中国东部主要入海河流河口区地球化学特征：理化指标与水溶态元素浓度

河水理化性质和元素组成特征直接影响到水体利用功能,入海河流元素输送量对近岸海洋生态环境具有重要影响。在中国东部33条入海河流下游河段或河口区布设了水地球化学调查点,分别在2007年夏季(丰水期)、2007年底—2008年初(枯水期)采样并测定了河水酸碱度、电导率值以及溶解态常量和微量元素浓度。研究表明,多数北方河流水体酸碱度、电导率值以及常量元素浓度高于南方河流,与中国土壤及其常量元素组成的南北分带相吻合,反映了我国南北气候分带对河水地球化学特征的控制作用,推断少数河流酸碱度、电导率和常量元素浓度的异常分布与海水混合作用、人为污染等作用有关;部分河流水体中微量元素浓度背离于区域正常浓度,其原因一是与区域地球化学背景有关,二是与城市污染影响有关,通过对比部分城市上、下游水体元素浓度证实城市污染的影响;研究认为丰水期易溶元素Na、Ca、K、Zn、Se浓度较低反映了大量降水的稀释效应,而丰水期河水Al、REE、Fe、Pb、Tl等元素浓度明显高于枯水期,主要与丰水期暴雨形成的地面径流携带大量胶体颗粒进入地表水有关。     

Fault on–off versus coseismic fluids reaction

The fault activation （fault on） interrupts the enduring fault locking （fault off） and marks the end of a seismic cycle in which the brittle-ductile transition （BDT） acts as a sort of switch. We suggest that the fluid flow rates differ during the different periods of the seismic cycle （interseismic, pre-seismic, coseismic and post-seismic） and in particular as a function of the tectonic style. Regional examples indicate that tectonic-related fluids anomalies depend on the stage of the tectonic cycle and the tectonic style. Although it is difficult to model an increasing permeability with depth and several BDT transitions plus independent acquicludes may occur in the crust, we devised the simplest numerical model of a fault constantly shearing in the ductile deeper crust while being locked in the brittle shallow layer, with variable homogeneous permeabilities. The results indicate different behaviors in the three main tectonic settings. In tensional tectonics, a stretched band antithetic to the normal fault forms above the BDT during the interseismic period. Fractures close and fluids are expellecl during the coseismic stage. The mechanism reverses in compressional tectonics. During the interseismic stage, an over-compressed band forms above the BDT. The band dilates while rebounding in the coseismic stage and attracts fluids locally. At the tip lines along strike-slip faults, two couples of subvertical bancls show different behavior, one in dilationJcompression and one in compressionJdilation. This deformation pattern inverts during the coseismic stage. Sometimes a pre-seismic stage in which fluids start moving may be observed and could potentially become a precursor.     

http://www.sciencedirect.com/science/article/pii/S1674987114000449

We review petrologic observations of reaction textures from high-grade rocks that suggest the passage of fluids with variable alkali activities. Development of these reaction textures is accompanied by regular compositional variations in plagioclase, pyroxenes, biotite, amphibole and garnet. The textures are interpreted in terms of exchange and net-transfer reactions controlled by the K and Na activities in the fluids. On the regional scale, these reactions operate in granitized, charnockitized, syenitized etc. shear zones within high-grade complexes. Thermodynamic calculations in simple chemical systems show that changes in mineral assemblages, including the transition from the hydrous to the anhydrous ones, may occur at constant pressure and temperature due only to variations in the H2O and the alkali activities. A simple procedure for estimating the activity of the two major alkali oxides, K2O and Na2O, is imple- mented in the TWQ software. Examples of calculations are presented for well-documented dehydration zones from South Africa, southern India, and Sri Lanka. The calculations have revealed two end-member regimes of alkalis during specific metamorphic processes： rock buffered, which is characteristic for the precursor rocks containing two feldspars, and fluid-buffered for the precursor rocks without K-feldspar. The observed reaction textures and the results of thermodynamic modeling are compared with the results of available experimental studies on the interaction of the alkali chloride and carbonate-bearing fluids with metamorphic rocks at mid-crustal conditions. The experiments show the complex effect of alkali activities in the fluid phase on the mineral assemblages. Both thermodynamic calculations and experiments closely reproduce paragenetic relations theoretically predicted by D.S. Korzhinskii in the 1940s.     

