鄂西渝东区志留系流体封存箱的演化与天然气成藏

因鄂西渝东区志留系勘探程度甚低,长期以来志留系一直被视为烃源层或盖层.随着建深1井在志留系钻获高压工业气流,曾经的"思维定式"发生了改变.通过对志留系油气成藏条件及碳、氧、锶稳定同位素追踪流体行为轨迹的分析认为,该区志留系具有自源供烃的特点以及流体相对封闭的独特性,这是形成志留系下统龙马溪组、小河坝组以及志留系中统韩家...     

苏里格气田东部二叠系盒8段储层次生孔隙形成主控因素

苏里格气田东部下二叠统石盒子组8段是苏里格气田东部主要含气层位,其储集空间以各类次生孔隙为主。为明确次生孔隙控制因素,结合铸体薄片鉴定与定量统计、流体包裹体温度及成分分析等手段,对研究区盒8段储层次生孔隙特征及主控因素进行了系统研究。结果表明,苏里格气田东部盒8段储层次生孔隙的形成受有机酸溶蚀、深部热流体作用共同影响;平面分布受沉积相、构造及油气运移路径复合控制。沿构造鼻隆轴线方向、基底断裂结合部位与厚砂体叠合区附近次生孔隙最发育。     

华北平原冬麦田土壤CH4的吸收特征研究

利用静态箱/气相色谱(GC)法,对华北平原冬小麦拔节—成熟期间麦田土壤CH4气体通量进行了测定,得出华北平原典型冬麦田土壤是大气CH4的弱吸收汇。试验期间土壤CH4通量存在明显的季节变化和日变化,麦田拔节—成熟期间土壤CH4通量日平均值为-18.3μg.m-2.h-1,波动范围为-4.3~-24.4μg.m-2.h-1;在土壤CH4通量的日变化中,观测到麦田土壤在午间和夜间都有一个吸收峰,峰值出现的时间因生育期不同而有所不同。试验期间CH4通量日平均值与土壤温度关系不明显,而与土壤水分呈负相关(α=0.01);日变化中土壤CH4通量与地表温度的相关性较差,而与5 cm地温相关密切。麦田拔节—成熟期间土壤CH4通量日平均值随NH4 -N施用量的增加呈递减规律,农田秸秆还田后不利于土壤对CH4的吸收。     

太湖、洞庭湖野生青虾肌肉中有机氯农药的气相色谱-质谱法测定

使用气相色谱质谱技术测定了青虾肌肉组织中的8种有机氯农药.包括六氯苯、氯丹、滴滴涕(ΣDDTs)、艾氏剂、狄氏剂、异狄氏剂、七氯和灭蚁灵,对太湖和洞庭湖15个点位29组野士青虾样品的测定结果显示,青虾肌肉组织内残留的有机氯农药主要是六氯苯和滴滴涕,六氯苯含量为nd-13.2μg/kg(湿重),滴滴涕含量为0.790-5.82μg/kg(湿重),洞庭湖青虾肌肉中有机氯农药的含量略高于太湖青虾,两湖青虾肌肉残留有机氯农药在枯水期时的含量多数大于丰水期时的含量.     

南海北部琼东南海域活动冷泉特征及形成模式

近年来,活动冷泉的研究越来越受到关注.本文利用多波束数据、多道地震数据以及底质取样结果研究琼东南海域活动冷泉系统,分析活动冷泉的羽状流特征、海底地貌与底质特征以及流体活动构造特征.多波束水体数据上,观测到多个延伸高度超过750 m的气泡羽状流,海底流体活动非常强烈;多道地震上识别出麻坑、流体运移通道、气烟囱等流体渗漏相关的构造,与其他海域观测到的反射特征不同,羽状流的下方流体运移通道呈强振幅"串珠"反射;重力活塞取样在两个站位上获得浅表层块状天然气水合物.其中一个站位位于活动冷泉附近,天然气水合物赋存于海底以下8 m左右.基于以上三方面的数据,笔者提出了一个用于描述活动冷泉系统的形成模式,游离气通过气烟囱向上运移到达浅层,一部分在天然气水合物稳定带内形成天然气水合物,另一部分穿透天然气水合物稳定带到达海底,形成活动冷泉的羽状流.     

