连县小带铅锌铁锰矿床特征与喷流沉积机制浅析

连县小带是粤北近几年发现的又一喷流沉积铅锌矿床。简要介绍其成矿环境、地质特征,讨论喷流(喷气)沉积(成矿)作用及成矿分带的主要地球化学机制,如因脉动喷流(喷气)造成盆地内地球化学性质的周期变化,引起矿石组构的周期变化等。     

用气体地球化学方法探讨活断层的有关问题

探讨了以氡为主的断层气测量结果与断层活动性的关系;并讨论了土质、土壤、含水量、取样深度等对断层气氡测量的影响。     

On the scavenging of gaseous nitrogen compounds by large and small rain drops I. A wind tunnel and theoretical study of the uptake and desorption of NH3 in the presence of CO2

An experimental study has been carried out in the Mainz vertical wind tunnel to determine the rate at which NH₃ in the presence of CO₂ is absorbed by freely suspended water drops. The experimental uptake rates were found to be in good agreement with the rates predicted by the Kronig-Brink convective diffusion model and, for gas concentrations in the ppbv range also by the model in which it is assumed that the absorbed gas is well mixed inside the drop (henceforth called well mixed model). The same conclusion was shown to apply also to the desorption of NH₃ from a drop previously exposed to NH₃. The latter result is in contrast to the desorption of SO₂ which must be described by a model which accounts for the diffusion of the species inside the drop. Comparison of our experimental results with theory show further that the uptake of NH₃ in presence of CO₂ is significantly overestimated if the slow reaction CO_2(aq)+H₂OHCO ₃ ^– +H⁺ is neglected in the theoretical computation.     

基于X射线衍射法对天然气水合物测试分析研究概述

天然气水合物（下称“水合物”）是由烃类气体和水分子组成,主要赋存于具有低温高压环境的海底沉积物和陆地永久冻土区,形成固态类冰的笼型结晶化合物（Sloan,1998）,又称“可燃冰”或者笼形包合物。水合物储载气体的能力极强,是一种超高密度的能源贮藏体,理论上1 m3水合物,储载了164 m3的甲烷气体（施伟光,2015）,据估计水合物全球储量是全球化石燃料的2倍,可以说是潜力巨大的高效清洁能源。     

鄂尔多斯盆地东部二叠系山西组页岩气成藏条件与有利区筛选

鄂尔多斯盆地东部榆106井区山西组页岩沉积在三角洲平原分流河道间沼泽、天然堤、决口扇远端与洼地环境。根据有机地球化学、物性、含气性、岩性实验分析,结合钻井、录井、测井资料与沉积相研究,开展了该区山西组页岩气成藏条件与有利区分布研究。山西组页岩有机碳含量较高,山二段平均5.28%,山一段平均3.02%,有机质类型以Ⅱ_2、Ⅲ型干酪根为主,有机质成熟度较高,R_o平均1.89%,生气条件优越。页岩孔隙度平均1.7%,渗透率平均0.0415×10~(-3)μm~2,平均含气量0.64 m~3/t,页岩单层厚度小,垂向上普遍与致密砂岩、煤层组成互层,累计厚度较大(平均达75 m),页岩渗透性较好而储集性能稍差。页岩脆性矿物含量平均49.9%,黏土矿物含量平均50.1%,黏土矿物含量较高,资源丰度普遍较低,但是页岩埋深小于3000 m,试气产能较高(0.64×10~4m~3/d),商业开发潜力较好。山二段有机质含量比山一段更高,含气性比山一段更好。主要基于页岩厚度与沉积相展布预测的山二段页岩气有利区呈北东向、南北向条带状展布,受分流河道间沼泽微相的控制。     

Fluid inclusion and microfabric studies on Zechstein carbonates (Ca2) and related fracture mineralizations – New insights on gas migration in the Lower Saxony Basin (Germany)

