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21.
22.
Kazuo Abe 《Journal of Oceanography》2002,58(4):577-588
The relationship between dissolved cadmium (Cd) and phosphate (PO4) was examined at three stations in the subtropical area near the Ryukyu Islands in May 1999. Preformed PO4 was obtained using the Redfield ratio in order to separate the surface water and the other layers in this study area. Almost
0 μM (−0.043 μM to 0.094 μM) was estimated in the layers above 300 m and 250 m at Sts. 1 and 3 and at St. 2, respectively.
Up to these depths, water was considered to be uniform, and these layers were defined as the surface water in this study area.
In the surface water, the slopes of the regression lines of the Cd-PO4 plot were 0.162, 0.156, and 0.226 (nM/μM) at Sts. 1, 2, and 3, respectively, and these values were much closer to the estimated
regenerated ratio of Cd to PO4 from the Apparent Oxygen Utilization (AOU)-Cd/PO4 plots, which was 0.197 (nM/μM) in this study area. Below surface layers, the slopes of the Cd-PO4 plot changed to 0.371, 0.352, and 0.362 (nM//μM) at Sts. 1, 2, and 3, respectively. In the relationships between Cd and PO4, clear deviations or kinks were observed at three stations at a PO4 concentration of approximately 0.2 μM in the plot, which was attributable to the discontinuity of surface water and the other
layers across the North Pacific subtropical mode water. In studies of the interaction between surface water and biogenic particles
concerning the Cd/PO4 ratio, separate analyses of seawater (surface water and the other layers) should be carried out to obtain the individual
surface water ratio because the Cd/PO4 ratio in the surface water is expected to differ from that of the underlying water. Furthermore, the biological fractionation
of these constituents is based on the surface water ratio.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
23.
Graham P. Wilson Angela L. Lamb Melanie J. Leng Silvia Gonzalez David Huddart 《Estuarine, Coastal and Shelf Science》2005,64(4):685-698
Microfossil analysis (e.g. diatoms, foraminifera and pollen) represents the cornerstone of Holocene relative sea-level (RSL) reconstruction because their distribution in the contemporary inter-tidal zone is principally controlled by ground elevation within the tidal frame. A combination of poor microfossil preservation and a limited range in the sediment record may severely restrict the accuracy of resulting RSL reconstructions. Organic δ13C and C/N analysis of inter-tidal sediments have shown some potential as coastal palaeoenvironmental proxies. Here we assess their viability for reconstructing RSL change by examining patterns of organic δ13C and C/N values in a modern estuarine environment. δ13C and C/N analysis of bulk organic inter-tidal sediments and vegetation, as well as suspended and bedload organic sediments of the Mersey Estuary, U.K., demonstrate that the two main sources of organic carbon to surface saltmarsh sediments (terrestrial vegetation and tidal-derived particulate organic matter) have distinctive δ13C and C/N signatures. The resulting relationship between ground elevation within the tidal frame and surface sediment δ13C and C/N is unaffected by decompositional changes. The potential of this technique for RSL reconstruction is demonstrated by the analysis of part of an early Holocene sediment core from the Mersey Estuary. Organic δ13C and C/N analysis is less time consuming than microfossil analysis and is likely to provide continuous records of RSL change. 相似文献
24.
U–Th decay series isotopes, δ18O and Si measurements in the river estuarine waters and sediments of the polluted Hooghly estuary as well as the surface waters of the Bay of Bengal, its high salinity end member, are reported. Dissolved Si indicates that there are probably two mixing regimes, dissolved U behaviour is nonconservative and δ18O behaves conservatively in the overall estuarine region. Isotopes of reactive elements, viz. 234Th and 210Po, are removed from the estuarine waters in <2 days and <1 month, respectively, which is due to high suspended matter (30–301 mg l−1). 228Ra and 226Ra are profusely released into the estuarine waters in the low to mid-salinity regions.As expected, the opposite trend is observed in the case of estuarine sediments and suspended matter. Reactive isotopes of Th, 210Pb and 210Po are enriched, whereas Ra isotopes are depleted with respect to their parent nuclides in the estuarine sediments and suspended matter. 232Th/Al ratio appears well suited to study the distribution and mixing of the bed load sediments of the Ganga–Brahmaputra (G–B) and the Hooghly rivers with those from other rivers on the Bay of Bengal floor. 相似文献
25.
