地下气体运移变化的物理化学机制研究

在河北省怀来县后郝窑地区，对地下气体运移变化的影响因素进行了野外模拟实验研究。选择３个试验点，对地下气体的扩散作用，物理化学影响因素及水压效应等进行了模拟实验，主要研究Ｈ２，ＣＯ２气体运移变化机制。实验研究表明，Ｈ２，ＣＯ２气体运移变化机制不尽相同，水压效应对Ｈ２，ＣＯ２等地下气体运移影响相当明显     

Pit crater structure and processes governing persistent activity at Masaya Volcano, Nicaragua

 Persistent activity at Masaya Volcano, Nicaragua, is characterised by cycles of intense degassing, lava lake development and pit crater formation. It provides a useful site to study the processes which govern such activity, because of its easy accessibility and relatively short cycles (years to decades). An understanding of the present activity is important because Masaya is visited by large numbers of tourists, is located close to major cities and has produced voluminous lavas, plinian eruptions and ignimbrites in the recent past. We provide structural and geophysical data that characterise the "normal" present state of activity. These indicate that the ongoing degassing phase (1993 to present) was not caused by fresh magma intrusion. It was associated with shallow density changes within the active Santiago pit crater. The activity appears to be associated predominantly with shallow changes in the pit crater structure. More hazardous activity will occur only if there are significant departures from the present gravity, deformation and seismic signatures. Received: 16 May 1997 / Accepted: 29 October 1997     

野外简易脱气装置简介

根据水力学原理结合水氡在实验室分析中水样鼓泡脱气的方法 ,进行了大量的野外试验 ,研制开发了野外简易脱气装置。通过几个月的试观测 ,脱气装置气流稳定 ,脱气效率高 ,完全可以满足自动化观测仪器对气量的需求。该装置解决了地下水化学在野外冷水泉无法进行气体观测的难题 ,而且制作简单、费用低廉 ,非常便于推广。     

日本南海海槽天然气水合物研究现状

本文介绍日本在其周围海域特别是南海海槽的海洋天然气水合物研究工作，首先介绍其研究简史，研究计划，研究队伍及早期研究成果，其次，介绍了西南海海槽天然气水合物的勘探、研究状况，然后,介绍了五年计划实施的东南海海槽地球物理勘探、钻探状况，最后指出，南海海槽的一些新资料深入的综合研究无疑会给世界水合物研究增添新的内容。     

Direct and Indirect pCO2 Measurements in a Wide Range of pCO2 and Salinity Values (The Scheldt Estuary)

Recent improvements in both Infra-red spectroscopy and equilibrator techniqueshave allowed to determine, for the first time, pCO₂using simultaneously and continuously both the direct and indirect methods in an estuary where pCO₂ values range from 500 to 8500 atm and salinity from 0 to 30. Our results show that both methods are in excellent agreement in the wholeestuary (r² = 0.999, n = 1075, p < 0.0001). Thus, the NBS (US National Bureau of Standards) scale, although inadequate for seawater samples, is appropriate for estuarine waters and can be applied with confidence to calculate pCO₂.     

中国海相油气田勘探实例(之一) 四川盆地罗家寨大型气田的发现和探明

罗家寨气田发现于2000年,是四川盆地迄今为止发现的储量规模最大的一个气田,2002年探明储量为581.08×108m3。其下三叠统飞仙关组储层由碳酸盐岩蒸发台地边缘优质鲕粒滩白云岩构成,圈闭面积大,构造幅度高,具有一定的埋藏隐蔽性。论述了气田的发现和探明过程,气藏地质的特征,以及对碳酸盐岩气藏勘探的启示。     

New high-resolution 2D seismic imaging of fluid escape structures in the Makran subduction zone,Arabian Sea

Seabed fluid escape is active in the Makran subduction zone, Arabian Sea. Based on the new high-resolution 2D seismic data, acoustic blanking zones and seafloor mounds are identified. Acoustic blanking zones include three kinds of geometries: Bell-shaped, vertically columnar and tilted zones. The bell-shaped blanking zone is characterized by weak and discontinuous reflections in the interior and up-bending reflections on the top, interpreted as gas chimneys. Vertically columnar blanking zone is interpreted as side-imaged gas chimneys associated with focused fluid flow and topped by a seafloor anomaly expressed as a localized reflection discontinuity, which may together serve as a vent structure. Tilted acoustic blanking zone could be induced by accretionary thrust activity and rapid sedimentation surrounding slope. Seafloor mounds occur at the sites of bell-shaped acoustic blanking zone and may be associated with the material intrusion. Bottom simulating refectors (BSRs) are widely distributed and exhibit a series of characteristics including diminished amplitude, low continuity as well as local shoaling overlapping with these acoustic blanking zones. The large amount of gases dissociated from the gas hydrates migrated upwards and then arrived at the near-seafloor sediments, followed by the formation of the gas hydrates and hence the seafloor mound.     

N1923-DA201大孔吸附树脂反相分配色层分离、偶氮胂Ⅲ比色测定矿石中钍

用N1923-二甲苯作固定相,AD201大孔聚二乙烯苯吸附树脂作裁体,研究了钍在硫酸介质中的反相分配色层分离条件。拟定了矿石中微量钍的测定方法。     

Gas generation and expulsion characteristics of Middle–Upper Triassic source rocks,eastern Kuqa Depression,Tarim Basin,China: implications for shale gas resource potential

Frontier exploration in the Kuqa Depression, western China, has identified the continuous tight-sand gas accumulation in the Lower Cretaceous and Lower Jurassic as a major unconventional gas pool. However, assessment of the shale gas resource in the Kuqa Depression is new. The shale succession in the Middle–Upper Triassic comprises the Taliqike Formation (T₃t), the Huangshanjie Formation (T₃h) and the middle–upper Karamay Formation (T_2–3k), with an average accumulated thickness of 260 m. The high-quality shale is dominated by type III kerogen with high maturity and an average original total organic carbon (TOC) of about 2.68 wt%. An improved hydrocarbon generation and expulsion model was applied to this self-contained source–reservoir system to reveal the gas generation and expulsion (intensity, efficiency and volume) characteristics of Middle–Upper Triassic source rocks. The maximum volume of shale gas in the source rocks was obtained by determining the difference between generation and expulsion volumes. The results indicate that source rocks reached the hydrocarbon expulsion threshold of 1.1% VR and the hydrocarbon generation and expulsion reached their peak at 1.0% VR and 1.28% VR, with the maximum rate of 56 mg HC/0.1% TOC and 62.8 mg HC/0.1% TOC, respectively. The volumes of gas generation and expulsion from Middle–Upper Triassic source rocks were 12.02 × 10¹² m³ and 5.98 × 10¹² m³, respectively, with the residual volume of 6.04 × 10¹² m³, giving an average gas expulsion efficiency of 44.38% and retention efficiency of 55.62%. Based on the gas generation and expulsion characteristics, the predicted shale gas potential volume is 6.04 × 10¹² m³, indicating a significant shale gas resource in the Middle–Upper Triassic in the eastern Kuqa Depression.     

加油站的雷电防护设计

通过对加油站所处环境特点、系统特点中雷电灾害各因素的分析，对加油棚、油罐及附属建筑的直击雷防护和接地，加油站电源、信号系统的雷电系统防护和静电防护等，依据GB50057、IEC61312、GB50156—2002标准对雷电防护的要求，提出了系统的解决方案。