二价铁氧化对铁锰循环功能微生物活性的影响及机制

地质微生物是沉积环境中铁、锰氧化还原循环的主要驱动因子,铁锰共存环境中二价铁氧化对不同铁、锰循环功能微生物活性的影响差异和机制尚不清楚.以铁还原菌Shewanella oneidensis MR-1、铁氧化菌Pseudogulbenkiania sp.strain 2002、锰氧化菌Pseudomonas putida MnB1和Leptothrix discophora SS-1作为代表性的铁、锰循环功能微生物,利用平板计数、荧光显微镜等手段探究了Fe(II)氧化对功能微生物活性的影响差异及机制.结果表明0.05 mM Fe2+氧化60 min可使MR-1和MnB1的活菌数量降低4~5个数量级,SS-1及S.2002无显著失活.Fe(II)氧化产生的吸附态。OH和胞内。OH是细菌失活的主要原因,胞外H₂O₂、胞外游离态。OH和三价铁氧化物是细菌失活的次要原因,SS-1及S.2002产生了氧化应激反应,成功抵御了活性氧化物种.      

Integration of zircon and apatite U–Pb geochronology and geochemical mapping of the Wude basalts(Emeishan large igneous province):A tool for a better understanding of the tectonothermal and geodynamic evolution of the Emeishan LIP

Radiogenic isotopic dating and Lu–Hf isotopic composition using laser ablation-inductively coupled plasma-mass spectrometry(LA-ICP-MS)of the Wude basalt in Yunnan province from the Emeishan large igneous province(ELIP)yielded timing of formation and post-eruption tectonothermal event.Holistic lithogeochemistry and elements mapping of basaltic rocks were further reevaluated to provide insights into crustal contamination and formation of the ELIP.A zircon U–Pb age of 251.3±2.0 Ma of the Wude basalt recorded the youngest volcanic eruption event and was consistent with the age span of 251-263 Ma for the emplacement of the ELIP.Such zircons hadε_Hf(t)values ranging from7.3 to+2.2,identical to those of magmatic zircons from the intrusive rocks of the ELIP,suggesting that crust-mantle interaction occurred during magmatic emplacement,or crust-mantle mixing existed in the deep source region prior to deep melting.The apatite U–Pb age at 53.6±3.4 Ma recorded an early Eocene magmatic superimposition of a regional tectonothermal event,corresponding to the Indian–Eurasian plate collision.Negative Nb,Ta,Ti and P anomalies of the Emeishan basalt may reflect crustal contamination.The uneven Nb/La and Th/Ta values distribution throughout the ELIP supported a mantle plume model origin.Therefore,the ELIP was formed as a result of a mantle plume which was later superimposed by a regional tectonothermal event attributed to the Indian–Eurasian plate collision during early Eocene.     

Geochronological and geochemical evidence for a Late Ordovician to Silurian arc-back-arc system in the northern Great Xing'an Range,NE China

The early Paleozoic tectonic evolution of the Xing'an-Mongolian Orogenic Belt is dominated by two oceanic basins on the northwestern and southeastern sides of the Xing'an Block,i.e.,the Xinlin-Xiguitu Ocean and the Nenjiang Ocean.However,the early development of the Nenjiang Ocean remains unclear.Here,we present zircon U-Pb geochronology and whole-rock elemental and Sr-Nd isotopic data on the gabbros in the Xinglong area together with andesitic tuffs and basalts in the Duobaoshan area.LA-ICP-MS zircon U-Pb dating of gabbros and andesitic tuffs yielded crystallization ages of 443-436 Ma and 452-451 Ma,respectively.The Early Silurian Xinglong gabbros show calc-alkaline and E-MORB affinities but they are enriched in LILEs,and depleted in HFSEs,with relatively low U/Th ratios of 0.18-0.36 andεNd(t)values of-1.6 to+0.5.These geochemical features suggest that the gabbros might originate from a mantle wedge modified by pelagic sediment-derived melts,consistent with a back-arc basin setting.By contrast,the andesitic tuffs are characterized by high MgO(>5 wt.%),Cr(138-200 ppm),and Ni(65-110 ppm)contents,and can be termed as high-Mg andesites.Their low Sr/Y ratios of 15.98-17.15 and U/Th values of 0.24-0.25 and moderate(La/Sm)_n values of 3.07-3.26 are similar to those from the Setouchi Volcanic Belt(SW Japan),and are thought to be derived from partial melting of subducted sediments,and subsequent melt-mantle interaction.The Duobaoshan basalts have high Nb(8.44-10.30 ppm)and TiO2 contents(1.17-1.60 wt.%),typical of Nb-enriched basalts.They are slightly younger than regional adakitic rocks and have positiveεNd(t)values of+5.2 to+5.7 and are interpreted to be generated by partial melting of a depleted mantle source metasomatized by earlier adakitic melts.Synthesized with coeval arc-related igneous rocks from the southeastern Xing'an Block,we propose that the Duobaoshan high-Mg andesitic tuffs and Nbenriched basalts are parts of the Late Ordovician and Silurian Sonid Zuoqi-Duobaoshan arc belt,and they were formed by the northwestern subduction of the Nenjiang Ocean.Such a subduction beneath the integrated Xing'an-Erguna Block also gave rise to the East Ujimqin-Xinglong igneous belt in a continental back-arc basin setting.Our new data support an early Paleozoic arc-back-arc model in the northern Great Xing'an Range.     

