C—O—H体系高温高压流体相组成的热力学研究

本文在C－O－H体系流体相平衡基础上,利用现有的热力学数据和新的p－V－T资料,在pT=∑pi假定下,计算了高温、高压条件下流体相组成。结果表明,该体系主要存在五种流体相,在不同温压条件下各流体相所占比例不同。在相对较低的温、压条件下,CH4是体系中占主要的流体相（约占70％）,且随温、压和氧逸度的升高,它所占比例却明显降低,所获结果为探讨无机成因天然气形成的可能性、存在的量比和稳定存在的物理化学条件提供了充分的理论依据。     

顶空气相色谱法测定海水二甲基硫和浮游植物细胞二甲基硫丙酸的研究

建立了顶空ＧＣ／ＦＰＤ测定海水中二甲基硫（ＤＭＳ）和浮游植物细胞中二甲基硫丙酸（ＤＭＳＰ）的方法，并研究盐度、温度、气液相比ＤＭＳ诸因素对ＤＭＳ顶空灵敏度的影响。该法对ＤＭＳ测定的相对标准偏差均小于６％，平均回收率为１０６％，最低检出限为２０ｎｇ／Ｌ。细胞ＤＭＳＰ先经碱作用转化为ＤＭＳ，在５０℃下作用时间不少于６ｈ，峰高与浓度的双对数线性相关系数大于０．９９。对１９９４年冬、１９９５年夏采自胶州湾     

Experimental investigation of hydrate formation in water-dominated pipeline and its influential factors

Blockage in water-dominated flow pipelines due to hydrate reformation has been suggested as a potential safety issue during the hydrate production. In this work, flow velocity-dependent hydrate formation features are investigated in a fluid circulation system with a total length of 39 m. A 9-m section pipe is transparent consisted of two complete rectangular loops. By means of pressurization with gas-saturated water, the system can gradually reach the equilibrium conditions. The result shows tha...     

The HNCO ring in the Sgr B2 region

The large-scale structure associated with the 2′N HNCO peak in Sgr B2 [Minh, Y.C., Haikala, L., Hjalmarson, Å., Irvine, W.M., 1998. ApJ 498, 261 (Paper I)] has been investigated. A ring-like morphology of the HNCO emission has been found; this structure may be colliding with the Principal Cloud of Sgr B2. This “HNCO Ring” appears to be centered at (l,b) = (0.7°,−0.07°), with a radius of 5 pc and a total mass of 1.0 × 10⁵ to 1.6 × 10⁶ M. The expansion velocity of the Ring is estimated to be 30–40 km s⁻¹, which gives an expansion time scale of 1.5 × 10⁵ year. The morphology suggests that collision between the Ring and the Principal Cloud may be triggering the massive star formation in the Sgr B2 cloud sequentially, with the latest star formation taking place at the 2′N position. The chemistry related to HNCO is not certain yet, but if it forms mainly via reaction with the evaporated OCN⁻ from icy grain mantles, the observed enhancement of the HNCO abundance can be understood as resulting from shocks associated with the collision between the Principal Cloud and the expanding HNCO Ring.     

复杂地质条件下气层的多参数识别

在复杂地质条件下,应用单一或两种孔隙测井资料直接识别气层,灵敏度不高,为了准确地识别复杂地质条件下的气层,需从不同角度,应用多参数进行综合识别,本文介绍了声波法,中子－密度法,双孔隙度法,中子－伽玛法,等效弹性模量法等,并应用它们对哈盆地两口井进行了重点分析,效果良好。     

上扬子区早寒武世黑色页岩磷结核特征及生化淀磷机制

通过野外观察、室内化学分析、矿物学分析、硫同位素分析、光学显微镜和扫描电镜观察,发现磷结核内所观察到的许多现象均与微生物的活动有关,微生物是使磷淀积的重要营力,这为磷结核的生物成矿作用提供了有力的证据.沉积物孔隙水物理化学条件的变化直接影响着磷结核的生长过程.     

