地幔橄榄岩矿物中富稀土元素的CO2流体包裹体及其地球化学意义

五个无水尖晶石橄榄岩（两个富含ＣＯ２流体包裹体，三个含ＣＯ２流体包裹体）的全岩和单矿物稀土元素中子活化分析结果，证实了ＬＲＥＥ在ＣＯ２流体包裹体中富集。富含ＣＯ２流体包裹体的全岩，斜方辉石和单斜辉石比相应不含ＣＯ２流体包裹体的，其ＬＲＥＥ分别高出１１倍，５９倍和３２倍。前是在经历了较大程度部分熔融之后的亏损地幔，又受富ＣＯ２流体的强烈交代作用。后刚为经历低程度熔融作用与富集过程，并可能导致地幔     

玻璃包裹体裂变径迹在46O矿床中的应用

460矿床是火山岩型铀矿床。玻璃包裹体中裂变径迹研究表明:成矿岩体次流纹斑岩的原始铀含量为13.0ppm;裂变径迹测年龄法在强烈蚀变地区可以作为一种测年龄的有效辅助手段。     

茅坪钨锡多金属矿床流体包裹体特征及地质意义

系统研究茅坪矿床各类型矿体矿物中包裹体显微镜下特征和均一温度、冷冻盐度、气液相成分、δD、δ~(18)O等特征及其差异,并对有关数据进行了热力学计算.结果表明锡钨矿化分别主要富集于高中温和中低温条件,矿化压力为500～550bar,pH为3.97—4.91、Eh为-208～-439mv,fo:为10~(-30)～10~(-50)bar,成矿流体来源于岩浆水和地层水.     

新疆巴楚瓦吉里塔格金伯利岩矿物中岩浆包裹体研究

笔者在代表金伯利质熔浆结晶演化产物的橄榄石巨斑、金云母斑晶和磷灰石精晶中首次发现了岩浆包裹体。捕晶角闪石、单斜辉石及橄榄石中岩浆包裹体研宄证实,其源于基性-超基性杂岩。依据充填物相态和成分,将本区岩浆包裹体划分为两类:A,硅酸盐熔融包裹体;B,流体熔融包裹体,前者又细分出一个亚炎(A′),即晶体-玻璃包裹体。经岩浆包裹体均一化温度值的测定和压力估算,原始金伯利质熔浆晶出巨斑橄榄石的温度略高于1116℃,压力约4.5GPa。     

四川威远气田烃流体包裹体的研究

通过烃流体包裹体的类型、均一化温度、气相及液相成分、盐度以及同位素的研究,可以认为威远气田的天然气主要是由白云岩中有机质形成。由于从80～160℃到200～240℃的热解作用,有机物质已演化到过成热阶段。这一过程可由白云岩中存在液态烃及含沥青烃流体包裹体得到证明。威远气田的特征是:震旦系白云岩中天然气的自产自储,以CH_4为主;油田水为古海水,盐度(4.3～17.2)wt%NaCl,pH>8,(CO+CH_4)/CO_2比值指示还原条件。在基底花岗岩石英中发现有气态烃包裹体,其成分及δ~(13)C‰与花岗岩储气层中产出的天然气一致,为部分天然气可能来自深部地壳或地幔提供了新的证据。因而,威远气田天然气的成因主要由有机物质形成,部分甲烷气可能经基底断裂来自地球深处。     

Discovery of Early Tertiary Hydrothermal Activity and Its Significance in Oil／Gas Geology,Dougpu Depression,Henan Province,China

Data from the super-deep wells(PS10,PS14 and YS1)led to the discovery of widespread met-al-bearing hydrothermal fluids (or hot brines) related to basic magmas in the Lower Tertiary clastic sequence in the Dongpu Depression .In terms of SEM and EDAX analyses, pore-casting thin section examination of sandstone ,the composition and forming temperature of fluid inclusions ,the trace ele-ment composition of mustone and kerogen and organic geochemical analyses, it is demonstrated that the hydrothermal fluids existing in the area studied are ejecting fluids, which have a close bearing on diagenesis and sedimentation, rather than intrusive veins along the tectonic fractures.The main indicators of hydrothermal activity are:(1)abnormal alteration of kerogen;(2) high-temperature altered mineral assemblage;(30abnormal distribution of hydrocarbons;(4) specific assemblages and abnormal contents of heavy metals in mudstone and kerogen;(5) specific composi-tion of complex compounds and assemblages of fluid inclusions in sandstone;(6) periodic basaltic magma activity.Results of geological observations and laboratory simulating experiments demonstrated that the hydrothermal fluids have a close bearing on hydrocarbon generation in the Dongpu Depression. Two aspects of the effect of hydrothermal fluids are noticed:hydrothermal hydrocarbon production and strong metal catalysis in oil and gas generation.     

Physicochemical Conditions of the Formation of Beryl and Aquamarin in Mufushan Granopegmatite Deposit,Hunan Province,China

The formation of the Mufushan granopegmatite was closely related to the Late Yenshanian multiphase and multistage magmatic activities,More than one generation of beryl and aquamarine occur in different types of pegmatite in the granites.The presence of melt and melt-fluid inclusions strongly indicates a melt-solution character of the pegmatitic magma.Forming temperatures of the different generations of beryl in a Na^ -K^ ,Ca^2 -CO3^2--Cl^--SO4^2- solution ranges from 990℃to 200℃.Aquamarine was formed at 720-180℃.The contents of alkali metals(Na^ K^ )in th ore-formming solution of aquamarine are lower than those in the beryl,but the contents of alkali earths(Ca) and salinity are higher,The granite was generated by remelting of the basement formation(meta-sedimentary rocks of the Lengjiaxi Group)which also served as the source of ore-forming material.Beryllium in the pegmatite was transported mainly in the form of Na[Be(CO3)2],with part of it being complexed with Cl^- and SO4^2-.During the generation and evolution of the pegmatite,equilibrium might have been reached in the solid-melt-fluid or solid-fluid system.The intergranular solutions may have reacted with the early crystallized minerals,resulting in potash-feldsparization,albitization and muscovitization during which the ore-forming elements were mobilized and transported in favour of ore deposition.     

新疆天格尔金矿成矿带矿物包裹体研究

天格尔金矿成矿带矿物包裹体的均一温度、爆裂温度、成矿压力、气相成分及物理化学条件的研究表明，金矿化可分为两个成矿阶段，矿化深度１～１．５ｋｍ，成矿热液具有酸性还原特性，金是以金硫络合物形式迁移沉淀的。     

熔融包裹体中水含量的测定方法

本文在对Ｎａｕｍｏｖ（１９７９）计算熔融包裹体中水含量计算模式作原则性修正的基础上建立了新的计算模式，其特点是充分考虑了熔体被捕获后在漫长地质时期内经历的各种变化对其中水含量计算精度的影响。通过加热使熔融包裹体均一，并在均一化过程中的每一个相变发生前后分别测量各相的相对体积百分比，可从本质上消除Ｎａｕｍｏｖ计算模式未曾考虑过的对水含量计算精度发生影响的因素，因此可较为准确地获得熔融包裹体中的水含量。计算实例表明，烙融包裹体中的水含量与其均一温度负相关，随均一温度的降低含水量增高。