A filtering approach for estimating lake water quality from remote sensing data

In this paper we consider the estimation of lake water quality constituent distributions from hyperspectral remote sensing data. We present a computational approach that can be used to assimilate information from mathematical evolution models into data processing. The method is based on a reduced order iterated extended Kalman filter, and a convection–diffusion model is used to describe the movement of the water quality constituents. The performance of the technique is evaluated in a simulation study. The results show that the filter approach with an appropriate evolution model yields estimates that have better spatial and temporal resolutions than those obtained with conventional methods. Furthermore, the use of a feasible evolution model may make it possible to obtain information also on the concentrations in the lower parts of the lake.     

Cartographic Design and the Space–Time Cube

This paper reports on the results of an empirical evaluation that aimed to define the effectiveness and efficiency of different visual variables in depicting the Space–Time Cube’s (STC) content. Existing STC applications demonstrate that the most used visual variables are size and colour hue. Less is known, however, about their usability metrics. The research sets design criteria for STC contents, such as space–time paths, based on the cartographic design theory. The visual variables colour hue, colour value, colour saturation, size and orientation have been applied in two different use case studies. Besides, to support the three-dimensional visual environment, depth cues such as shading and transparency were considered too. User tests have been executed based on real-world problems with particular attention for the visualization strategy and data complexity. The outcomes revealed the most efficient and effective visual variables to represent data of various complexities in the STC.     

Cartographic Symbol Design Considerations for the Space–Time Cube

The cartographic representation of geographic phenomena in the space–time cube comes with special challenges and opportunities when compared with two-dimensional maps. While the added dimension allows the display of attributes that vary with time, it is difficult to display rapidly varying temporal data given the limited display height. In this study, we adapt 2D cyclic point symbols to construct 3D surfaces designed along a helical path for the space–time cube. We demonstrate how these complex?3D helical surfaces can display detailed data, including data reported daily over 100 years and data reported in four-hour intervals over a year. To create the point symbols, each value is plotted along the curve of a helix, with each turn of the helix representing one year or week, respectively. The model is modified by varying the radii from the time axis to all points using the attribute value, in these cases maximum daily temperature and four-hourly ridership, and then creating a triangulated surface from the resulting points. Using techniques common to terrain representation, we apply hue and saturation to the surface based on attribute values, and lightness based on relief shading. Multiple surfaces can be displayed in a space–time cube with a consistent time interval facing the viewer, and the surfaces or viewer perspective can be rotated to display synchronized variations. We see this method as one example of how cartographic design can refine or enhance operations in the space–time cube.     

Comparison of Cu and Zn cycling in eutrophic lakes with oxic and anoxic hypolimnion

Data on the cycling of Cu and Zn in two eutrophic lakes are presented: Lake Greifen that becomes seasonally anoxic in its hypolimnion and Lake Sempach that is aerated during winter and oxygenated during summer. They suggest that hypolimnetic oxygenation 1) enhances the release of copper from the sediment but 2) also accelerates the entrapment and deposition of Cu and Zn by freshly formed Mn- and Fe-oxides.     

BIFoR FACE: Water–soil–vegetation–atmosphere data from a temperate deciduous forest catchment,including under elevated CO2

The ecosystem services provided by forests modulate runoff generation processes, nutrient cycling and water and energy exchange between soils, vegetation and atmosphere. Increasing atmospheric CO₂ affects many linked aspects of forest and catchment function in ways we do not adequately understand. Global levels of atmospheric CO₂ will be around 40% higher in 2050 than current levels, yet estimates of how water and solute fluxes in forested catchments will respond to increased CO₂ are highly uncertain. The Free Air CO₂ Enrichment (FACE) facility of the University of Birmingham's Institute of Forest Research (BIFoR) is the only FACE in mature deciduous forest. The site specializes in fundamental studies of the response of whole ecosystem patches of mature, deciduous, temperate woodland to elevated CO₂ (eCO₂). Here, we describe a dataset of hydrological parameters – seven weather parameters at each of three heights and four locations, shallow soil moisture and temperature, stream hydrology and CO₂ enrichment – retrieved at high frequency from the BIFoR FACE catchment.     

