Determination of picomolar iron in seawater by double Mg(OH)2 precipitation isotope dilution high-resolution ICPMS

A low-blank pre-concentration procedure is described for the analysis of picomolar iron (Fe) in seawater by isotope dilution high-resolution inductively coupled plasma mass-spectrometry (HR-ICPMS). The procedure uses a two-step Mg(OH)₂ co-precipitation procedure to extract Fe from a 50 ml seawater sample into a 100 μl 4% nitric acid (HNO₃) solution followed by HR-ICPMS measurement. The high pre-concentration ratio ( 500:1) achieved by the procedure minimizes the Fe blank due to ICPMS instrumental Fe background and results in a detection limit of  2 pM and a precision of  4% at the 50 pM Fe level. The measurement of a low-Fe seawater sample spiked with gravimetric Fe standard shows that the method can clearly distinguish 0.01 nM Fe from 0.02 nM Fe in seawater with high accuracy. The method is demonstrated by the analysis of dissolved Fe in the equatorial Pacific Ocean.     

多源信息融合在维西-兰坪矿产勘查中的应用

运用遥感图像处理软件ERDAS中的图像增强方法,分析ETM+遥感数据,提取与金属矿化有关的异常信息,将化探异常图像和遥感信息叠加进行相关异常信息与成矿的关系研究,对本区找矿预测具有较好的指导作用。     

滇东南老寨湾金矿化探异常查证与找矿方向

运用化探测量、X萤光分析仪现场检测、地质检查等多种找矿方法,获得含金工业品位的找矿信息;发现具工业价值的金矿体并建立该类矿床找矿模型。     

双频激电法在云南禄劝新发铜矿区的应用

以禄劝新发铜矿区为例,研究在山区运用双频激电法进行矿产远景调查的效果。结果表明:在交通不便、自然条件差的山区,双频激电法具有轻便、快速等优点。找矿效果理想,与地质、化探结果吻合,为双频激电法研究提供了一个可供参考的实例。     

天津市中心城区地下空间资源开发利用适宜性评价探讨

探讨了天津市中心城区的地下空间资源开发利用评价,提出了地下空间资源开发利用评价方法。分析了天津市中心城区的地质背景,论证选取了适宜的评价因子,结合目前中心城区地下空间的开发利用现状,对中心城区地下空间资源的开发利用进行了适宜性分区评价,为将来天津市中心城区地下空间资源的合理开发利用提出了建议。     

主流海表风场资料在舟山群岛近海的性能评估

再分析风场资料已广泛应用于我国舟山群岛海域可再生能源评估、海洋灾害预防决策以及港口运维和船舶运输等涉海发展领域,然而不同业务机构所提供的再分析数据在舟山近海的性能表现不一,严重阻碍了此类数据的有效应用。基于2018年全年单点浮标观测资料,综合评价了舟山群岛近海面(10 m)风场的长期变化趋势,并利用误差分析和风玫瑰图等统计工具对6种主流海表风场再分析资料,包括:ECMWF第五代全球大气再分析数据(the 5th generation ECMWF atmospheric reanalysis,ERA5)、NECP第二版全球高分辨率再分析数据(climate forecast system version 2,CFSv2)、美国宇航局物理海洋学分布存档中心的多卫星融合资料(cross-calibrated multi-platform,CCMP)、日本55年再分析数据(Japanese 55-year reanalysis,JRA-55)、第二版现代研究与应用回顾性分析数据(modern-era retrospective analysis for research and applications version 2,MERRA-2)和ECMWF哥白尼大气监测服务再分析数据(the Copernicus Atmosphere Monitoring Service,CAMS)在时间变化特征上进行了对比与评估。研究表明:在综合性能方面,ERA5对风场的再现能力最优,其次为JRA-55;在要素可信度方面,ERA5对风速的再现情况相对较优,而CFSv2的风向再现情况较好;风场产品在不同季节的模拟能力有所差异;不同风场产品在不同风速区间的重构能力也有所不同;在全年风向分布方面,各再分析资料都存在显著的东向偏差。研究结果为不同应用场景下风场资料的选取提供评估依据,并为进一步开发适用于舟山群岛近海的高精度长周期风场数据产品奠定基础。     

中国科技资源配置效率测度及其时空格局演变特征(英文)

