Modelling Feedback of Chemical Reactions on Flow Fields in Hydrothermal Systems

Coupled reactive transport models of hydrothermal systems provide new insights and deeper understanding of the processes occurring due to fluid flow, heat transfer, solute transport, and chemical reactions. Basic concepts of species transport (diffusion, dispersion, and advection) and chemical precipitation and dissolution reactions are discussed, and five end-member types of reactive transport environments are introduced. One of these reactive transport environments, named ‘reactions within thermal gradients’, is used to demonstrate how free thermal convection can lead to redeposition of minerals and, due to the feedback of reaction on the flow field, a change of the convection pattern. The direct consequence of changing the flow field is a significant variation of the temperature distribution within the modelled area. With the example it is shown how reactive transport simulation can be applied for the detailed study of fossil and recent hydrothermal systems.     

Estimating parameters of the channel width–flow discharge relation using rill and gully channel junction data

Eroding channels can usually be characterized by a power relationship between channel width (W) and channel discharge (Q). This paper examines the WQ relation using a recently developed channel junction approach to extend the validity of the WQ relation and to develop a procedure for estimating the WQ exponent and proportionality coefficient. Rill and gully channel data from the literature, and new data collected in different badland areas and in a few forest mountain streams, are analysed. Analysis shows that the WQ relation for channel width collected in badlands and forests agrees with trends observed for cropland. The exponent increases with increasing channel width in a continuous fashion rather than in a step‐like way and tends to a maximum whose value ranges between 0·5 and 0·6. The proportionality coefficient can be split into two terms, one expressing the case in which an eroding channel can broaden, the other reflecting the difficulties in removing the less erodible clods or rock fragments from the channel bed. Its splitting allows the development of a more correct form of the WQ relation in agreement with modern approaches of channel geometry: one part has the dimension of a discharge and makes the power base dimensionless, while the other brings the dimension of a length, needed for the channel width, into the WQ relation. The interpretation of the two constants is supported by data collected in rainfall‐runoff simulation experiments conducted in the field. Values characterizing the two constants in some environments are also given. Nevertheless the approach is not sufficiently parameterized yet to be of practical use (e.g. in models or for estimating peak discharge in areas where rill channels have formed). Copyright © 2009 John Wiley & Sons, Ltd.     

3D Numerical modelling of flow divisions at open channel junctions with or without vegetation

The flow division at an open channel junction is affected by the inflow discharge and the downstream water depths of the junction. The growth of vegetation in a channel system is environmental friendly, but its effect on the flow in an open channel junction can be significant. In this work a 3D RANS (Reynolds Averaged Navier–Stokes equation) model has been implemented to investigate the flow phenomena in channel junctions with or without vegetation. The model is first validated by two cases: flow in an open channel T-junction without vegetation, and flow in a single open channel with vegetation. The model is then applied to simulate flow in an open channel T-junction with varying width ratio and vegetation density of the branch channel. The results quantitatively predict the trend of increasing flow in the branch channel with the increase in branch channel width and/or the decrease in vegetation density. The overall energy loss coefficient of the system, however, decreases with the amount of flow in the branch channel.     

Insights from numerical modeling on the hydrodynamics of non-radial flow in faulted media

The objective of this work is to explore the use of flow dimensions as a tool for characterizing hydraulic conditions in faulted media. Transient flow is numerically simulated in synthetic vertically-faulted reservoirs. Analysis of the obtained time series following the Generalized Radial Flow (GRF) model displays combined radial and fractional signals with a flow dimension n=1.5$n=1.5$. Investigating the transient geometry of the frontal equipotential surface shows that fractional flow occurrence is due to abnormal fault diffusion as a consequence of water supply from the matrix under specific conditions. An original hydrodynamical explanation for fractional flow in vertically faulted media is suggested, along with a reinterpretation of the bilinear regime. It is shown that the GRF theory remains valid in such discontinuum as the fundamental relationship between n and the cross-flow area is satisfied. These results provide insights in the use of the flow dimension as a hydraulic diagnostic tool in faulted media.     

