance. The optimum conditions were seen to be: temperature 42.0°C, NaCl concentration 0.30 g/mL, and extraction time 28 min. The response variable was the summation of the THMs chromatography peak areas and the reproducibility of this was investigated in five replicate experiments under the optimized conditions. The relative standard deviations (RSD%) of the THMs ranged from 8.0–11.6%. The limits of detection (LODs), based on a signal‐to‐noise ratio (S/N) of three ranged from 0.42–0.78 μg/L, and were lower than the maximum limits for THMs in drinking water established by the WHO. 相似文献
125.
基于野外地质和钻井资料,结合相关实验测试结果,对湘西北地区下古生界海相页岩储层特征进行了深入研究,并探讨了页岩甲烷含气性及影响因素。结果表明:牛蹄塘组黑色页岩以深水陆棚斜坡相沉积为主,厚度范围为50~250 m;龙马溪组为闭塞海湾沉积,底部黑色页岩发育。两组页岩有机质类型均属于Ⅰ型,有机碳含量平均为3.57%和1.16%,热演化程度较高,平均达2.61%和2.08%。受沉积环境和成岩作用影响,两组页岩均具有高石英、低黏土、少量碳酸盐矿物的组成特征。页岩储集空间可划分为3大类:矿物基质孔、有机质孔、微裂缝。受有机质和黏土矿物等因素影响,页岩内部孔隙结构参数各不同,但主体上孔径小于50 nm的微孔和中孔提供了大部分比表面积和孔体积,为气体存储主要场所。牛蹄塘组页岩甲烷最大吸附量平均为1.98 cm3/g;龙马溪组页岩甲烷最大吸附量较低,为1.16 cm3/g。其中有机质与黏土矿物对页岩甲烷吸附量均有一定的贡献,而过高的成熟度和含水量可导致页岩吸附能力下降。 相似文献
126.
通过对苏里格气田北部20余口钻井岩心的岩石学特征、沉积构造、剖面结构的详细研究,结合测井相标志和古生物标志,认为苏里格气田北部盒8段属辫状河沉积,发育河道和洪泛平原两个业相。河道亚相可进一步划分为河床底部滞留沉积和心滩两个微相,往往组成向上变细的剖面结构,测井曲线一般为中-高幅的齿化或微齿化的箱形或钟形;洪泛平原亚相在剖面结构上表现为砂泥岩的不等厚互层,测井曲线多呈锯齿状。在微相分析的基础上,编制了盒8上和盒8下两个时期的沉积微相平面图,其显示出河道心滩砂体呈南北向展布的规律。根据沉积相的时空展布规律,建立了本区盒8段的沉积相模式。 相似文献
127.
Habib Belayouni Angelida Di Staso Francesco Guerrera Manuel Martín Martín Crina Miclǎuş Francisco Serrano Mario Tramontana 《International Journal of Earth Sciences》2009,98(1):157-176
An integrated stratigraphic analysis has been made of the Tarcău Nappe (Moldavidian Domain, Eastern Romanian Carpathians),
coupled with a geochemical study of organic-rich beds. Two Main Sequence Boundaries (Early Oligocene and near to the Oligocene–Aquitanian
boundary, respectively) divide the sedimentary record into three depositional sequences. The sedimentation occurred in the
central area of a basin supplied by different and opposite sources. The high amount of siliciclastics at the beginning of
the Miocene marks the activation of the “foredeep stage”. The successions studied are younger than previously thought and
they more accurately date the deformation of the different Miocene phases affecting the Moldavidian Basin. The intervals with
black shales identified are related to two main separate anoxic episodes with an age not older than Late Rupelian and not
before Late Chattian. The most important organic-rich beds correspond to the Lower Menilites, Bituminous Marls and Lower Dysodilic
Shales Members (Interval 2). These constitute a good potential source rock for petroleum, with homogeneous Type II oil-prone organic matter, highly lipidic and thermally immature. The deposition of black shales has been interpreted as occurring
within a deep, periodically isolated and tectonically controlled basin. 相似文献
128.
