角闪石族和辉石族矿物的系统矿物学分类命名

角闪石族和辉石族矿物是链状硅酸盐矿物的重要组成部分,它们中的许多矿物种属于造岩矿物和/或工业矿物,具有重要的成因矿物研究意义和工业应用开发价值。国内学者对它们的分类命名和基本系统认识主要源自于王璞等(1984)编著的《系统矿物学》。随着科学技术发展和矿物学研究的不断深入,原有的矿物基础资料和分类命名都在不断更新与完善,迄今已有专业学术机构和学者在不同年代陆续发表了不同版本对该两类矿物的修订或修改意见,但一直没有统一整合,导致在涉及该两类矿物的应用研究中,在分类命名上与国际标准不统一。根据本课题组在国家公益性行业科研专项项目(新编《系统矿物学》)所承担的研究任务和当前国内外研究进展,本文系统归纳、梳理并综述了角闪石族和辉石族矿物的分类方案和命名原则,使分类命名统一标准、原则和认识并与国际接轨,这有利于该两类矿物的理论研究与开发应用,更好地支撑地质学及相关学科的研究与发展。     

郯庐断裂带(安徽段)内磁铁石榴角闪岩的形成条件、年代学及构造归属的探究

通过对肥东群南缘特征性岩石——磁铁石榴角闪岩的构造地质学和岩相学研究表明,磁铁石榴角闪岩及其围岩以构造透镜体形式产出,该变质岩具有两个阶段变质矿物组合,热力学评价显示①阶段的温压范围为：T=616~700℃和P=0.66~0.85GPa,平均温压为T=653±35℃和P=0.75±0.09GPa。②阶段的温压范围为：T=597~643℃和P=0.51~0.94GPa,平均温压为T=620±15℃和P=0.73±0.15GPa,并表现出一个快速等压降温P-T演化特征。锆石U-Pb定年和拉曼光谱分析表明,该磁铁石榴角闪岩的变质年龄为2469±49Ma。结合地质背景和前人的研究,可以判定该类岩石可能源于华北板块。由于郯庐断裂的左旋走滑作用被构造并置与扬子板块中。从而进一步推测,郯庐断裂（安徽段）横向宽度可达到10~15km。     

由电子探针分析数据估算角闪石、黑云母中的Fe~（3＋）、Fe~（2＋）

待定矿物化学式中阳离子数法是由电子探针分析值求矿物中Ｆｅ￣（３＋）、Ｆｅ￣（２＋）的新方法。在该方法中，矿物化学式中的阴离子数是唯一已知条件，阳离子数未知，通过本文给出的一系列步骤可以得出实际阳离子数的可能估计。进而求出Ｆｅ＿２Ｏ＿２、ＦｅＯ。该法对Ｆｅ＿２Ｏ＿３、ＦｅＯ的计算结果避免了出现负值，在总体上，该方法的计算结果较其它方法更接近其化学分析值。     

新疆黄山杂岩体矿物学特征及其意义

黄山杂岩体造岩矿物有橄榄石、斜方辉石、单斜辉石、斜长石、角闪石和黑云母。其中斜方辉石的多色性不是由Fe~(2+)引起,而是由Ti~(4+)引起。单斜辉石结晶后常与岩浆继续发生化学反应,形成一种岩浆岩结构——角闪反应补丁结构。橄榄石中镍含量的亏损程度反映杂岩体曾经历过硫化物熔离作用。单斜辉石Si,Al~Ⅳ,Ti的变化表明杂岩体属于拉斑玄武岩系列。超镁铁岩中K,Ba,Th,Hf等元素反常的地球化学行为是由该岩石中黑云母矿物引起。     

南太行山地区中基性侵入岩中角闪石的矿物学及其成因

角闪石作为南太行山地区中基性侵入岩中主要组成矿物,其详细的成因矿物学研究对了解该套岩石的形成机理具有重要意义。电子探针分析表明角闪石的成分变化很大如SiⅣ、AlⅣ和A位置上的Na和K离子,主要为韭闪石、韭闪石质普通角闪石、普通角闪石和阳起石质普通角闪石。且富镁和钙,为钙镁质角闪石。同时,不同岩石类型中的角闪石的组成无显著差异。大颗粒的核心部位形成于深部岩浆房中(18 ~25km),其组成的连续变化主要反映结晶深度的不同。角闪石的成因矿物学研究表明该套岩石不可能来源于华北古老的下地壳,而可能起源于新增生的下地壳和/或壳幔过渡带。     

