零价铁去除Cr（Ⅵ）的批实验研究

零价铁去除Cr(Ⅵ)的一系列批实验结果表明：水溶液中发生的氧化还原反应符合准一级反应；对于相同粒度的铁屑(比表面积2．89m^2／g)，固液比由05g／100mL增加到2．0g／100mL，Cr(Ⅵ)质量浓度达到排放标准所需反应时间从26．7min降为3．6min；在固液比相同、原水中Cr(Ⅵ)质量浓度不超过30mg／L时，原水质量浓度增大，达到饮用水标准的反应时间增加；其他条件相同，升高温度可提高零价铁与Cr(Ⅵ)的反应速率。     

近临界特性的地层水及其对烃源岩生排烃过程的影响

研究利用特制的地层孔隙热压模拟实验装置, 开展了模拟地层孔隙空间高压液态水热体系烃源岩生排烃模拟实验.模拟实验施加的流体压力为38±2 MPa, 温度为290~390 ℃.模拟实验结果显示了有关高压液态水及其与之相联系的流体压力和孔隙空间等因素对烃源岩生排烃影响作用的一些重要现象, 实验发现高压液态水介质条件有利于液态油的生成和保存, 不利于液态油向气态烃的转化, 而且干酪根的生烃潜力和排油效率有一定的提高.这些新的实验现象可能主要与近临界特性的高压液态地层水的作用有关, 进一步推断近临界特性的高压液态水参与干酪根向油气的转化反应, 增加了水对油气的溶解能力.在地下实际烃源岩生排烃的温压(100~200 ℃, 30~120 MPa)条件下, 岩石孔隙中的地层水是一种相对低温高压压缩液态水, 这种地层水可能具有近临界特性, 对烃源岩生排烃过程有重要影响.但目前对这种现象的机理和石油地质意义还知之较少.因此, 加强高压地层水近临界条件下烃源岩生排烃热压模拟实验研究, 对进一步深入理解地层条件下的近临界水介质、流体压力、孔隙空间因素对生排烃过程的影响, 深化烃源岩生排烃机理的探讨, 建立地质尺度上的烃源岩生排烃动力学模型, 都具有重要的理论和实际意义.      

Contrasting morphodynamics in alluvial fans and fan deltas: effect of the downstream boundary

Alluvial fans and fan deltas can, in principle, have exactly the same upstream conditions, but fan deltas by definition have ponding water at their downstream boundary. This ponding creates effects on the autogenic behaviour of fan deltas, such as backwater adaptation, mouth bars and backward sedimentation, whereas alluvial fans may lack these effects. Hence the present authors hypothesize that morphodynamics on alluvial fans are determined primarily by upstream boundary conditions, whereas morphodynamics on fan deltas are determined by both the upstream and the downstream boundary condition and changes therein. To isolate the effects of the upstream and downstream boundaries, five new alluvial fan experiments are compared with the details of three fan deltas published earlier that were formed under very similar and simple conditions. Similar to the fan deltas, the alluvial fans build up by sheet flow, whilst quasi‐regular periods of incision cause temporary channelized flow. Incision is followed by channel backfilling, after which the fan returns to sheet flow. The channelization and backfilling in alluvial fans is markedly less pronounced and more prone to autogenic disturbance than in fan deltas. The difference is caused by morphodynamics at the downstream boundary. In a fan delta, the flow expansion of the channel causes deposition of all the sediment, which forms a mouth bar and causes strong backfilling. In an alluvial fan, on the other hand, the slope break at the fan perimeter causes some deposition, but transport is not reduced to zero. Consequently, the backfilling in alluvial fans is less pronounced than in fan deltas. Other published experiments support this trend: removal of the mouth bar by a river leads to permanent channelization, whilst pronounced mouth‐bar formation in highly channelized deltas promotes backward sedimentation. The experimental results for this study predict that, when alluvial fans prograde into lakes or deep rivers, they transition to fan deltas with increasingly deeper channels and thicker backfill deposits.     

土壤有机碳同位素样品制备过程的影响因素讨论

土壤有机碳同位素地球化学在气候和植被恢复方面的研究已得到广泛应用,但目前对不同类型、不同时代的土壤总有机碳同位素样品制备过程的系统研究较少.本文选取黄土高原不同地区、不同类型的现代土壤和古土壤,对其有机碳同位素样品制备过程进行了较系统的研究.( 1)去除土壤中无机碳酸盐对有机碳同位素组成的干扰:对于现代土壤样品,在室温条件下,用 0.5～ 6 mol/L HCl反应 1 d去除碳酸盐,均可获得理想数据;在 70 ℃反应条件下,用 0.5～ 2 mol/L HCl反应 2 h去除碳酸盐可获得理想数据,但用 6 mol/L HCl,δ 13C值偏负 0.65‰;( 2)在 850 ℃氧化温度条件下,样品制备加铜丝,对现代土壤及古土壤样品的δ 13C值均没有影响,结果表明在用封管法进行现代土壤及古土壤的有机碳同位素样品制备时,可以不加铜丝;( 3)对于有机碳含量较高的有机碳标准物质、植物和现代土壤样品,在 850 ℃氧化条件下,恒温 2.5 h,足以保证样品有机质氧化完全,不会产生同位素分馏;对于深层黄土和红粘土样品,由于样品体系复杂,在上述氧化条件下难以获得理想数据,合适的氧化条件有待进一步深入研究.     