This paper presents a field study conducted in northwest Turkey and characterizes the NH3 concentration and emission measured in summer season from three chicken farms. The influence of environmental conditions on NH3 concentration and emission was also investigated in this study. Ammonia concentration, temperature, relative humidity and airflow rate were continuously recorded for four sequential days. The environmental conditions were measured using a multifunction temperature and humidity‐meter with a hot wire probe. Portable multiple gas detectors with electro‐chemical sensors were used to measure NH3 concentration. The NH3 emission rates for houses were calculated by multiplying simultaneously measured NH3 concentrations and air flow rates. The average daily mean (ADM) house concentrations of house 1 (H1), house 2 (H2), and house 3 (H3) were measured as 4.43, 3.71, and 6.20 ppm, respectively. NH3 concentration was inversely proportional to temperature (r = ?0.279), relative humidity (r = ?0.063) and airflow rate (r = ?0.554) for all monitored houses. The ADM house NH3 emission was 135 g/(h house) for H1, 255 g/(h house) for H2, and 117 g/(h house) for H3. The combined average emission rate in this study (0.26 g/(d bird)) was lower than the emission rate measured in chicken farms in the USA. However, our results were comparable to rates calculated in European studies because house design, ventilation system and bird diet applied in Turkish chicken farms are very similar to those employed in European countries. The NH3 emissions were significantly correlated to NH3 concentrations (r = 0.45, p ≤ 0.001) and airflow rates (r = 0.97, p ≤ 0.001). A clear diurnal pattern was obtained for NH3 concentrations rather than NH3 emissions at the end of the study. 相似文献
129.
沿裂隙发育的天然气水合物是印度深水盆地细粒沉积物中水合物的重要产出方式,水合物以结核状或脉状充填在高角度裂隙中.天然气水合物主要沿着构造主应力方向生成,由于裂隙的存在,含水合物的沉积物层呈现各向异性.利用孔隙介质中水合物呈均匀分布的速度模型计算的NGHP01-10D井水合物饱和度高达40%,而压力取芯表明水合物饱和度占孔隙空间的20%左右.为了研究水合物饱和度差异,基于层状介质的各向异性模型计算了裂隙充填型水合物的饱和度.在垂直井孔中,由于波入射角与裂隙倾角有关,考虑裂隙倾角变化,利用纵波和横波速度同时反演水合物饱和度和裂隙倾角.利用层状介质模型计算的水合物占孔隙空间的15%~25%,裂隙的倾角在60°~90°,多为高角度裂隙.在NGHP01-10D井中,纵横波速度联合计算的饱和度与压力取芯结果吻合更好. 相似文献
130.
本文以墨西哥湾水合物区域为背景,利用数值模拟方法研究了过平衡钻井条件下,当钻井液温度高于地层中水合物稳定温度时,水基钻井液侵入海洋含水合物地层的动态过程及其一般性规律.与侵入常规油气地层相比,耦合水合物分解和再形成是钻井液侵入海洋含水合物地层的主要特征.模拟结果表明,钻井液密度、温度和盐度都对侵入过程有影响.在一定条件下,钻井液密度越大,温度和含盐量越高,则钻井液侵入程度越深,热量传递越远,水合物分解程度越大.分解的水气在合适条件下又会重新形成水合物,影响了钻井液进一步侵入.而重新形成的水合物的饱和度甚至可能高于原位水合物饱和度,在井周形成一个"高饱水合物"环带.这一现象归因于钻井液侵入的驱替推挤、水合物分解的吸热以及地层传热的滞后等因素共同作用.在地层物性一定的条件下,高饱水合物环带的出现与否主要受钻井液温度和盐度控制.水合物分解以及高饱水合物环带的出现对井壁稳定和电阻率测井解释有很大影响.因此,为维护井壁稳定、确保测井准确和减少水合物储层伤害,就必须对钻井液密度、温度和滤失量进行严格控制,防止地层中的水合物大量分解.最好采用控制压力钻井(MPD)和深侧向测井方式,同时尽量选用低矿化度的含水合物动力学抑制剂的钻井液体系,采取低温快速循环方式. 相似文献