Phase equilibria modelling of retrograde amphibole and clinozoisite in mafic eclogite from the Tso Morari massif,northwest India: constraining the P–T–M(H2O) conditions of exhumation

Phase equilibria modelling of post‐peak metamorphic mineral assemblages in (ultra)high‐P mafic eclogite from the Tso Morari massif, Ladakh Himalaya, northwest India, has provided new insights into the potential behaviour and source of metamorphic fluid during exhumation, and constrained the P–T conditions of hydration. A series of P–M(H₂O) pseudosections constructed in the Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O (NCKFMASHTO) system show that a number of petrographically distinct hydration episodes occurred during exhumation from peak P–T conditions (~640 °C, 27–28 kbar), resulting in the formation of abundant compositionally zoned amphibole and minor clinozoisite poikiloblasts at the expense of a peak assemblage dominated by garnet and omphacite. Initial hydration is interpreted to have occurred as a result of the destabilization of talc following isothermal decompression to ~23 kbar, which led to the formation of barroisite–winchite amphibole core domains. An episode of fluid infiltration from an external source at ~19 kbar, with or without syn‐decompressional cooling to ~560 °C, resulted in further barroisitic–winchitic amphibole growth, followed by the formation of clinozoisite poikiloblasts. Continued buoyancy‐driven exhumation to the base of the lower crust is constrained to have taken place with no additional fluid input. A final hydration event is characterized by the formation of magnesiohornblende rims on the barroisite–winchite cores, with the former interpreted to have formed during later prograde overprinting in the middle crust associated with the final stages of exhumation. Notably, the vast majority of externally sourced H₂O, comprising just over half of the current bulk rock fluid content, was added during this later hydration event. In a middle crustal setting, this is interpreted as the result of devolatilization reactions occurring in migmatitic host orthogneiss and/or metasedimentary units, or following the crystallization of partial melt.     

柴北缘鱼卡河超高压变质金红石中Si含量及其地质意义

利用LA-ICP-MS方法对柴达木盆地北缘鱼卡河超高压变质的多硅白云母榴辉岩及共生的石榴角闪钠长岩中的金红石进行了详细的矿物学和LA-ICP-MS原位微量元素研究。结果表明:多硅白云母榴辉岩中金红石显示Si成分环带,且Si含量(质量分数,下同)随变质压力而发生规律性的变化;从进变质到峰期变质阶段,金红石中Si含量从核部向边部呈升高趋势,峰期金红石的边部Si含量达到最高,退变质阶段金红石中Si含量从核部向边部呈降低趋势;石榴角闪钠长岩中的金红石主要呈包体产于多硅白云母、石榴子石、角闪石和钠长石中;在相同的超高压变质条件下,石榴角闪钠长岩中多硅白云母包体金红石的Si含量((1018~2741)×10^-6,平均为1924×10^-6)明显高于多硅白云母榴辉岩中的峰期金红石((450~2397)×10^-6,平均为952×10^-6)。综合多硅白云母榴辉岩和石榴角闪钠长岩的产状、变质演化和全岩成分以及前人对大别—苏鲁超高压榴辉岩中富硅金红石的研究结果提出,超高压变质岩石中金红石的Si含量与变质压力成正相关关系,金红石中Si含量大于500×10^-6可以作为榴辉岩经历超高压变质作用的指示标志。超高压金红石中Si含量与全岩成分中SiO2和TiO2含量有关,随SiO2含量的升高和TiO2含量的降低而升高。     