Experimental investigation of hydrate formation in water-dominated pipeline and its influential factors

Blockage in water-dominated flow pipelines due to hydrate reformation has been suggested as a potential safety issue during the hydrate production. In this work, flow velocity-dependent hydrate formation features are investigated in a fluid circulation system with a total length of 39 m. A 9-m section pipe is transparent consisted of two complete rectangular loops. By means of pressurization with gas-saturated water, the system can gradually reach the equilibrium conditions. The result shows tha...     

气体地球化学方法在震后趋势判断中的应用

初步讨论了气体地球化学方法在顺义4.5级地震震后趋势判断中的应用。研究表明，震中区土壤Hg释放量快速衰减；延庆龙庆峡水库翻花冒气异常释放的主要气体CH4来源于生物成因，而非地震前兆异常。据此认为顺义地震之后，首都圈构造活动水平没有增强的趋势，并于1996年12月27日提出未来15天内首都圈发生Ms≥5.0地震的可能性很小的预测意见。     

核磁共振测井在天然气勘探中的应用

核磁共振测井不仅能够测得孔隙度、渗透率等岩石物理信息，为储层评价提供科学依据，而且通过采用适当的探测手段和数据处理方法，可以探测到地层中天然气的信息，并能给出储层含气饱和度，而成为天然气勘探的一个重要方法，本文论述了核磁共振测井探测天然气的基本原理和数据处理方法，并对几个实例作了分析。     

Terbuthylazine and Deethylterbuthylazine in Rain and Surface Water – Determination by Enzyme Immunoassay and Gas Chromatography/Mass Spectrometry

Rain and surface water samples from Southern Germany were investigated from 1991 to 1995 for terbuthylazine and one of its major metabolites, deethylterbuthylazine. The concentrations observed were compared to the concentrations found for atrazine and deethylatrazine in the same water samples. Concentrations ranged from < 0.02 μg/L to 0.7 μg/L for terbuthylazine and from < 0.02 μg/L to 0.6 μg/L for deethylterbuthylazine, compared to concentrations of < 0.02 μg/L to 3 μg/L and < 0.02 μg/L to 0.5 μg/L for atrazine and deethylatrazine, respectively. The ratios of metabolite concentrations to parent compound concentrations were calculated for deethylterbuthylazine to terbuthylazine (DTR) and deethylatrazine to atrazine (DAR). In rain water, DTR of 0.8…3.0 and DAR of 0.3… 1.9 were determined with mean values of 0.9… 1.7 for DTR and 0.6…0.9 for DAR in the different years. The ratios increased during summer periods. The highest ratios were observed in samples from forest stands, showing that degradation of the herbicide has occurred during transport between the source and the sampling site. The DTR in rain water were about 50… 100% higher than the DAR. This indicates a higher degradation rate of terbuthylazine during atmospheric transport. In surface water, DTR of 0.3… 1.2 with mean values of 0.5…0.8 and DAR of 0.2…2.2 with mean values of 0.2… 1.3 were observed. The ratios increased from June to September.     

Mechanical behaviour of deep rock core samples from a seismically active gas field

This study concerns the laboratory testing of core samples from massive sedimentary rocks from an oil and gas field. The depth of extraction of the samples analysed varies between 1000 and 5000 metres. In all, 65 tests were performed, most of which included systematic measurement of acoustic activity during loading. The aim of the testing was to determine which types of fracture could occur in the rock matrix under field-stress conditions by examining in particular the relationship between confining pressure and the transition from brittle to ductile behaviour. The results of the laboratory tests are used to predict the occurrence of seismic activity resulting from the depletion of the gas reservoir which has been monitored during the last twenty years.