鄂东铁矿成矿地质特征与找矿预测

鄂东铁矿地处长江中下游铁铜多金属成矿带西部,三叠系下统大冶群及中上统蒲圻群是鄂东铁铜矿主要成矿地层,岩浆夕卡岩型铁铜矿成矿与其关系密切.侵入接触带构造,捕虏体接触带构造,断裂叠加接触带构造,断裂构造是矿床的容矿构造.以中酸性岩为主的燕山期岩浆岩提供了主要的成矿物质来源.文章在系统研究以往地质物探资料的基础上,阐述了鄂东地区铁矿成矿地质特征,总结了该区铁矿的成矿规律,并进行了成矿预测,提出了下一步鄂东地区铁矿找矿方向.     

Research on red tide occurrences using enclosed experimental ecosystems in west Xiamen Harbor, China—Relationship between various factors and red tide occurrences

A series of enclosed ecosystem experiments were conducted in a land-based tank near the seaside of West Xiamen Harbor. The results of experiments conducted in different seasons and years showed a repeatable phytoplankton succession. In this relatively stable ecosystem with added nutrients and trace metals, diatoms dominated initially, dinoflagellates dominated in the later stage, and dinoflagellate red tides eventually occurred. Vitamin B₁₂ enrichment may speed up this succession process. Stirring the water column could stop this process. Soluble Mn at a level of 3–4 μg/L in seawater, which also is the existing concentration of soluble Mn in Xiamen Harbor seawater, is sufficient for the multiplication of algae and occurrence of red tide. The present study showed that excessive soluble Mn in Xiamen Harbor cannot cause red tide, and that Fe was one of the important factors causing diatiom red tide in this present study. Project 39570145 supported by NSFC.     

Hydrodynamic performance of a T-shaped floating breakwater

The comprehensive utilization of floating breakwaters, specially acting as a supporting structure for offshore marine renewable energy explorations, has received more and more attention recently. Based on linear water-wave theory, the hydrodynamic performance of a T-shaped floating breakwater is semi-analytically investigated through the matched eigenfunction expansion method (MEEM). Auxiliary functions, to speed up the convergence and improve the accuracy in the numerical computations, are introduced to represent the singular behavior of fluid field near the lower salient corners of the structure. The effects of the height and installation position of the vertical screen on the reflection and transmission coefficients, dynamic response and wave forces are examined. It is found that the presence of the screen shifts the resonance frequency of RAO for both surge and pitch modes to the low-frequency area, while has no effect on heave mode. The identical added masses, damping and transmission coefficients can be obtained in the cases where the screen holds the same distance away from the longitudinal central axis of the upper box-type structure. Moreover, a relatively small pitch response can be achieved in a wide wave–frequency range, when the breakwater is Γ-shaped.     