用m-氨基苯甲酸作原料,经溴代、重氮化、还原脱氨、酰氯化和酯化反应等步骤,合成了六种新型的三溴苯甲酸的溴代和非溴代芳酯,即;双(2,4,6-三溴苯甲酸)-2',3',5',6'-四溴-1',4'-苯二酯,2,4,6-三溴苯甲酸-2',3',4',5',6'-五溴苯酯,2,4,6-三溴苯甲酸-2',4',6'-三溴苯酯,2,4,6-三溴苯甲酸-4'-溴苯酯,2,4,6-三溴苯甲酸-4'-甲基苯酯和2,4,6-三溴苯甲酸苯酯.通过对产物中碳、氢、溴元素的定量分析以及红外吸收光谱和氢核磁共振谱的研究,验证了合成产物的结构。 相似文献
26.
27.
以苯酚和4—溴苯甲酸为原料,合成一种尚未见文献记载的新化合物——4—溴苯甲酸—2,3,4,5,6—五溴苯酯,用无水三氯化铝催化苯酚的全溴化。此产物可望在阻燃剂方面得到应用。 相似文献
28.
北京市基础测绘技术规程的探讨 总被引:1,自引:1,他引:0
分析了规程与现行相关法律、法规和标准的关系,探讨了北京市基础测绘技术规程的内容,介绍了其创新点和应用情况。通过分析介绍,该地方标准统一了北京市基础测绘的技术标准,规范了基础测绘成果,有利于实现测绘信息资源的共享和有效利用。 相似文献
29.
通过对塔东地区古城4井上寒武统和中、上奥陶统碳酸盐岩围岩及充填物的碳、氧、锶同位素地球化学和流体包裹体成分的对比研究表明,充填于中、上奥陶统和上寒武统的流体分属于2个不同来源的流体体系。充填于中、上奥陶统灰岩裂缝中方解石脉的w(87Sr)/w(86Sr)介于0.7084~0.7088,它与早奥陶世海水的w(87Sr)/w(86Sr)相近;流体体系为CH4-H2O体系;充填物与围岩间具有明显的碳、氧同位素差异,表明上部流体体系中的流体来自于奥陶系地层本身。上寒武统白云岩裂缝中方解石脉的w(87Sr)/w(86Sr)为0.7138,明显地高于同时代海水的锶同位素值;流体体系为CO2-H2O体系;下部流体体系中的流体为外来富锶流体。上、下流体体系间互不连通暗示着上寒武统地层具有相对较好的保存条件。 相似文献
30.
Ordovician fracture-cavity carbonate reservoir beds are the major type of producing formations in the Tahe oilfield, Tarim Basin. The seismic responses of these beds clearly changes depending on the different distance of the fracture-cavity reservoir bed from the top of the section. The seismic reflection becomes weak or is absent when the fracture-cavity reservoir beds are less than 20 ms below the top Ordovician. The effect on top Ordovician reflection became weaker with deeper burial of fracture-cavity reservoir beds but the developed deep fracture-cavity reservoir beds caused stronger reflection in the interior of the Ordovician. This interior reflection can be divided into strong long-axis, irregular and bead string reflections, and was present 80 ms below the top Ordovician. Aimed at understanding reflection characteristics, the spectral decomposition technique, which uses frequency to "tune-in" bed thickness, was used to predict Ordovician fracture-cavity carbonate formations in the Tahe oilfield. Through finely adjusting the processing parameters of spectral decomposition, it was found that the slice at 30 Hz of the tuned data cube can best represent reservoir bed development. Two large N-S-trending strong reflection belts in the mid-western part of the study area along wells TK440- TK427-TK417B and in the eastern part along wells TK404-TK409 were observed distinctly on the 30 Hz slice and 4-D time-frequency data cube carving. A small N-S trending reflection belt in the southern part along wells T403-TK446B was also clearly identified. The predicted reservoir bed development area coincides with the fracture-cavities connection area confirmed by drilling pressure testing results. Deep karst cavities occur basically in three reservoir bed-development belts identified by the Ordovician interior strong reflection. Spectral decomposition proved to be a useful technique in identifying fracture-cavity reservoir beds. 相似文献