According to the connotation and structure of science and technology resources and some relevant data of more than 286 cities at prefecture level and above during 2001–2010, using modified method—Data Envelopment Analysis(DEA), science and technology(ST) resource allocation efficiency of different cities in different periods has been figured out, which, uncovers the distributional difference and change law of ST resource allocation efficiency from the time-space dimension. Based on that, this paper has analyzed and discussed the spatial distribution pattern and evolution trend of ST resource allocation efficiency in different cities by virtue of the Exploratory Spatial Data Analysis(ESDA). It turned out that:(1) the average of ST resource allocation efficiency in cities at prefecture level and above has always stayed at low levels, moreover, with repeated fluctuations between high and low, which shows a decreasing trend year by year. Besides, the gap between the East and the West is widening.(2) The asymmetrical distribution of ST resource allocation efficiency presents a spatial pattern of successively decreasing from Eastern China, Central China to Western China. The cities whose ST resource allocation efficiency are at higher level and high level take on a cluster distribution, which fits well with the 23 forming urban agglomerations in China.(3) The coupling degree between ST resource allocation efficiency and economic environment assumes a certain positive correlation, but not completely the same. The differentiation of ST resource allocation efficiency is common in regional development, whose existence and evolution are directly or indirectly influenced by and regarded as the reflection of many elements, such as geographical location, the natural endowment and environment of ST resources and so on.(4) In the perspective of the evolution of spatial structure, ST resource allocation efficiency of the cities at prefecture level and above shows a notable spatial autocorrelation, which in every period presents a positive correlation. The spatial distribution of ST resource allocation efficiency in neighboring cities seems to be similar in group, which tends to escalate stepwise. Meanwhile, the whole differentiation of geographical space has a diminishing tendency.(5) Viewed from LISA agglomeration map ofST resource allocation efficiency in different periods, four agglomeration types have changed differently in spatial location and the range of spatial agglomeration. And the continuity of ST resource allocation efficiency in geographical space is gradually increasing.     

湿地公园小品设计原则分析

湿地公园小品即指使用于栖息地保护的湿地场所,也能为人类提供某种活动方式,包含科普教育、自然风景观光、休闲散步和观鸟等内容的设施或建筑。它是湿地景观中的一种新的文化类型,其重要作用正日益被人们所认识。从生态保护、功能齐全、公众参与、人性化、文化传播、节能减材等方面分析了湿地公园小品的设计原则,为今后湿地公园小品的设计提供参考。     

梅雨锋云系的模态研究Ⅱ：出现频率及转换特点

基于经验正交函数（EOF）分解方法提取的1998～2008年梅雨活跃期共16次过程的梅雨锋云系主导模态,讨论了这些主导模态的发生频率、维持时间及相互转换特征。结果表明,在16个梅雨活跃期内,云系的第1主导模态正相位出现的频率最高,并且在4个活跃期内作为首次出现模态率先出现;第5模态正位相的出现频率最低,且该模态多数伴随其他模态一同出现,为过渡模态。统计发现,各主导模态的维持时间并不相同,其中第2模态负位相持续时间最长,为81 h;第5模态正位相的最大持续时间最短,仅为18 h;第6模态负位相的平均持续时间最长。对不同主导模态转换方向和频次的计算表明,各个位相的模态最多（最少）向9种（3种）（含正负位相）其他模态进行转换。除第6模态负位相和第5模态负位相向其他模态的转化具有较好的方向性外,其他模态间的相互转换多表现出随机性特征。其中,第6模态负位相在超过半数的情况下向第5模态负位相转换,而第5模态负位相则多向第3模态正位相和第1模态负位相进行转换。     

1961-2010年辽宁省高温日数和高温热浪特征分析

利用1961-2010年辽宁省52个气象站日最高气温资料,分析辽宁地区高温日数及热浪的分布特征和变化趋势,结果表明：辽宁省区域年平均高温日数为7.72 d/ a。辽宁高温日数呈东少西多的空间分布,沿海地区较少甚至部分地区无高温情况出现。高温日出现最多的朝阳站,为26.48 d/ a。从20世纪60年代开始,高温日数呈缓慢增加趋势,其中2000年为有气象记录以来高温日最多的年份。热浪也呈东少西多的分布特征,热浪最多的朝阳站发生频次为2.90次/ a。辽宁省以持续3-5 d的轻度热浪为主,占86.27 %,中度热浪占12.58 %,超过10 d的重度热浪占1.14 %,仅有喀左、北票和羊山地区发生过持续10 d以上的重度热浪。