An efficient and robust approach to predict ship self-propulsion coefficients

Achieving a reliable and accurate numerical prediction of the self-propulsion performance of a ship is still an open problem that poses some relevant issues. Several CFD methods, ranging from boundary element methods (BEM) to higher-fidelity viscous Reynolds averaged Navier–Stokes (RANS) based solvers, can be used to accurately analyze the separate problems, i.e. the open water propeller and the hull calm water resistance. However, when the fully-coupled self-propulsion problem is considered, i.e. the hull advancing at uniform speed propelled by its own propulsion system, several complexities rise up. Typical flow simplifications adopted to speed-up the simulations of the single analysis (hull and propeller separately) lose their validity requiring a more complex solver to tackle the fully-coupled problem. The complexity rises up further when considering a maneuver condition. This aspect increases the computational burden and, consequently, the required time which becomes prohibitive in a preliminary ship design stage.The majority of the simplified methods proposed in literature to include propeller effects, without directly solve the propeller flow, in a high-fidelity viscous solver are not able to provide all the commonly required self-propulsion coefficients. In this work, a new method to enrich the results from a body force based approach is proposed and investigated, with the aim to reduce as much as possible the computational burden without losing any useful result. This procedure is tested for validation on the KCS hull form in self-propulsion and maneuver conditions.     

CFD modelling of a small–scale fixed multi–chamber OWC device

Wave Energy Converters (WECs) have excellent potential as a source of renewable energy that is yet to be commercially realised. Recent attention has focused on the installation of Oscillating Water Column (OWC) devices as a part of harbor walls to provide advantages of cost–sharing structures and proximity of power generation facilities to existing infrastructure. In this paper, an incompressible three–dimensional CFD model is constructed to simulate a fixed Multi–Chamber OWC (MC–OWC) device. The CFD model is validated; the simulation results are found to be in good agreement with experimental results obtained from a scale physical model tested in a wave tank. The validated CFD model is then used for a benchmark study of 96 numerical tests. These investigate the effects of the PTO damping caused by the power take–off (PTO) system on device performance. The performance is assessed for a range of regular wave heights and periods. The results demonstrate that a PTO system with an intermediate damping can be used for all chambers in the MC–OWC device for most wave period ranges, except for the long wave periods. These require a higher PTO damping. An increased incident wave height reduces the device capture width ratio, but there is a noticeable improvement for long wave periods.     

马里亚纳海沟挑战者深渊初期多金属氧化物的 矿物学、地球化学特征及其成因环境研究

对大洋27航次在西太平洋马里亚纳海沟挑战者深渊获取的3个多金属氧化物样品进行了X射线矿物衍射分析、穆斯堡尔谱分析及地球化学元素分析,研究其矿物、地球化学特征差异。结果表明,所取样品处于多金属氧化物发育的初始阶段,具有独特的矿物地球化学特征:(1)相较于太平洋CC区及中太平洋海盆获取的多金属结核样品,本研究样品的矿物组成中含有异常高的石英、斜长石以及黏土矿物,而水羟锰矿和钙锰矿含量较低。(2)样品中铁相矿物主要为正方针铁矿(91.6%),另含少量纤铁矿(8.4%),推测是纤铁矿向更加稳定的正方针铁矿衍变的结果。(3)由于样品中深海黏土组分以及氧化物核心物质的混入,加上吸附金属氧化物时间较短,导致SiO₂和Al₂O₃含量均高于正常结核,而Fe、Mn、Cu、Co、Ni等其余金属元素含量较低。(4)由于形成时间较短,样品中稀土元素含量相对较低,ΣREE仅约为0.4×10^-3(一般太平洋CC区及中太平洋结核中稀土含量均大于1.0×10^-3);加之海水氧化还原作用的降低以及研究区海底热液活动的影响,Ce元素未表现出多金属结核中常见的正异常。     

Cartographic Design and the Space–Time Cube

This paper reports on the results of an empirical evaluation that aimed to define the effectiveness and efficiency of different visual variables in depicting the Space–Time Cube’s (STC) content. Existing STC applications demonstrate that the most used visual variables are size and colour hue. Less is known, however, about their usability metrics. The research sets design criteria for STC contents, such as space–time paths, based on the cartographic design theory. The visual variables colour hue, colour value, colour saturation, size and orientation have been applied in two different use case studies. Besides, to support the three-dimensional visual environment, depth cues such as shading and transparency were considered too. User tests have been executed based on real-world problems with particular attention for the visualization strategy and data complexity. The outcomes revealed the most efficient and effective visual variables to represent data of various complexities in the STC.