钻井液侵入海洋含水合物地层的一维数值模拟研究

本文以墨西哥湾水合物区域为背景,利用数值模拟方法研究了过平衡钻井条件下,当钻井液温度高于地层中水合物稳定温度时,水基钻井液侵入海洋含水合物地层的动态过程及其一般性规律.与侵入常规油气地层相比,耦合水合物分解和再形成是钻井液侵入海洋含水合物地层的主要特征.模拟结果表明,钻井液密度、温度和盐度都对侵入过程有影响.在一定条件下,钻井液密度越大,温度和含盐量越高,则钻井液侵入程度越深,热量传递越远,水合物分解程度越大.分解的水气在合适条件下又会重新形成水合物,影响了钻井液进一步侵入.而重新形成的水合物的饱和度甚至可能高于原位水合物饱和度,在井周形成一个"高饱水合物"环带.这一现象归因于钻井液侵入的驱替推挤、水合物分解的吸热以及地层传热的滞后等因素共同作用.在地层物性一定的条件下,高饱水合物环带的出现与否主要受钻井液温度和盐度控制.水合物分解以及高饱水合物环带的出现对井壁稳定和电阻率测井解释有很大影响.因此,为维护井壁稳定、确保测井准确和减少水合物储层伤害,就必须对钻井液密度、温度和滤失量进行严格控制,防止地层中的水合物大量分解.最好采用控制压力钻井(MPD)和深侧向测井方式,同时尽量选用低矿化度的含水合物动力学抑制剂的钻井液体系,采取低温快速循环方式.     

色谱法在稀土元素分离分析研究中的应用进展

稀土作为一种重要的不可再生资源,在各行业的应用正逐渐被人们所重视。色谱技术以其快速、高效、自动化程度高等优势已成为稀土元素分离分析的主要方法。文章总结了纸色谱法、薄层色谱法、气相色谱法、超临界色谱法、高效液相色谱法、毛细管电泳法等色谱法在稀土元素分离分析中的应用及研究概况。其中,纸色谱法因展开时间过长,分离效果不理想已很少应用;薄层色谱法因其操作方便、设备简单、显色容易等优点,可用于稀土元素分离分析的初步检测;气相色谱法由于对样品热稳定性的限制,以及因常用的β-二酮类稀土螯合物配体存在分辨率差和吸附等问题也很少应用;超临界色谱法在分离稀土元素络合物中分离效果较好,但是仪器难以普及,限制了技术的发展;高效液相色谱法因分离效率高、重复性好、自动化操作等优点已成为目前稀土元素分离分析的主要方法;毛细管电泳法具有高效、样品及试剂用量少、操作模式灵活等优点,在稀土元素分离分析方面更具有广阔的发展空间。     

利用包裹体中气体地球化学特征与源岩生气模拟实验探讨鄂尔多斯盆地靖边气田天然气来源

鄂尔多斯盆地上、下古生界地层包裹体气体与气藏中气体地球化学性质对比表明:上古生界气藏中气体与包裹体中气体地球化学性质相似,气藏中气体的地球化学性质能代表成藏初期气体的原始特征;而下古生界气藏中气体与包裹体中气体的地球化学性质差别很大,下古生界气藏中的气体与下古生界源岩模拟生成气体也有非常大的差别。因此,下古生界气藏中的气体不能代表来自下古生界源岩产生天然气。结合前人关于奥陶系源岩的模拟生成天然气、包裹体中气体以及靖边气田天然气的地球化学特征,提出来源于奥陶系的天然气应具有δ¹³C₁<-38‰、δ¹³C₂<-28‰的特征。下古生界地层包裹体中气体与气藏中气体地球化学性质对比表明,下古生界气田天然气乙烷碳同位素的变化范围也比甲烷碳同位素的变化范围大很多,乙烷碳同位素不适合作为判断靖边气田天然气来源的标准。在此基础上,以上古生界天然气甲烷碳同位素的平均值(-32.90‰)与下古生界δ¹³C₁<-38‰天然气甲烷碳同位素的平均值(-39.04‰)分别作为上、下古生界来源天然气甲烷碳同位素的界限值,通过简单计算认为靖边气田大约85%的天然气来源于上古生界煤系。     

Estimation of viscoelastic attenuation of real seismic data by use of ray tracing software: Application to the detection of gas hydrates and free gas

Analysis of P wave velocity profiles and seismic data recorded over the 2002 Hydratech cruise conducted in the Storegga region, North of Norway, has shown the existence of anomalies (a velocity decrease) in some layers of the medium. An elastic propagation model is not sufficient to explain clearly these anomalies, since the viscoelastic attenuation, represented by the quality factor Q_P, is sensitive to physical phenomena of geological media. The combination of the quality factor profile with the velocity profile leads to realistic explanations of these anomalies. In this article, we explain the procedure which we developed for determining the Q_P profile from the P wave velocity profile and the seismic data recorded during Hydratech cruise. Both the Q_P and velocity profiles indicate anomalies in the same layers. Based on previous studies, we interpret that these anomalies are being due to existence of gas hydrates and free gas within these layers.     