地球物理测井在天然气水合物勘探中的应用

天然气水合物是一种潜在的巨大能源。美国、日本、俄罗斯等发达国家在该领域已经进行了大量的研究工作，试图从各个角度去探测天然气水合物的存在并评价其蕴藏量。地球物理测井在天然气水合物探测与储量评价领域发挥了重要作用并且随着以勘探天然气水合物为目的的钻井的增多，日益受到重视。基于国内在该领域研究较少的现状，综述了国外地球物理测井技术在天然气水合物勘探中的应用，详细介绍了常规测井方法定性识别和定量评价天然气水合物储层的孔隙度、饱和度方法和技术，基于含天然气水合物储层的碳氧比能谱测井解释模型以及成像测井在含天然气水合物井段的测井响应。并在此基础上分析了我国在该领域的研究思路。     

Application of the Response Surface Method for Optimization of Headspace Liquid Phase Microextraction of Trihalomethanes in Drinking Water

An optimized analysis method based on headspace liquid phase microextraction (HS‐LPME) and gas chromatography coupled with mass spectrometry was proposed for the determination of trihalomethanes (THMs) in drinking water. The response surface method (RSM) was used to optimize the extraction of THMs for analysis by HS‐LPME. The temperature, extraction time and NaCl concentration were found to be important extraction parameters. The coefficient of determination (R²) for the model was 94.97%. A high probability value (P < 0.0001) for the regression indicated that the model had a high level of significance. The optimum conditions were seen to be: temperature 42.0°C, NaCl concentration 0.30 g/mL, and extraction time 28 min. The response variable was the summation of the THMs chromatography peak areas and the reproducibility of this was investigated in five replicate experiments under the optimized conditions. The relative standard deviations (RSD%) of the THMs ranged from 8.0–11.6%. The limits of detection (LODs), based on a signal‐to‐noise ratio (S/N) of three ranged from 0.42–0.78 μg/L, and were lower than the maximum limits for THMs in drinking water established by the WHO.     

水合物赋存形式对石英砂电性特征影响的数值模拟研究

天然气水合物储层精确评价关系到储层的生产与开发过程.由于储层微观结构具有非均质性, 且水合物合成分解过程中分布形式复杂, 水合物储层物性变化规律尚不明晰, 从而难以对储层水合物饱和度进行准确预测.为明确水合物赋存模式对电性特征的影响规律, 本文基于石英砂样品采用随机模拟的方法实现了颗粒包裹型、孔隙填充型和团簇状分布三类赋存模式的水合物数字岩心构建, 并进一步提取孔径分布分析不同水合物分布模式下的微观结构变化特征, 利用有限元方法对含水合物数字岩心进行电性模拟, 结合阿尔奇公式得到适用于含水合物石英砂介质的经验参数取值, 并采用实验室内水合物合成实验电阻率测量数据与实际储层电阻率测井数据对比验证了阿尔奇经验参数取值的正确性及有效性.结果表明, 随着水合物饱和度逐渐增加, 在相同水合物饱和度下, 颗粒包裹型生长引起的微观结构变化对电传导过程的影响最为显著; 孔隙填充型水合物生长引起的孔隙结构变化对电传导过程影响最小; 不同水合物赋存形式下, 沉积物孔径分布变化规律从微观角度解释了三类分布模式的电性差异.研究结果有助于研究储层内含水合物沉积物合成分解过程中的电性特征演化规律.

     

灾害预报与鸡西煤矿瓦斯爆炸事件

2002年上半年,伴随着厄尔尼诺现象的日益加剧,全球性重大自然灾害频繁发生.6月20日发生在中国黑龙江省鸡西煤矿的瓦斯爆炸事件和6月22日发生在伊朗的强烈地震,时间恰逢月亮近地潮的6月19日和太阳潮半日形变最大值的夏至的6月21日附近,是地球形变和排气较强烈的时段.据国内外有关资料,月球与地球发震有关系的重要条件是“近地点兼朔、望”以及各大行星特定位置的配合,张元东称之为“特殊天象组合期”[1];郭增建等提出,月亮赤纬角或太阳黄赤交角最大时地球形变和排气最强烈[2～5].在此期间,中国各种大的突发性灾难,如空难、海难、火车事故、矿…