沙尔湖煤田巨厚煤层异地成煤分析

通过对主煤层煤岩组分对比发现,沙尔湖煤田煤显微煤岩组分以惰质组分为主,组分因埋深不同有差异.利用镜质组与惰质组组份含量比例关系,推测煤层在沼泽积水较深还原环境中形成.煤中惰质组分含量较高,说明成煤期地壳缓慢上升,沼泽积水变浅的氧化环境.煤田自西向东主煤层形成时期沼泽积水深浅(地壳升降)变化韵律一致,早期深水中心偏向东部(葛洲坝煤矿方向),晚期深水中心偏向西部(格鑫煤矿方向),东部持续缓慢抬升使成煤阶段处于氧化环境,惰质组含量逐渐增高,并明显高于西部.同时,煤中无机质含量较高,反映当时为水动力条件较弱的成煤环境.据巨厚煤层产出、聚煤中心赋存(直接在二叠系老地层上)和煤层稳定性及变化趋势多方煤层特征,认为沙尔湖煤田巨厚煤层的形成具异地成煤特点.     

Phase Equilibria of the Lyngdal Granodiorite (Norway): Implications for the Origin of Metaluminous Ferroan Granitoids

The Proterozoic (950 Ma) Lyngdal granodiorite of southern Norwaybelongs to a series of hornblende–biotite metaluminousferroan granitoids (HBG suite) coeval with the post-collisionalRogaland Anorthosite–Mangerite–Charnockite (AMC)suite. This granitoid massif shares many geochemical characteristicswith rapakivi granitoids, yet granodiorites dominate over granites.To constrain both crystallization (P, T, fO₂, H₂O in melt) andmagma generation conditions, we performed crystallization experimentson two samples of the Lyngdal granodiorite (with 60 and 65 wt% SiO₂) at 4–2 kbar, mainly at fO₂ of NNO (nickel–nickeloxide) to NNO + 1, and under fluid-saturated conditions withvarious H₂O–CO₂ ratios for each temperature. Comparisonbetween experimental phase equilibria and the mineral assemblagein the Lyngdal granodiorite indicates that it crystallized between4 and 2 kbar, from a magma with 5–6 wt % H₂O at an fO₂of NNO to NNO + 1. These oxidized and wet conditions sharplycontrast with the dry and reduced conditions inferred for thepetrogenesis of the AMC suite and many other rapakivi granitesworldwide. The high liquidus temperature and H₂O content ofthe Lyngdal granodiorite imply that it is not a primary magmaproduced by the partial melting of the crust but is derivedby the fractionation of a mafic magma. Lyngdal-type magmas appearto have volcanic equivalents in the geological record. In particular,our results show that oxidized high-silica rhyolites, such asthe Bishop Tuff, could be derived via fractionation of oxidizedintermediate magmas and do not necessarily represent primarycrustal melts. This study underlines the great variability ofcrystallization conditions (from anhydrous to hydrous and reducedto oxidized) and petrogenetic processes among the metaluminousferroan magmas of intermediate compositions (granodiorites,quartz mangerites, quartz latites), suggesting that there isnot a single model to explain these rocks. KEY WORDS: ferroan granitoids; crystallization conditions; experiments; Norway; Sveconorwegian; Bishop Tuff     

油藏成藏年代学分析

成藏年代学研究是成藏动力学研究的重要方面 ,是揭示成藏过程、成藏速率研究的有效途径。文中系统介绍了成藏年代学研究方法 ,即以储层自生伊利石年代学分析法为主 ,与其它传统地质方法相结合 ,对大庆油田的成藏年代学进行了系统研究。大庆油田北部的喇嘛甸、萨尔图、杏树岗块状背斜构造油藏成藏年龄在 65～ 4 0Ma ,南部受岩性控制的背斜构造油藏成藏年龄在 77.4～ 73Ma ,采用数值模拟方法对其进行了验证 ,揭示了石油二次运移、聚集成藏的动力学过程具有快速、高效的特征     

北京、郑州和深圳三城市空气中气溶胶单颗粒特征的扫描电镜分析

分别采集北京、深圳和郑州3个城市气溶胶样品,使用场发射扫锚电镜-能谱仪观察气溶胶单颗粒的显微形貌和元素组成,并利用图像分析系统对PM2.5的粒径进行了分析。结果表明,城市气溶胶单颗粒类型以矿物颗粒、烟尘和球形颗粒(飞灰和二次粒子)为主。对比3个城市气溶胶中不同颗粒类型数量百分比发现,矿物颗粒数量最多的城市是北京,飞灰和烟尘数量最多的城市是郑州,而规则矿物颗粒数量最多的城市是深圳。3个城市气溶胶单颗粒的数量-粒径分布均呈单峰分布。深圳气溶胶中颗粒物的粒径相对较小,其次为郑州、北京。3个城市气溶胶中颗粒物来源不同程度上都受到交通污染源影响,而燃煤源对北京和郑州气溶胶中颗粒物来源影响仍然不容忽视。     

青藏高原冬季积雪异常对东,南亚夏季风影响的初步数值模拟研究

利用一个耦合了简化的简单生物圈模式的大气环流谱模式（ＳＳｉＢ－ＧＣＭ），初步探讨了青藏高原冬季积雪异常对东、南亚夏季季风环流和降水的影响及其机理。结果表明，高原地区积雪增加将使随后地夏季东、南来季风明显减弱，主要表现为东、南亚季风区降水减少，索马里急流、印度季风的印度西南气流弱弱。另外，还提出欧亚大陆雪盖与整个高原雪盖和高原东部雪盖对东、南亚夏季风影响的敏感问题。与欧亚大陆雪盖相比，高原雪盖是影响