New petrographic and fluid inclusion data from core samples of Upper Permian dolomitic limestone (Hauptdolomit, Zechstein group, Stassfurt carbonate sequence) from a gas field located at the northern border of the Lower Saxony Basin (LSB) essentially improve the understanding of the basin development. The gas production at the locality is characterized by very high CO₂ concentrations of 75–100% (with CH₄ and N₂).Samples consist of fine grained, mostly laminated and sometimes brecciated dolomitic limestone (mudstone/wackestone) from the transition zone between the shallow water zone (platform) and the upper slope. The study focuses on migration fluids, entrapped as fluid inclusions in diagenetic anhydrite, calcite, and fluorite, and in syn-diagenetic microfractures, as well as on the geochemistry of fluorite fracture mineralizations, obtained by LA-ICP-MS analysis. Fluid inclusion studies show that the diagenetic fluid was rich in H₂ONaClCaCl₂. Recrystallized anhydrite contains aqueous inclusions with homogenization temperatures (T_h) of ca. 123 °C, but somewhat higher T_h of ca. 142 °C was found for calcite cement followed by early Fluorite A with T_h of 147 °C. A later Fluorite B preserves gas inclusions and brines with maximum T_h of 156 °C. Fluorite B crystallized in fractures during the mobilization of CO₂-bearing brines. Crossing isochores for co-genetic aqueous-carbonic and carbonic inclusions indicate fluid trapping conditions of 180–200 °C and 900–1000 bars. δ¹³C-isotopic ratios of gas trapped in fluid inclusions suggest an organic origin for CH₄, while the CO₂ is likely of inorganic origin.Basin modelling (1D) shows that the fault block structure of the respective reservoir has experienced an uplift of >1000 m since Late Cretaceous times.The fluid inclusion study allows us to, 1) model the evolution of the LSB and fluid evolution by distinguishing different fluid systems, 2) determine the appearance of CO₂ in the geological record and, 3) more accurately estimate burial and uplift events in individual parts of the LSB.     

Monitoring land motion due to natural gas extraction: Validation of the Intermittent SBAS (ISBAS) DInSAR algorithm over gas fields of North Holland,the Netherlands

The differential interferometric synthetic aperture radar (DInSAR) remote sensing technique has proven to be invaluable in the remote monitoring of earth surface movements associated with the extraction and geostorage (subsurface injection) of natural resources (water, oil, gas). However, a significant limitation of this technique is the low density and uneven coverage that may be achieved over vegetated rural environments. The Intermittent Small Baseline Subset (ISBAS) method, an amended version of the established SBAS algorithm, has been designed to improve coverage over rural, vegetated, land cover classes by allowing for the intermittent coherence that is predominant in such areas. In this paper we perform a validation of the ISBAS method over an area of gas production and geostorage in North Holland, the Netherlands. Forty-two ERS-2 (SAR) C-band images (1995–2000) and 63 ENVISAT (ASAR) C-band images (2003–2010) were processed using the ISBAS technique and the derived measurements enabled the identification of subsidence patterns in rural and urban areas alike. The dominant feature was an area of subsidence to the west of Alkmaar, attributed to natural gas production from the Bergermeer reservoir, where subsidence rates in the region of 3 mm/year were measured. Displacements derived using linear and non-linear surface deformation models were validated with respect to the first order system of levelling benchmarks which form the Amsterdam Ordnance Datum (NAP). It was established that ISBAS products were accurate to within 1.52 mm/year and 1.12 mm/year for the ERS and ENVISAT data sets respectively. Errors achieved were comparable to results using persistent scatterers interferometry (PSI) during a validation activity carried out in the European Space Agency Terrafirma project. These results confirm the capability of the ISBAS method to provide a more regular sampling of land motion measurements over gas fields that may be critically used in future to infer the properties of buried, fluid-filled, porous rock.     

Numerical investigation on the gas entrainment of ventilated partial cavity based on a multiscale modelling approach

Ventilated cavitation which is acknowledged as an efficient drag reduction technology for underwater vehicle is characterised by the very disparate length and time scales, posing great difficulty in the application of this technology. A multiscale numerical approach which integrates a sub-grid air entrainment model into the two-fluid framework is proposed in this paper to resolve the complex flow field created by ventilated cavity. Simulations have been carried out for the partially ventilated cavity underneath flat plate, with special efforts putting on understanding the gas entrainment at the cavity tail and the bubble dispersion process downstream. The flow parameters including the void fraction, the bubble velocity and the bubble size distributions in and downstream of the ventilated cavity are fully investigated. Comparisons between the numerical results with the experimental data are in satisfactory agreement, demonstrating the potential of the proposed methodology. The ventilation rate effect on the cavity shape and bubbly flow parameters are further investigated, obtaining the law of bubble dispersion and the bubble size evolution. This research not only provide a useful method for the investigation on the multiscale multiphase flow, but also give insight on understanding the combined drag reduction mechanism resulted from large-scale cavity and microbubbles.     