Height prediction of water flowing fractured zones based on BP artificial neural network

Factures caused by deformation and destruction of bedrocks over coal seams can easily lead to water flooding (inrush) in mines, a threat to safety production. Fractures with high hydraulic conductivity are good watercourses as well as passages for inrush in mines and tunnels. An accurate height prediction of water flowing fractured zones is a key issue in today's mine water prevention and control. The theory of leveraging BP artificial neural network in height prediction of water flowing fractured zones is analysed and app-lied in Qianjiaying Mine as an example in this paper. Per the comparison with traditional calculation results, the BP artificial neural network better reflects the geological condi-tions of the research mine areas and produces more objective, accurate and reasonable results, which can be applied to predict the height of water flowing fractured zones.     

太子河本溪城区段河流水生态系统健康评价

太子河作为本溪的主要河流,是本溪工业、农业、生活的主要水源,为了更好的了解太子河本溪城区段的水体情况,以太子河本溪城区段流域为研究对象,基于2017年的平水期（4月）、丰水期（8月）、枯水期（11月）18个监测断面的监测数据,结合太子河本溪城区段的实际情况和特点,利用层次分析法的评价指标体系,对太子河本溪城区段进行水生态系统健康评价。通过比较分析,最终以平水期的评价结果为主,丰水期和枯水期的评价结果为辅。结果表明：仅有22%的监测断面处于健康状态、56%的监测断面处于亚健康状态、22%的监测断面处于一般状态,说明太子河本溪城区段大部分流域处于亚健康状态,水生态系统退化,需要加强管理和治理保护。     

Prediction of Flowing Bottomhole Pressures for Two-Phase Coalbed Methane Wells

A method is proposed to predict the flowing bottomhole pressures(FBHPs)for two-phase coalbed methane(CBM)wells.The mathematical models for both gas column pressure and two-phase fluid column pressure were developed based on the well liquid flow equation.FBHPs during the production were predicted by considering the effect of entrained liquid on gravitational gradients.Comparison of calculated BHPs by Cullender-Smith and proposed method was also studied.The results show that the proposed algorithm gives the desired accuracy of calculating BHPs in the lowproductivity and low-pressure CBM wells.FBHP is resulted from the combined action of wellhead pressure,gas column pressure and fluid column pressure.Variation of kinetic energy term,compressibility and friction factors with depth increments and liquid holdup with velocity should be considered to simulate the real BHPs adequately.BHP is a function of depth of each column segment.The small errors of less than 1.5%between the calculated and measured values are obtained with each segment within 25 m.Adjusting BHPs can effectively increase production pressure drop,which is beneficial to CBM desorption and enhances reservoir productivity.The increment of pressure drop from 5.37 MPa2 to 8.66 MPa2 leads to an increase of CBM production from 3270 m3/d to 6700 m3/d and is attributed to a decrease in BHP from 2.25 MPa to 1.33 MPa.     

A numerical study on the occurrence of flowing wells in the discharge area of basins due to the upward hydraulic gradient induced wellbore flow

