中国内蒙古白云鄂博Fe-Nb-REE矿床地质特征与陨石撞击成因

中国内蒙古白云鄂博Ｆｅ－Ｎｂ－ＲＥＥ矿床由于其独特的矿床地质与矿物地球化学特征而明显有别于世界上其它绝大多数的Ｆｅ、Ｎｂ、ＲＥＥ矿床。本文提出该矿床是约１５００Ｍａ前一块富含ＲＥＥ、Ｎｂ的铁陨石撞击在华北地台北缘碳酸盐沉积陆架上形成的。现在矿床矿体中心的块状铁矿石更多地代表了陨石的成分,矿体外侧富含ＲＥＥ、Ｎｂ的环状白云岩是陨石撞击浅海碳酸盐沉积陆架释放的巨大能量使海水（含Ｍｇ）迅速受热溶解陨石中的ＲＥＥ、Ｎｂ等形成的含金属热液蚀变沉积成因方解石质碳酸盐沉积物的结果。块状铁矿石和环状白云岩之间矿物成分异常复杂、结晶颗粒十分细小的条带状、侵染状Ｆｅ－Ｎｂ－ＲＥＥ矿石组成的矿体则是撞击瞬间导致的由陨石（Ｆｅ、Ｎｂ、ＲＥＥ）、海水（Ｍｇ、Ｎａ、Ｋ等）和碳酸盐（含少量硅质夹层）（Ｃａ、Ｓｉ、Ａｌ等）组成的超高温、多组分、富水体系在快速冷却条件下反应生成的产物。撞击释放的巨大热能,在撞击体（陨石）下部相对不易释放,导致部分碳酸盐沉积物在富含ＲＥＥ、Ｎｂ、Ｍｇ等的热液参与下融熔,然后侵入到周围岩石裂隙形成矿区内众多的富含ＲＥＥ、Ｎｂ的白云岩脉。撞击的瞬间导致大量岩石、矿物碎屑、海水、蒸汽弥漫天空,同时引发巨大的海啸,然     

Accumulation of Phosphorus and Heavy Metals in the Peel-Harvey Estuary in Western Australia: Results of a Preliminary Study

Concentrations of P and of heavy metals (Zn, Cd, Pb, Cu) were determined in sediment cores from the Peel-Harvey Estuary in Western Australia. Two cores were extracted, each representing one of the two basins of the estuary. Sediments were dated by surplus²¹⁰Pb, by¹³⁷Cs and by changes in the Fe/S ratio. Increasing exports of P from the mainly agricultural catchments have resulted in more than a doubling of both total P and acid extractable inorganic P in sediments of the estuary. Accumulation of P in the estuary is less than expected for complete retention of inputs of P from the major tributaries. Historical data show that since 1950 average concentrations of dissolved inorganic P have approximately doubled in the Peel Inlet and increased by times seven in the Harvey Estuary. Increases in concentrations in surface sediments of acid extractable Zn, Cd, Pb and Cu are noticeable in the Peel Inlet, and of Zn and Cd in the Harvey Estuary. The greatest increase, relative to background, is shown by Zn. Concentrations of extractable Zn and Cd in surface sediments are similar to those estimated from average concentrations in the water column for equilibrium adsorption to organic matter in sediments. Extractable Pb is greater than estimated for equilibrium adsorption to sediments. Extractable Cu is of the order of what can be expected for equilibrium adsorption to sediments in the Peel Inlet, but is less than expected in the Harvey Estuary.     

水温分层型水库铁、锰垂直分布特征

贵阳市主要饮用水源地阿哈水库系水温分层型季节性缺氧水库,由于沉积物含高浓度Ｆｅ,Ｍｎ至使库水受到污染,经多年测定不同季节２０ｍ深垂直水柱结果表明,Ｆｅ,Ｍｎ分布随着季节变化,水库水温分层而变化,呈现明显的垂直分布规律,高浓度Ｆｅ,Ｍｎ主要出现在水温分层期水库中,下层,与库底缺氧,ＰＨ下降沉积物浓度Ｆｅ,Ｍｎ释放造成的二次污染等密切相关,从而为自来水厂实施优化分层取水和污染控制提供了依据。     

湖北金山店矽卡岩型铁矿田硫同位素特征及其地质意义

矿集区或矿田尺度硫同位素的空间分布特征研究不仅具有重要的理论意义,而且对找矿实践具有重要的指示作用。本文对金山店矿田范围内的矽卡岩型铁矿床开展了系统的硫同位素研究工作,发现该矿田内矽卡岩型铁矿床中的黄铁矿(+15. 1‰~+25. 6‰)、硬石膏(+24. 9‰~+31. 5‰)和石膏(+27. 5‰~+30. 4‰)均具有富集重硫同位素的特征,明显不同于岩浆热液矿床中这些矿物的δ~(34)S值组成特征,且硬石膏和石膏的δ~(34)S值与三叠系嘉陵江组地层中沉积石膏的δ34S值较为接近,暗示金山店矿田内矽卡岩型铁矿中的硫可能主要来自于含膏盐地层。含膏盐地层广泛参与了金山店矿田中矽卡岩型铁矿的成矿作用,对成矿作用产生了重要的影响:大量硫酸根(SO_4~(2-))的还原过程可以将成矿体系中的Fe~(2+)氧化成Fe~(3+),导致大量磁铁矿的形成;含膏盐地层与流体作用形成大量的盐溶角砾岩,有利于加速成矿流体与围岩之间的水岩作用,并提供容矿空间。系统的对比研究发现,大冶地区的矽卡岩型铁矿和矽卡岩型铁铜矿的赋矿地层、热液硬石膏/石膏规模和硫同位素值组成均存在明显的差异,暗示这些矿床的成矿围岩存在显著的差异。鄂东矿集区尺度的硫同位素等值线所揭示的空间变化规律具有重要的找矿指示作用:在天青石矿区(如狮子立山)或附近可能具有寻找大冶式矽卡岩型铁矿床或铁铜矿床的潜力,而在硬石膏/石膏发育的矽卡岩型铁矿区(如金山店铁矿田和程潮铁矿)或附近则具有寻找狮子立山式热液天青石矿床的潜力。     