角闪石高温高压实验研究进展及其地球物理意义

高温高压实验作为地球科学研究的重要方向之一,通过模拟地球深部的温度和压力条件,了解地球深部物质的物理化学性质、地球内部结构和动力学演化。角闪石属于双链硅酸盐矿物,为地幔岩石圈的重要组成,广泛分布在海洋地壳、俯冲板块、变质岩和火成岩中。作为俯冲带的重要含水矿物,角闪石的广泛分布和高温高压下的脱水对于理解俯冲带水含量以及水迁移具有重要作用,同时在俯冲带的地震活动、高电导率异常、地震波速异常和岩浆活动中扮演重要角色。在过去的近百年时间里,国内外学者对角闪石高温高压物理化学性质进行了大量的研究。角闪石具有非常复杂的元素组成和结构特征,由此也导致了不同角闪石物理化学性质存在显著不同,包括脱水与脱羟基反应中元素迁移的差异、角闪石形成与分解过程中碱性元素(K+Na)和H2O含量对热稳定的影响、不同空间群结构下的高压结构相变、原位条件下不同结晶方向的电导率异常、不同结晶学优选方位(CPO)下的波速异常等。已有的研究对于角闪石的物理化学性质以及其在俯冲带中发挥的作用有了比较清楚的认识,但仍然有许多问题需要进一步研究,如角闪石的高压脱水动力学、热物性和变形机制等。     

Neoproterozoic Tectonic Setting of Southeast China: New Constraints from SHRIMP U-Pb Zircon Ages and Petrographic Studies on the Mamianshan Group

<正>Precambrian tectonic history of Zhejiang,Fujian,and Jiangxi provinces of south China is important for understanding the tectonic evolution of South China but its magmatic activity, petrogenesis,stratigraphic sequence of the Mamianshan Group is still strongly controversial.Here we present new sensitive high resolution ion micro-probe(SHRIMP) U-Pb zircon geochronological data for the Mamianshan Group and petrographical data to constrain the tectonic framework of the regions.Our results showed that the SHRIMP U-Pb zircon age of green schists of the Dongyan Formation is 796.5±9.3 Ma,the Daling Formation is 756.2±7.2 Ma,and mica-quartz schist of the Longbeixi Formation is 825.5±9.8 Ma.These data indicate that the Mamianshan Group was formed not in the Mesoproterozoic,but in the Neoproterozoic and its stratigraphic sequences should be composed of Longbeixi,Dongyan,and Daling Formations from the bottom to the top.Rocks from this Group, from Zhejiang,Fujian and Jiangxi provinces,constituted the upper basement of the Cathaysia Block that overlay the lower basement of the Mayuan Group.Detailed petrographic studies demonstrate that the amphibole schists of the Dongyan Formation in the Mamianshan Group were formed within an intra-arc rift setting rather than a continental rift as previously suggested.Rather,this island-arc type formation was developed by collision and/or subduction between various blocks resulting from the breakup of the supercontinent Rodinia at c.850-750 Ma.The Zhuzhou conglomerate,distributed near Dikou Town,Jian'ou City,Fujian Province and previously considered as evidence of the Mesoproterozoic Dikou movement,is shown here not to be the basal conglomerate above the angular unconformity between the upper and lower basements.Our conclusions have important implications for understanding the Precambrian tectonics of South China.     

Experimental and theoretical bond critical point properties for model electron density distributions for earth materials

Generalized X-ray scattering factor model experimental electron density distributions and bond critical point, bcp, properties generated in recent studies for the earth materials stishovite, forsterite, fayalite and cuprite with high energy single crystal synchrotron X-ray diffraction data and those generated with high resolution diffraction data for coesite and senarmonite were found to be adequate and in relatively good agreement, ~5% on average, with those calculated with quantum chemical methods with relatively robust basis sets. High resolution low energy single crystal diffraction data, recorded for the molecular sieve AlPO₄-15, were also found to yield model electron density distribution values at the bcp points for the AlO and PO bonded interactions that are in relatively good to moderately good agreement with the theoretical values, but the Laplacian values of the distribution at the points for the two bonded interactions were found to be in relatively poor agreement. In several cases, experimental bcp properties, generated with conventional low energy X-ray diffraction data for several rock forming minerals, were found overall to be in poorer agreement with the theoretical properties. The overall agreement between theoretical bcp properties generated with computational quantum methods and experimental properties generated with synchrotron high energy radiation not only provides a basis for using computational strategies for studying and modeling structures and their electron density distributions, but it also provides a basis for improving our understanding of the crystal chemistry and bonded interactions for earth materials. Theoretical bond critical point properties generated with computational quantum methods are believed to rival the accuracy of those determined experimentally. As such the calculations provide a powerful and efficient method for evaluating electron density distributions and the bonded interactions for a wide range of earth materials.Dedicated to Professor Robert F. Stewart of Carnegie Mellon University on his retirement for his brilliant and original work modeling electron density distributions.