The occurrence of flowing wells in basins has been found to be closely related to the discharge area with an upward hydraulic gradient. Unfortunately, previous studies on upward gradient induced wellbore flow with equaling total inflow (Q_in) in the deep and total outflow (Q_out) in the shallow could not explain the occurrence of flowing wells. By representing wells using the MNW2 Package imbedded in MODFLOW 2005, we obtain the exchange of groundwater between the aquifer and the well in the discharge area of 3D unit basins and identify three scenarios: Q_in = Q_out, Q_in > Q_out > 0 and Q_in > Q_out = 0. The relationship of Q_in > Q_out well explains why flowing wells only develop in a limited part of the discharge area. Sensitivity analysis shows that well location, water table undulation, and basin length–depth ratio do not change the profile of the ratio of cumulative flow rate in a flowing well to total inflow (Q_v/Q_in) versus the relative elevation in the inflow segment, z_in*, but could significantly change the length of the inflow segment; well depth could change both the length of the inflow segment and the profile of Q_v/Q_in versus z_in*. Based on the numerical results in homogeneous and isotropic basins with different basin length–depth ratios in the current study, the ratio of inflow in the lower half part of a flowing well to the total inflow is found to be at least 67% and could be close to 100%, indicating that water at the outlets of flowing wells with long open sections is mainly from the deep part of the well.     

含瓦斯煤样横向变形与瓦斯流动特性耦合关系试验研究

以二次成型煤样为研究对象,运用自行研制开发的含瓦斯煤热-流-固耦合三轴伺服渗流试验装置对含瓦斯煤样三轴加载过程中横向变形和与瓦斯流动特性的耦合关系进行了试验研究。结果表明：弹性力学定义的泊松比不能准确表征含瓦斯煤样的横纵应变特性,其关系可用二次函数表征;在预加载荷引起的横压向应变恢复阶段瓦斯流动速度变化呈先急剧降低再缓慢增加特性;在横向应变逐渐向扩张应化转变阶段,煤样内部的瓦斯流动速度呈单调缓慢增加趋势,且存在一个内部结构临界状态点使煤样内瓦斯流动速度最小;含瓦斯煤样处于横向压应变状态起始时的瓦斯流动速度要大于处于横向应变呈扩张状态末端时的瓦斯流动速度。     

A new jadeitite jade locality (Sierra del Convento, Cuba): first report and some petrological and archeological implications

A new jadeitite jade locality has been discovered in the serpentinite-matrix subduction mélange of the Sierra del Convento (eastern Cuba) in a context associated with tectonic blocks of garnet-epidote amphibolite, tonalitic–trondhjemitic epidote gneiss, and blueschist. The mineral assemblages of jadeitite jade and jadeite rocks are varied and include combinations of jadeite, omphacite, albite, paragonite, analcime, clinozoisite-epidote, apatite, phlogopite, phengite, chlorite, glaucophane, titanite, rutile, zircon, and quartz formed during various stages in their P–T evolution. Field relationships are obscure, but some samples made almost exclusively of jadeite show evidence of crystallization from fluid in veins. In one of these samples studied in detail jadeite shows complex textural and chemical characteristics (including oscillatory zoning) that denote growth in a changing chemical medium. It is proposed that interaction of an Al–Na rich fluid with ultramafic rocks produced Al–Na–Mg–Ca fluids of varying composition. Episodic infiltration of these fluids, as a result of episodic opening of the veins, developed oscillatory zoning by direct precipitation from fluid and after reaction of fluid with pre-existing jadeite. The latest infiltrating fluids were richer in Mg–Ca, favouring the formation of omphacite and Mg–Ca rich jadeite in open voids and the replacement of earlier jadeite by fine-grained omphacite + jadeite at 550–560°C. This new occurrence of jadeite in Cuba opens important perspectives for archeological studies of pre-Columbian jade artifacts in the Caribbean region.     

四川兴文二叠纪风暴稳流场颗粒运动的分形研究

颗粒是一种分形介质,其尺寸大到若干米,小到若干埃。通过颗粒系统各种密度函数的研究,可以得到微观方面—分形颗粒的粒径分布分维对系统的影响,对表征颗粒流动性具有重要意义。根据分形介质DLK反映模型的一级反映扩散方程,把布朗颗粒的运动及热力学理论推广到风暴流场,得到Γ(t)-D模型,此模型把颗粒径的分布分维和颗粒的空间坐标(或位移)、密度(或浓度)等总体微观统计特征,及经过空间某一位置的速度、粒径随时间的动态变化行为和颗粒流动的不均匀空间分布结构特征等丰富的信息为作我们研究颗粒运动提供重要的理论依据。