Drying increases organic colloidal mobilization in the karst vadose zone: Evidence from a 15-year cave-monitoring study

Understanding the hydrological processes of colloids within the karst vadose zone is vital to the security of karst groundwater and providing appropriate paleohydrological explanations of colloid-facilitated metals in speleothem. This study addresses the mobilization mechanisms driving colloidal organic matter (COM) transport in the karst vadose zone using a 15-year long monthly monitoring dataset from a cave drip point (HS4) in Heshang Cave, Qingjiang Valley, China. Variations in COM concentrations were reported as the fluorescence difference values of raw and filtered (<0.22 μm) samples at an excitation wavelength of 320 nm and emission wavelength of ~400 nm. A fluorescence humification index (HIX) lower than 0.8 and an autochthonous index (BIX) higher than 1.2 indicated that the origin of COM was mainly from the karst vadose zone, rather than the soil zone. The COM concentration varied from 0.001 to 0.038 Raman Unit (RU), with evident seasonal fluctuations. Rising limbs for COM values occurred prior to rising limbs within a dripwater hydrograph; moreover, the COM peak values corresponding to the beginning of the increasing hydrograph generally suggested that the mobilization of COM reflected the movement of the air–water interface (AWI) in the karst vadose zone rather than rainfall intensity or flow velocity. COM peak values were positively correlated with the antecedent drying duration and negatively correlated with HIX values. These phenomena may be explained by the increased amount of organic matter that was aggregated and absorbed on the surface of carbonate in the karst vadose zone during a longer drying duration. Moreover, the longer drying duration was also beneficial to autochthonous biological activity, which subsequently decreased the HIX value of the organic matter in the karst vadose zone. The movement of AWI and the drying duration are both controlled by the outside weather conditions. This study is therefore conducive to evaluating the security of karst groundwater in response to climate change, and challenges prevailing paleoclimate interpretations of colloid-facilitated metal abundance timeseries reported from speleothems.     

Investigation of inner-basin variation: Impact of large reservoirs on water regimes of downstream water bodies

Large dams and reservoirs alter not only the natural flow regimes of streams and rivers but also their flooding cycles and flood magnitudes. Although the effect of dams and reservoirs has been reported for some vulnerable locations, the understanding of the inner-basin variation with respect to the effects remains limited. In this study, we analyse the Three Gorges Dam (TGD) built on the Changjiang mainstream (Yangtze River) to investigate the dam effect variations in the system of interconnected water bodies located downstream. We investigated the effect of flow alterations along the downstream river network using discharge time series at different gauging stations. The river–lake interactions (referring to the interactions between the Changjiang mainstream and its tributary lakes i.e. the Dongting and Poyang lakes) and their roles in modifying the TGD effect intensity were also investigated in the large-scale river–lake system. The results show that the water storage of the tributary lakes decreased after the activation of the TGD. Severe droughts occurred in the lakes, weakening their ability to recharge the Changjiang mainstream. As a consequence, the effect of the TGD on the Changjiang flow increase during the dry season diminished quickly downstream of the dam, whereas its impact on the flow decrease during the wet season gradually exacerbated along the mainstream, especially at sites located downstream of the lake outlets. Therefore, when assessing dam-induced hydrological changes, special attention should be paid to the changes in the storage of tributary lakes and the associated effects in the mainstream. This is of high importance for managing the water resource trade-offs between different water bodies in dam-affected riverine systems.     

Impacts of groundwater flow on the evolution of a thermokarst lake in the permafrost–dominated region on the Qinghai–Tibet plateau

As a result of global warming induced permafrost degradation in recent decades, thermokarst lakes in the Qinghai–Tibet plateau (QTP) have been regulating local hydrological and ecological processes. Simulations with coupled moisture–heat numerical models in the Beiluhe basin (located in the hinterland of permafrost regions on the QTP) have provided insights into the interaction between groundwater flow and the freeze–thaw process. A total of 30 modified SUTRA scenarios were established to examine the effects of hydrodynamic forces, permeability, and climate on thermokarst lakes. The results indicate that the hydrodynamic condition variables regulate the permafrost degradation around the lakes. In case groundwater recharges to the lake, a low–temperature groundwater flow stimulates the expansion of the surrounding thawing regions through thermal convection. The thawing rate of the permafrost underlying the lake intensifies when groundwater is discharged from the lake. Under different permeability conditions, spatiotemporal variations in the active layer thickness significantly influence the occurrence of an open talik at the lake bottom. A warmer and wetter climate will inevitably lead to a sharp decrease in the upper limit of the surrounding permafrost, with a continual decrease in the duration of open talik events. Overall, our results underscore that comprehensive consideration of the relevant hydrologic processes is critical for improving the understanding of environmental and ecological changes in cold environments.     