Downstream variation in bankfull width of wadeable streams across the conterminous United States

Bankfull channel width is a fundamental measure of stream size and a key parameter of interest for many applications in hydrology, fluvial geomorphology, and stream ecology. We developed downstream hydraulic geometry relationships for bankfull channel width w as a function of drainage area A, w = α A^β, (DHG_wA) for nine aggregate ecoregions comprising the conterminous United States using 1588 sites from the U.S. Environmental Protection Agency's National Wadeable Streams Assessment (WSA), including 1152 sites from a randomized probability survey sample. Sampled stream reaches ranged from 1 to 75 m in bankfull width and 1 to 10,000 km² in drainage area. The DHG_wA exponent β, which expresses the rate at which bankfull stream width scales with drainage area, fell into three distinct clusters ranging from 0.22 to 0.38. Width increases more rapidly with basin area in the humid Eastern Highlands (encompassing the Northern and Southern Appalachians and the Ozark Mountains) and the Upper Midwest (Great Lakes region) than for the West (both mountainous and xeric areas), the southeastern Coastal Plain, and the Northern Plains (the Dakotas and Montana). Stream width increases least rapidly with basin area in the Temperate Plains (cornbelt) and Southern Plains (Great Prairies) in the heartland. The coefficient of determination (r²) was least in the noncoastal plains (0.36–0.41) and greatest in the Appalachians and Upper Midwest (0.68–0.77). DHG_wA equations differed between streams with dominantly fine bed material (silt/sand) and those with dominantly coarse bed material (gravel/cobble/boulder) in six of the nine analysis regions. Where DHG_wA equations varied by sediment size, fine-bedded streams were consistently narrower than coarse-bedded streams. Within the Western Mountains ecoregion, where there were sufficient sites to develop DHG_wA relationships at a finer spatial scale, α and β ranged from 1.23 to 3.79 and 0.23 to 0.40, respectively, with r² > 0.50 for 10 of 13 subregions (range: 0.36 to 0.92). Enhanced DHG equations incorporating additional data for three landscape variables that can be derived from GIS—mean annual precipitation, elevation, and mean reach slope—significantly improved equation fit and predictive value in several regions, most notably the Western Mountains and the Temperate Plains. Channel width was also related to human disturbance. We examined the influence of human disturbance on channel width using several indices of local and basinwide disturbance. Contrary to our expectations, the data suggest that the dominant response of channel width to human disturbance in the United States is a reduction in bankfull width in streams with greater disturbance, particularly in the Western Mountains (where population density, road density, agricultural land use, and local riparian disturbance were all negatively related to channel width) and in the Appalachians and New England (where urban and agricultural land cover and riparian disturbance were all negatively associated with channel width).     

无定河及其各支流的断面水力几何形态

水力几何形态关系是对河道形态与水力学特征之间的关系进行定量描述的一种重要方法,对于河道整治有着重要的意义。本文以无定河及其支流为研究区域,利用该流域1959~1969年期间的实测流量资料,分析了34个河段的断面水力几何形态指数。结果发现,无定河所有河道的水力几何形态指数总体上可以分为三类:b>f &; m>f &; b+ f>m;b&; m相似文献   

Online Preconcentration and Determination of Trace Levels Cadmium in Water Samples Using Flow Injection Systems Coupled with Flame AAS

A rapid and sensitive method for the determination of trace levels cadmium in water samples by flame atomic absorption spectrometry was developed. It is based on the online sorption of Cd(II) ions on a microcolumn packed with HCl treated bamboo charcoal. In a pH range of 5.0–7.5, Cd(II) ions were effectively retained on the microcolumn, which exhibited fast kinetics, permitting the use of high sample flow rates up to at least 12.8 mL/min without the loss of retention efficiency. The retained Cd(II) ions were quantitatively eluted with HCl (2.0 mol/L) for an online determination. With a preconcentration time of 80 s at a sample loading flow rate of 8.6 mL/min, a sensitivity enhancement factor of 63 was obtained compared with the slope of the linear portion of the calibration curves before and after preconcentration. The calibration graph using the preconcentration system for cadmium was linear with a correlation coefficient of 0.9997, at levels from 1–40 ng/mL. The precision (RSD) for 11 replicate measurements were 3.2% for the determination of 5 ng/mL Cd(II) and 1.8% for 20 ng/mL Cd(II), respectively, and the detection limit (3s) was 0.36 ng/mL. The accuracy was assessed through the determination of a certified reference material, and also through recovery experiments.     

近数十年来东平水道河床演变特征

东平水道受径、潮动力相互作用,水流、泥沙和河床演变具有独特的时空变化特征.20世纪80年代以前处于缓慢的自然淤浅过程,由于航道整治工程调整作用和疏浚维护等因素的影响,80年代中后期由淤积转变为冲刷状态,大规模的河床采沙是90年代以来河槽加剧加深增容的主导因素.近数十年来,虽然东平水道平滩水位下降,但是造床流量增加,潮汐动力相对增强,河床演变特征表现为宽深比下挫,滩槽高差提升,满槽容积增大,河槽向有利于水沙输送的窄深方向发展.