Since the 1990s, interest in the magmatic fluids and their relation to mineralization has been re-aroused[1—6]. Studies on stable isotopes of low-sulfidation deposits commonly show the predominance of meteoric water[7]. Paradoxically, the evidence for me… 相似文献
We present results of laboratory experiments to study the behavior of liquids moving in unsaturated wide-aperture fractures. A 5-mm-thick glass plate cut with a 1.7-mm aperture was used as a fractured rock analog to study behavior of film and capillary droplet flow modes. Flow rates ranged between 0.6 and 6.0 ml/min. Variability in the ambient barometric pressure, resulting from weather conditions, seemed to play a role in the natural selection of flow mode. For droplet mode, constant input conditions resulted in highly variable transport properties within the fracture. The advancing meniscus exhibited a dynamic contact angle that was a function of the droplet speed and much larger than the static contact angle. Flow rate was reduced due to the larger contact angle. Analytical expressions for droplet velocity and flow capacity are presented as a function of the dynamic rather than the static contact angle. 相似文献
The Quaternary Takidani Granodiorite (Japan Alps) is analogous to the type of deep-seated (3–5 km deep) intrusive-hosted fracture network system that might support (supercritical) hot dry/wet rock (HDR/HWR) energy extraction. The I-type Takidani Granodiorite comprises: porphyritic granodiorite, porphyritic granite, biotite-hornblende granodiorite, hornblende-biotite granodiorite, biotite-hornblende granite and biotite granite facies; the intrusion has a reverse chemical zonation, characterized by >70 wt% SiO2 at its inferred margin and <67 wt% SiO2 at the core. Fluid inclusion evidence indicates that fractured Takidani Granodiorite at one time hosted a liquid-dominated, convective hydrothermal system, with <380°C, low-salinity reservoir fluids at hydrostatic (mesothermal) pressure conditions. ‘Healed’ microfractures also trapped >600°C, hypersaline (35 wt% NaCleq) fluids of magmatic origin, with inferred minimum pressures of formation being 600–750 bar, which corresponds to fluid entrapment at 2.4–3.0 km depth. Al-in-hornblende geobarometry indicates that hornblende crystallization occurred at about 1.45 Ma (7.7–9.4 km depth) in the (marginal) eastern Takidani Granodiorite, but later (at 1.25 Ma) and shallower (6.5–7.0 km) near the core of the intrusion. The average rate of uplift across the Takidani Granodiorite from the time of hornblende crystallization has been 5.1–5.9 mm/yr (although uplift was about 7.5 mm/yr prior to 1.2 Ma), which is faster than average uplift rates in the Japan Alps (3 mm/yr during the last 2 million years). A temperature–depth–time window, when the Takidani Granodiorite had potential to host an HDR system, would have been when the internal temperature of the intrusive was cooling from 500°C to 400°C. Taking into account the initial (7.5 mm/yr) rate of uplift and effects of erosion, an optimal temperature–time–depth window is proposed: for 500°C at 1.54–1.57 Ma and 5.2±0.9 km (drilling) depth; and 400°C at 1.36–1.38 Ma and 3.3±0.8 km (drilling) depth, which is within the capabilities of modern drilling technologies, and similar to measured temperature–depth profiles in other active hydrothermal systems (e.g. at Kakkonda, Japan). 相似文献
Minor granulites (believed to be pre-Triassic), surrounded by abundant amphibolite-facies orthogneiss, occur in the same region as the well-documented Triassic high- and ultrahigh-pressure (HP and UHP) eclogites in the Dabie–Sulu terranes, eastern China. Moreover, some eclogites and garnet clinopyroxenites have been metamorphosed at granulite- to amphibolite-facies conditions during exhumation. Granulitized HP eclogites/garnet clinopyroxenites at Huangweihe and Baizhangyan record estimated eclogite-facies metamorphic conditions of 775–805 °C and ≥15 kbar, followed by granulite- to amphibolite-facies overprint of ca. 750–800 °C and 6–11 kbar. The presence of (Na, Ca, Ba, Sr)-feldspars in garnet and omphacite corresponds to amphibolite-facies conditions. Metamorphic mineral assemblages and P–T estimates for felsic granulite at Huangtuling and mafic granulite at Huilanshan indicate peak conditions of 850 °C and 12 kbar for the granulite-facies metamorphism and 700 °C and 6 kbar for amphibolite-facies retrograde metamorphism. Cordierite–orthopyroxene and ferropargasite–plagioclase coronas and symplectites around garnet record a strong, rapid decompression, possibly contemporaneous with the uplift of neighbouring HP/UHP eclogites.