Stormflow concentration–discharge dynamics of suspended sediment and dissolved phosphorus in an agricultural watershed

Concentration–discharge (C-Q) relationships are an effective tool for identifying watershed biogeochemical source and transport dynamics over short and long timescales. We examined stormflow C-Q, hysteresis, and flushing patterns of total suspended sediment (TSS) and soluble reactive phosphorus (SRP) in two stream reaches of a severely impaired agricultural watershed in northeastern Wisconsin, USA. The upper watershed reach—draining a relatively flat, row crop-dominated contributing area—showed predominantly anti-clockwise TSS hysteresis during storms, suggesting that particulate materials were mobilized more from distal upland sources than near- and in-channel areas. In contrast, the incised lower watershed reach produced strong TSS flushing responses on the rising limb of storm hydrographs and clockwise hysteresis, signalling rapid mobilization of near- and in-channel materials with increasing event flows. C-Q relationships for SRP showed complex patterns in both the upper and lower reaches, demonstrating largely non-linear chemodynamic C-Q behaviour during events. As with TSS, anti-clockwise SRP hysteresis in the upper reach suggested a delay in the hydrologic connectivity between SRP sources and the stream, with highly variable SRP concentrations during some events. A broad range of clockwise, anti-clockwise, and complex SRP hysteresis patterns occurred in the lower watershed, possibly influenced by in-channel legacy P stores and connection to tile drainage networks in the lower watershed area. Total suspended sediment and SRP responses were also strongly related to precipitation event characteristics including antecedent precipitation, recovery period, and precipitation intensity, highlighting the complexity of stormflow sediment and phosphorus responses in this severely impaired agricultural stream.     

The δ13C–δ18O variations in marble in the Hida Belt,Japan

Marble has a great potential to understand a history of various geological events occurring during tectonic processes. In order to decode metamorphic–metasomatic records on C–O isotope compositions of marble at mid-crustal conditions, we conducted a C–O–Sr isotope study on upper amphibolite-facies marbles and a carbonate–silicate rock from the Hida Belt, which was once a part of the crustal basement of the East Asian continental margin. Carbon and oxygen isotope analyses of calcite from marbles (Kamioka area) and a carbonate–silicate rock (Wadagawa area) show a large variation of δ¹³C [VPDB] and δ¹⁸O [VSMOW] values (from −4.4 to +4.2 ‰ and +1.6 to +20.8 ‰, respectively). The low δ¹³C values of calcites from the carbonate–silicate rock (from −4.4 to −2.9 ‰) can be explained by decarbonation (CO₂ releasing) reactions; carbon–oxygen isotope modeling suggests that a decrease of δ¹³C strongly depends on the amount of silicate reacting with carbonates. The occurrence of metamorphic clinopyroxene in marbles indicates that all samples have been affected by decarbonation reactions. All δ¹⁸O values of calcites are remarkably lower than the marine-carbonate values. The large δ¹⁸O variation can be explained by the isotope exchange via interactions between marble, external fluids, and/or silicates. Remarkably low δ¹⁸O values of marbles that are lower than mantle value (~+5 ‰) suggest the interaction with meteoric water at a later stage. Sr isotope ratios (⁸⁷Sr/⁸⁶Sr = 0.707255–0.708220) might be close to their protolith values. One zircon associated with wollastonite in a marble thin-section yields a U–Pb age of 222 ± 3 Ma, which represents the timing of the recrystallization of marble, triggered by H₂O-rich fluid infiltration at a relatively high-temperature condition. Our isotope study implies that the upper amphibolite-facies condition, like the Hida Belt, might be appropriate to cause decarbonation reactions which can modify original isotope compositions of marble if carbonates react with silicates.