西昆仑阿克萨依铁矿二长花岗岩岩石成因及动力学背景:年代学、地球化学及Sr-Nd-Pb-Hf同位素约束

对甜水海地块东北部阿克萨依矽卡岩型铁矿区内与矿化有关的二长花岗岩开展LA-ICP-MS锆石U-Pb年代学、全岩主微量元素、Sr-Nd-Pb同位素及锆石Lu-Hf同位素研究,旨在厘定花岗岩的形成时代、岩石成因及成矿动力学背景.LA-ICP-MS锆石U-Pb定年结果表明,二长花岗岩侵位年龄为12.37±0.18 Ma(中新...     

安徽峙门口铜-铁-金-硫矿床地球化学特征

峙门口铜—铁—金—硫矿床发育上部层状矿体和下部脉状矿体。上部层状矿石重晶石的 δ34 S 值为+1410‰～+1890‰。上部层状矿石黄铁矿和方铅矿的 δ34 S 值为+350‰～+584‰, 下部脉状矿石黄铁矿的 δ34 S 值为+480‰～+680‰。下部脉状矿石中脉石英的 δ18 O 值为+143‰～+185‰, δ30Si值为-03‰～-02‰。下部脉状矿石黄铁矿Re/Os比值为78342～175540,上(顶)部层状矿石中黄铁矿Re/Os比值为62298～169545。从下部脉状矿石到上部层状矿石,δ34 S 值、Re/Os比值和流体包裹体温度249 ℃→97 ℃逐渐降低, 206 Pb/204 Pb、 207 Pb/204 Pb、 208 Pb/204 Pb 平均值和Os总、Re、 187 Re 等含量逐渐增高。矿石黄铁矿Re Os 同位素等时线年龄303±33 Ma。地质地球化学特征反映峙门口铜—铁—金—硫矿床为海底热水喷流沉积成因。      

纳米镍／铁对四氯乙烯快速脱氯试验

实验室合成的纳米Ni/Fe(粒径20~60nm,比表面积为52. 61m2 /g),在固液比相对较低条件下(5. 4g/L),对四氯乙烯(PCE)能够快速并完全脱氯,在6h时,脱氯率为99. 70%,反应符合准一级反应动力学方程,标准化反应速率常数kSA为3. 04mL·m-2·h-1。反应过程中水样未检测到其他的氯代中间产物或最终产物,无毒的烃类乙烷(C2H6 )是主要产物,约占加入时PCE总碳质量的94% ~110%。试验结果说明加氢催化剂Ni的存在,通过原电池腐蚀作用提高了脱氯速率并同时增加了良性产     

Photochemical activity and characterization of the complex of humic acids with iron(III)

This study examined the effects of humic acids (HA) and Fe(III)–HA complex on the photodegradation of atrazine, one of the most widely used herbicides. It was shown that the photolysis of atrazine proceeded via first-order reaction kinetics and that atrazine photodegradation was inhibited by the presence of HA, whereas the rate for atrazine photolysis was promoted in solutions containing both HA and Fe(III). Interactions of Fe(III) with HA were characterized by SEM, EDX, UV–Vis and FTIR, revealing that Fe(III)–HA complex was formed by ligand exchange between oxygen groups of HA and Fe(III). Using fluorescence spectrometry the stability constant (K_c) and the fraction of fluorophores available for complexation (f) were obtained as log K_c = 4.28 and f = 74%. Photoformed Fe(II) by ligand-to-metal charge-transfer (LMCT) within the Fe(III)–HA complex was the most important factor involved in photolysis of atrazine, since Fe(II) was the reactant to generate hydroxyl radical. Thus, the rate of atrazine photodegradation in natural sunlit waters is dependent on both the amount of iron present and the interaction between HA and iron.     

Physical behavior of the SEEDS iron-fertilized patch by sulphur hexafluoride tracer release

The first iron (Fe) – fertilization experiment in the western North Pacific was carried out using SF₆ to trace the Fe-fertilized water mass. A solution in 10,800 liters of seawater of 350 kg of Fe and 0.48 M of SF₆ tracer was released into the mixed layer over a 8 × 10 km area. On the first underway transects through the patch after the Fe release, we observed a significant increase of dissolved Fe (ave. 2.89 nM). The fertilized patch was traced for 14 days by on-board SF₆ analysis. A Lagrangian frame of reference was maintained by the use of a drogued GPS buoy released at the center of the patch. The patch moved westward at a rate of 6.8 km d⁻¹. Mixed layer depth increased from 8.5 to 15 m during the experiment. Horizontal diffusivity was determined by the change of SF₆ concentration in the patch. The horizontal diffusivity increased during the experiment. We evaluate here the fate of Fe in a Fe-fertilized patch using the dilution rate determined from sulphur hexafluoride (SF₆) concentration. Dissolved Fe concentrations subsequently decreased rapidly to 0.15 nM on Day 13. However, the dissolved Fe half-life of 43 h was relatively longer than in previous Fe-enrichment studies, and we observed a larger increase of the centric diatom standing stock and corresponding drawdown of macro-nutrients and carbon dioxide than in the previous studies. The most important reason for the larger response was the phytoplankton species in the western North Pacific. In addition, the smaller diffusivity and shallower mixed layer were effective to sustain the higher dissolved Fe concentration compared to previous experiments. This might be one reason for the larger response of diatoms in SEEDS.