Carbonic fluid (CO2-rich) inclusions are predominant in both HP granulites and granulitized HP/UHP eclogites/garnet clinopyroxenites. They have low densities, having been reset during decompression. Minor amounts of CH4 and/or N2 as well as carbonate are present. In the granulitized HP/UHP eclogites/garnet clinopyroxenites, early fluids are high-salinity brines with minor N2, whereas low-salinity fluids formed during retrogression. Syn-granulite-facies carbonic fluid inclusions occur either in quartz rods in clinopyroxene (granulitized HP garnet clinopyxeronite) or in quartz blebs in garnet and quartz matrices (UHP eclogite). For HP granulites, a limited number of primary CO2 and mixed H2O–CO2(liquid) inclusions have also been observed in undeformed quartz inclusions within garnet, orthopyroxene, and plagioclase which contain abundant, low-density CO2±carbonate inclusions. It is suggested that the primary fluid in the HP granulites was high-density CO2, mixed with a significant quantity of water. The water was consumed by retrograde metamorphic mineral reactions and may also have been responsible for metasomatic reactions (“giant myrmekites”) occurring at quartz–feldspar boundaries. Compared with the UHP eclogites in this region, the granulites were exhumed in the presence of massive, externally derived carbonic fluids and subsequently limited low-salinity aqueous fluids, probably derived from the surrounding gneisses. 相似文献
Abstract. The Ta'ergou tungsten deposit in Gansu province, northwestern China, is located in the western part of the North Qilian Caledonian orogen, and consists of scheelite skarn bodies and wolframite quartz veins. The tungsten‐bearing skarn developed by the replacement of carbonate layers intercalated in the Precambrian schist and amphibolite whereas wolframite‐quartz ore veins developed along a group of fractures that cut through horizontal skarns. The Ta'ergou tungsten deposit is genetically related to the Caledonian Yeniutan granodiorite intrusion and occurs ca. 500 m wide in the exo‐contact zone 300 ~ 500 m apart from the intrusion. The granodiorite displays a lower grade of differentiation, low content of SiO2 and high contents of mafic components. There are three types of fluid inclusions in the wolframite‐quartz vein systems, i. e. aqueous, CO2‐H2O and CO2‐rich. The homogenization temperature of aqueous inclusion ranges from 140 to 380d?C and their salinities from 6.4 to 17.4 equivalent wt% NaCl. Laser Raman spectroscopy shows that the inclusions contain a relatively high content of CO2. The δ34S values of skarn type sulfides range from +8.1 to +12.7 per mil and those of quartz vein sulfides from +9.3 to +14.9 per mil, similar to sulfides of the granodiorite with from +6.0 to +11.7 per mil. The δ18O values of quartz are between +10.5 and +13.3 per mil and those of wolframite between +3.4 and +5.1 per mil. The δ18O water values of ore forming fluids range from +0.6 to +6.4 per mil and suggest the mixture of magmatic fluids with meteoric water formed the ore‐forming fluids. It has been proved that Precambrian strata in the west sector of North Qilian region are enriched in tungsten. We propose the strata were remelted to be tungsten‐granitoid during subduction. The polymetallic tungsten was gradually accumulated into the roof pendants of the granite intrusion by fractional crystallization and then was deposited by hydrothermal fluids during metasomatism and infilling along fractures. On the other hand, the granite intrusion also acted as “heating machine” to make hydrothermal fluids leach out the metals from Precambrian strata and these metals joined the ore‐forming hydrothermal system. 相似文献
Eighty-two core samples were collected from the Spring Valley #1 well which penetrates the Upper Carboniferous strata in the Late Devonian–Early Permian Maritimes Basin. The strata consist of alternating sandstones and mudstones deposited in a continental environment. The objective of this study is to characterize the relationship of sandstone porosity with depth, and to investigate the diagenetic processes related to the porosity evolution. Porosity values estimated from point counting range from 0% to 27.8%, but are mostly between 5% and 20%. Except samples that are significantly cemented by calcite, porosity values clearly decrease with depth. Two phases of calcite cement were distinguished based on Cathodoluminescence, with the early phase being largely dissolved and preserved as minor relicts in the later phase. Feldspar dissolution was extensive and contributed significantly to the development of secondary porosity. Quartz cementation was widespread and increased with depth. Fluid inclusions recorded in calcite and quartz cements indicate that interstitial fluids in the upper part of the stratigraphic column were dominated by waters with salinity lower than that of seawater, the middle part was first dominated by low-salinity waters, then invaded by brines, and the lower part was dominated by brines. Homogenization temperatures of fluid inclusions generally increase with depth and suggest a paleogeothermal gradient of 25 °C/km, which is broadly consistent with that indicated by vitrinite reflectance data. An erosion of 1.1–2.4 (mean 1.75) km of strata is inferred to have taken place above the stratigraphic column. δ18O values of calcite cements (mainly from the late phase) decrease with depth, implying increasing temperatures of formation, as also suggested by fluid-inclusion data. δ13C values of calcite cements range from −13.4‰ to −5.7‰, suggesting that organic matter was an important carbon source for calcite cements. A comparison of the porosity data with a theoretical compaction curve indicates that the upper and middle parts of the stratigraphic column show higher-than-normal porosity values, which are related to significant calcite and feldspar dissolution. Meteoric incursion and carboxylic acids generated from organic maturation were probably responsible for the abundant dissolution events. 相似文献