Source and accumulation of gas hydrate in the northern margin of the South China Sea

The northern South China Sea (NSCS) experienced continuous evolution from an active continental margin in the late Mesozoic to a stable passive continental margin in the Cenozoic. It is generally believed that the basins in the NSCS evolved as a result of Paleocene–Oligocene crustal extension and associated rifting processes. This type of sedimentary environment provides a highly favourable prerequisite for formation of large-scale oil- and gas–fields as well as gas hydrate accumulation. Based on numerous collected data, combined with the tectonic and sedimentary evolution, a preliminary summary is that primitive coal-derived gas and reworked deep gas provided an ample gas source for thermogenic gas hydrate, but the gas source in the superficial layers is derived from humic genesis. In recent years, the exploration and development of the NSCS oil, gas and gas hydrate region has provided a basis for further study. A number of 2D and 3D seismic profiles, the synthetic comparison among bottom simulating reflector (BSR) coverage characteristics, the oil-gas area, the gas maturity and the favourable hydrate-related active structural zones have provided opportunities to study more closely the accumulation and distribution of gas hydrate. The BSR has a high amplitude, with high amplitude reflections below it, which is associated with gas chimneys and pockmarks. The high amplitude reflections immediately beneath the BSR are interpreted to indicate the presence of free gas and gas hydrate. The geological and geochemical data reveal that the Cenozoic northern margin of the NSCS has developed coal-derived gas which forms an abundant supply of thermogenic gas hydrate. Deep-seated faults and active tectonic structures facilitate the gas migration and release. The thermogenic gas hydrate and biogenic gas are located at different depths, have a different gas source genesis and should be separately exploited. Based on the proven gas hydrate distribution zone, we have encircled and predicted the potential hydrate zones. Finally, we propose a simple model for the gas hydrate accumulation system in the NSCS Basin.     

Geochemistry,origin and accumulation of natural gases in the deepwater area of the Qiongdongnan Basin,South China Sea

The Qiongdongnan Basin, South China Sea has received huge thickness (>12 km) of Tertiary-Quaternary sediments in the deepwater area to which great attention has been paid due to the recent discoveries of the SS22-1 and the SS17-2 commercial gas fields in the Pliocene-Upper Miocene submarine canyon system with water depth over 1300 m. In this study, the geochemistry, origin and accumulation models of these gases were investigated. The results reveal that the gases are predominated by hydrocarbon gases (98%–99% by volume), with the ratio of C₁/C_1-5 ranging from 0.92 to 0.94, and they are characterized by relatively heavy δ¹³C₁ (−36.8‰ to −39.4‰) and δD_CH4 values (−144‰ to −147‰), similar to the thermogenic gases discovered in the shallow water area of the basin. The C_5-7 light hydrocarbons associated with these gases are dominated by isoparaffins (35%–65%), implying an origin from higher plants. For the associated condensates, carbon isotopic compositions and high abundance of oleanane and presence of bicadinanes show close affinity with those from the YC13-1 gas field in the shallow water area. All these geochemical characteristics correlate well with those found in the shales of the Oligocene Yacheng Formation in the Qiongdongnan Basin. The Yacheng Formation in the deepwater area has TOC values in the range of 0.4–21% and contains type II_b–III gas-prone kerogens, indicating an excellent gas source rock. The kinetic modeling results show that the δ¹³C₁ values of the gas generated from the Yacheng source rock since 3 or 4 Ma are well matched with those of the reservoir gases, indicating that the gas pool is young and likely formed after 4 Ma. The geologic and geochemical data show that the mud diapirs and faults provide the main pathways for the upward migration of gases from the deep gas kitchen into the shallow, normally pressured reservoirs, and that the deep overpressure is the key driving force for the vertical and lateral migration of gas. This gas migration pattern implies that the South Low Uplift and the No.2 Fault zone near the deepwater area are also favorable for gas accumulation because they are located in the pathway of gas migration, and therefore more attention should be paid to them in the future.