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11.
The kinetics of conversion of iron(III) (hydr)oxides to ferrous iron mediated by fulvic acid have been investigated in order to improve the understanding of the redox cycling of iron at the oxic-anoxic boundary in natural waters. Under the conditions similar to natural waters, fulvic acid is able to reduce the iron(III) (hydr)oxide. The kinetics of the reaction depend on the reactivity of iron(III) (hydr)oxides and the reducing power of the fulvic acid. The rate of reaction is 60 nm/h obtained under following conditions: total concentration of Fe(III) 1.0 × 10–4 M, pH 7.5, fulvic acid 5 mg/L. The rate is considered as a net result of reduction and oxidation in the > FeIII-OH/Fe(II) wheel coupled with fulvic acid. In a real natural water system, reductants other than fulvic acid may be of importance. The results obtained in the laboratory, however, provide evidence that the Fe(OH)3(s)/Fe(II) redox couple is able to act as an electron-transfer mediator for the oxidation of natural organic substances, such as fulvic acid by molecular oxygen either in the absence of microorganisms or as a supplement to microbial activity. 相似文献
12.
冀西北长城纪宣龙式铁矿层中微体植物化石的发现及其意义 总被引:10,自引:0,他引:10
本文研究的是笔者等在冀西北长城系串岭沟组宣龙式铁矿层中发现的微体植物化石,这些化石都保存在铁质叠层石(肾状赤铁矿)和铁质核形石(鲕状赤铁矿)的基本层中。微化石以丝状体为主,部分为球状体。归属于原核生物蓝藻门颤藻科的两个属和色球藻科的一个属。化石层同位素年龄约在1800—1757Ma。这些化石与北美冈弗林特组微化石比较,既有些相似,又有些区别。该化石的发现为研究铁矿的成因,指示沉积环境及层位对比都很有意义。 相似文献
13.
Laboratory experiments were carried out to acquire more insight and understanding of the phenomena associated with the in-situ arsenic remediation. Visualization techniques are the most informative for the detection of Fe(II) while flowing in soils. Green Rust (GR) was considered as representative of in-situ iron precipitates. In a visualization flat cell, the change in color of GR to orange, due to oxidation, was monitored by a digital camera and the images were analyzed giving the spatial and temporal distribution of Fe(II). Moreover, both oxygen and pH changes in time were recorded in two sections along the flow direction in the cell. The measured and calculated concentration profiles were compared and the actual reaction rates were predicted. The reaction rate constants measured in this study, under flowing conditions, are in a good agreement with the values obtained from batch experiments reported in the literature. 相似文献
14.
Yongfeng JIA Xin WANG George Demopoulos 《中国地球化学学报》2006,25(B08):35-35
Adsorption of arsenate on hydrous iron oxide is an important process controlling geochemical cycling of arsenic in environment as well as the fate of arsenic-bearing mining wastes. The widely accepted view on the mechanism of adsorption is that arsenate is adsorbed via bidentate binuclear inner-sphere complexation. In this study, we characterized the arsenate-hydrous iron oxide sorption solids synthesized at pH=3-8 using Fourier transformed infrared spectroscopy (FTIR) and X-ray diffraction (XRD). It has been determined that poorly crystalline ferric arsenate developed on the surface of iron oxide when arsenate was sorbed at acidic pH, while at alkaline pH the adsorption of arsenate was via bidentate complexation. 相似文献
15.
Yoko Fujikawa Daisuke Yoneda Atushi Minami Hiroshi Yashima Toshio Tonokai Sotoji Tani Masami Fukui Tatuhide Hamasaki Masataka Sugahara 《中国地球化学学报》2006,25(B08):113-113
Biological iron and manganese removal utilizing indigenous iron and manganese oxidizing bacteria (IRB hereafter) in groundwater can also be applied to arsenic removal according to our pilot-scale test. The arsenic removal probably occurred through sorption and complexation of arsenic to iron and manganese oxides formed by enzymic action of IRB. We investigated the chemical properties of iron and manganese oxides in IRB floc and the valence state of arsenic sorbed to the floc to clarify the mechanisms of the arsenic [especially As (Ⅲ)] removal. The floc samples were collected from two drinking water plants using IRB (Jyoyo and Yamatokoriyama, Japan), and our pilot - scale test site where arsenic and iron removal using IRB is under way (Mukoh, Japan). The Jyoyo and Yamatokoriyama IRB floc samples were subjected to As (Ⅲ) and As(Ⅴ) sorption experiments. The elemental composition of the floc samples was measured. XANES spectra were collected on As, Fe and Mn K-edges at synchrotron radiation facility Spring 8 (Hyogo, Japan). FT-IR and the X-ray diffraction spectra of the samples were also obtained. The IRB floc contained ca. 35 % Fe, 0.3%-3.5% Mn and 2%-6% P. The samples were highly amorphous and contained ferrihidrites and hydrated iron phosphate. According to XANES analyses of IRB, As associated with IRB was in +5 valence state when As (Ⅲ) (or As (Ⅴ)) was added in laboratory sorption test, Fe in +3 valence state, and Mn a mixture of+3 and +4 valence states. Small shift was observed in the XANES spectra of IRB on As K-edge as the equilibration time of the sorption experiment was increased. Gradual oxidation of a small amount of As (Ⅲ) associated with IRB or change in arsenic binding with sorption site were the probable mechanism. 相似文献
16.
为了解2004年11月24日乌鲁木齐市两座电网瑶线铁塔倒塌事故的气象原因,通过实地调查,并对高低空环流形势场、加密气象站信息等进行了分析。结果表明,乌鲁木齐地区不同地理位置风速差异很大,红雁池和头屯河区瞬间极大风速分别比市区大12.8m/s和18.4m/s。纠正了过去认为东南大风的强中心只出现在红雁池附近的说法,为今后制作大风分区预报提供了参考,也可为城区高层建筑及相关设计规范的修正提供借鉴。 相似文献
17.
18.
华北陆块北缘西段狼山—白云鄂博裂谷系中元古代形成的大型多金属矿床 ,是我国重要的铁、稀土、铜、铅、锌矿产地。矿床为产于沉积岩中热水沉积型多金属矿床。其形成受地层、构造控制 ,与裂谷作用有着密切的关系。裂谷系内外分支的地质环境及矿床矿种不同 ,导致矿床特征及成因具有一定差异。白云鄂博铁、稀土矿床为钾、钠、磷等含量较高的热水沉积型 ,霍各乞铜、铅、锌多金属矿床为与中基性火山岩有关的过渡热水沉积型 ,东升庙和甲生盘等铅、锌多金属矿床为热水沉积型。文中将对上述矿床分别进行论述。 相似文献
19.
Bradon Ellem 《The Australian geographer》2003,34(3):281-296
This paper examines the attempt by mining management in Western Australia's Pilbara to replace mining unions—quite literally—by removing them from the processes of representation and bargaining. It analyses the way in which those unions have tried to re-place themselves, in the senses of transforming themselves in those spaces in which they were already operating and reviving themselves where they were not. Where unionists have succeeded in these engagements, it has been by working at a range of geographical scales, using the ‘power of place’ in the Pilbara and reshaping traditional geographies of union organisation. It is suggested here that many of these emergent outcomes are the result of the embeddedness of geographically specific historical structures along with new intersections of nationally and locally scaled labour politics. 相似文献
20.
细菌浸铜技术在紫金山铜矿的应用 总被引:4,自引:0,他引:4
介绍了生物浸矿技术在紫金山铜矿的应用及在这一过程中发现的一些问题,并提出了有待进一步解决的一些问题。 相似文献