PAHs distribution in sediments associated with gas hydrate and oil seepage from the Gulf of Mexico

Six sediment samples collected from the Gulf of Mexico were analyzed. Total concentrations of the PAHs ranged from 52 to 403 ng g⁻¹ dry weight. The lowest PAH concentration without 5–6 rings PAHs appeared in S-1 sample associated with gas hydrate or gas venting. Moreover, S-1 sample had the lowest organic carbon content with 0.85% and highest reduced sulfur level with 1.21% relative to other samples. And, analysis of the sources of PAHs in S-1 sample indicated that both pyrogenic and petrogenic sources, converserly, while S-8, S-10 and S-11 sample suggested petrogenic origin. The distribution of dibenzothiophene, fluorine and dibenzofuran and the maturity parameters of triaromatic steranes suggested that organic matters in S-1 sample were different from that in S-8, S-10 and S-11 sample. This study suggested that organic geochemical data could help in distinguish the characteristic of sediment associated with gas hydrate or with oil seepage.     

Atmospheric Concentrations and Phase Partitioning of Polycyclic Aromatic Hydrocarbons in Izmir,Turkey

Ambient air polycyclic aromatic hydrocarbon (PAH) samples were collected at a suburban (n = 63) and at an urban site (n = 14) in Izmir, Turkey. Average gas‐phase total PAH (∑₁₄PAH) concentrations were 23.5 ng m^?3 for suburban and 109.7 ng m^?3 for urban sites while average particle‐phase total PAH concentrations were 12.3 and 34.5 ng m^?3 for suburban and urban sites, respectively. Higher ambient PAH concentrations were measured in the gas‐phase and ∑₁₄PAH concentrations were dominated by lower molecular weight PAHs. Multiple linear regression analysis indicated that the meteorological parameters were effective on ambient PAH concentrations. Emission sources of particle‐phase PAHs were investigated using a diagnostic plot of fluorene (FLN)/(fluorine + pyrene; PY) versus indeno[1,2,3‐cd]PY/(indeno[1,2,3‐cd]PY + benzo[g,h,i]perylene) and several diagnostic ratios. These approaches have indicated that traffic emissions (petroleum combustion) were the dominant PAH sources at both sites for summer and winter seasons. Experimental gas–particle partition coefficients (K_P) were compared to the predictions of octanol–air (K_OA) and soot–air (K_SA) partition coefficient models. The correlations between experimental and modeled K_P values were significant (r² = 0.79 and 0.94 for suburban and urban sites, respectively, p < 0.01). Octanol‐based absorptive partitioning model predicted lower partition coefficients especially for relatively volatile PAHs. However, overall there was a relatively good agreement between the measured K_P and soot‐based model predictions.     

The Influencing Factors of Escaped Radon from the Jiayuguan Fault Zone and Its Earthquake Reflecting Effect

The paper analyzes the radon data of nearly two decades on the Jiayuguan fault zone,discusses the main influencing factors,and puts forward the relationship between radon and air temperature,ground temperature and rainfall.We summarized the earthquake reflecting effect for ML≥5.0 about 400km within the Jiayuguan station,and reached the conclusion that it has better earthquake-reflecting ability before an earthquake,usually appearing as abnormal changes in sustained low value.By extracting the annual trend of radon in Jiayuguan station over many years,we discovered that the annual trend of radon has a close relationship with the seismic activity in surrounding areas,namely,if the annual variation of radon is larger,the seismic activity in surrounding areas is stronger;Otherwise,if the annual variation of radon is relatively stable,the seismic activity in the vicinity is weak.     

Geochemical Features of the Hubin Spring Gases from the Northern Caldera Lake of the Tianchi Volcano,Changbai Mountains

This paper deals with geochemical features of gas emitted from the Hubin Springs.The Hubin Springs zone,a strong thermal emission zone,is are locatedd at the north edge of the Tianchi caldera lake.Very young deposits with uncertain eruption date are found on the top area of the Tianwenfeng,which might have been formed in one of the recent eruptions or the Millennium Eruption.It is of significance to study the geochemistry features of the emitting gas from the Hubin Springs to understand the activities of the Tianchi Volcano.This paper systematically sampled and analyzed the gases emitted from the Hubin Springs and discussed their geochemistry features.The results show that there is a high content of deep derived gases,such as CO2,He,CH4 and Ar in Hubin Springs zone.The isotopic ratio of He lies between 4.18 and 5.95 Ra.The averaged mantle derived gas content calculated from the 4He/20Ne ratio and He content reaches 67.1%.All these show that the Hubin Springs are located on a special belt of deep gases released in high intensity and large scale.The spatial distribution of Helium isotope is characterized by concavity,showing that this special area may be related to the volcanic edifice.It is highly possible that the released gases represent the residual gas samples of the latest eruptions from the Tianchi Volcano.However more detailed studies are demanded.     

聊古1井在不同取水模式下气体观测效果的对比分析

为解决聊古1井断流问题,聊城地震水化试验站先后引进、开发了人工激发引流观测技术和潜水泵变频稳流抽水技术.对天然自流观测系统、人工激发引流观测系统和潜水泵变频稳流抽水观测系统等3种不同取水模式下产出的气体观测数据进行一致性分析.结果表明,人工激发引流观测系统下气体观测动态特征年变比较明显,潜水泵变频稳流抽水观测系统下气体观测动态特征与天然自流状态下的动态特征基本一致.     

青海木里冻土区水合物稳定带的特征研究——模拟与钻探结果对比

基于青海木里冻土区的气体组成、钻孔泥浆的温度测量数据等对该区水合物稳定带的顶底深度进行了模拟计算,并将计算结果与钻探揭示的水合物产出深度进行了对比.模拟计算的水合物顶深在148.8～122.7 m 间,底深在324.6～354.8 m间,水合物厚度在175.8～232.2 m间,钻探揭示水合物及其异常产出在133～39...