Comparison of two three-dimensional hydrodynamic modeling systems for coastal tidal motion

A comparison of two three-dimensional numerical modeling systems for tidal elevations and velocities in the coastal waters is presented. The two modeling systems are: (1) the Princeton Ocean Model (POM) and (2) the MIKE 3 flow model. The model performance results for Singapore's coastal waters show that the predicted tidal elevations from the two hydrodynamic modeling systems are almost identical and are in very good agreement with field measurement data. The simulated tidal current velocities match well with field measurement data at the selected stations, but it seems that the POM provides the slightly better simulation, compared to the MIKE 3 flow model. The depth profiles of the velocities obtained from the two modeling systems may be greatly different at some time, due to the vertical diffusion coefficient calculated from different turbulent sub-models in the two modeling systems. The POM generally predicts larger peak tidal velocities. The maximum speed differences for the model results from the two modeling systems occur in the top and differ from time to time and from location to location, reaching up to 20%.     

不同生长期坛紫菜多糖中组分含量的变化

于１９９０－１９９１年，运用＾１３Ｃ－ＮＭＲ和化学分析方法研究南方产和移植北方养殖的不同生长发育阶段坛紫菜多糖的组分变化，结果表明，随着藻体生长发育，坛紫菜琼胶中３，６－内醚－Ｌ－半乳糖和６－ＯＣＨ３－Ｄ－半乳糖的含量逐渐增加，而硫酸基的含量呈现先增加后减少的规律；北移坛紫菜琼胶中３，６－内醚－Ｌ－半乳糖的含量高于南方坛紫菜，而硫酸基和６－ＯＣＨ３－Ｄ－半乳糖的含量低于南方坛紫菜。     

Random wave-current interactions in water of varying depth

Refraction of incoherent random gravity waves with currents and bottom topography results in spatial variations in the spectral characteristics of the free surface. Prediction of such variations based on the radiation transfer equation is in a simple analytic form for the case of one dimensional inhomogeneities in currents and topography. This analytic form is examined in terms of two-dimensional wave number- and polar frequency-direction spectra along the associated dynamic and kinematic constraints relevant to wave breaking and reflection. Results are specialized to the simplest case of horizontal shear currents in deep and shallow water with explicit examples to illustrate the relative and combined effects of currents and topography on free surface spectra.     

Geochemical cycling in the Hooghly estuary, India

U–Th decay series isotopes, δ¹⁸O and Si measurements in the river estuarine waters and sediments of the polluted Hooghly estuary as well as the surface waters of the Bay of Bengal, its high salinity end member, are reported. Dissolved Si indicates that there are probably two mixing regimes, dissolved U behaviour is nonconservative and δ¹⁸O behaves conservatively in the overall estuarine region. Isotopes of reactive elements, viz. ²³⁴Th and ²¹⁰Po, are removed from the estuarine waters in <2 days and <1 month, respectively, which is due to high suspended matter (30–301 mg l⁻¹). ²²⁸Ra and ²²⁶Ra are profusely released into the estuarine waters in the low to mid-salinity regions.As expected, the opposite trend is observed in the case of estuarine sediments and suspended matter. Reactive isotopes of Th, ²¹⁰Pb and ²¹⁰Po are enriched, whereas Ra isotopes are depleted with respect to their parent nuclides in the estuarine sediments and suspended matter. ²³²Th/Al ratio appears well suited to study the distribution and mixing of the bed load sediments of the Ganga–Brahmaputra (G–B) and the Hooghly rivers with those from other rivers on the Bay of Bengal floor.     

Seasonal variations in faunal distribution and activity across the continental slope of the goban spur area (NE Atlantic)

Density, biomass and community structure of macrofauna were estimated together with several sediment characteristics at seven stations ranging from 208 m to 4460 m water depth along the OMEX transect in the Goban Spur area (NE Atlantic) during three seasons (October 1993, May 1994, and August 1995). Median grain size decreased with increasing water depth and showed no differences between the seasons. The percentages of organic carbon and total nitrogen were highest at mid-slope depths (1000 to 1500 m), and were significantly higher in August at the upper part of the slope to a depth of 1500 m. The C:N ratio in the surface layer amounted to 7 to 8 in May, 10 to 12 in August and 14 to 17 in October at all stations (except the deepest at 4460 m, where it was 11 in May and August), indicating arrival of fresh phytodetritus in May, and therefore seasonality in food input to the benthos. Densities of macrofauna decreased exponentially with increasing water depth. Significantly higher densities of macrofauna were found in May at the upper part of the slope to a depth of 1500 m. These differences were mainly due to high numbers of postlarvae of echinoids at the shallowest station and ophiuroids at the deeper stations. Biomass values also decreased with increasing water depth, but biomass was relatively high at the 1000 m station and low at 1500 m, due to relatively high and low mean weights of the individual macrofaunal specimens. No significant differences in biomass were found between the seasons. Respiration was high (15 to 20 mgC·m⁻²·d⁻¹) in May at the upper part of the slope to a depth of 1000 m and low (1–3 mg C·m⁻²·d⁻¹) at the deeper part. At the shallowest stations to a depth of 1000 m respiration was highest in May, at the mid-slope stations (1400–2200 m) it was highest in August, whereas the deepest stations (3600 to 4500 m) did not show any differences in respiration rates. In conclusion; seasonal variation in organic input is reflected in denstiy, community structure and activity of the macrofauna along the continental slope in the NE Atlantic.     

溴素的有机化学──I．2，4，6－三溴苯甲酸溴代和非溴代芳酯的合成

用ｍ－氨基苯甲酸作原料，经溴代、重氮化、还原脱氨、酰氯化和酯化反应等步骤，合成了六种新型的三溴苯甲酸的溴代和非溴代芳酯，即；双（２，４，６－三溴苯甲酸）－２＇，３＇，５＇，６＇－四溴－１＇，４＇－苯二酯，２，４，６－三溴苯甲酸－２＇，３＇，４＇，５＇，６＇－五溴苯酯，２，４，６－三溴苯甲酸－２＇，４＇，６＇－三溴苯酯，２，４，６－三溴苯甲酸－４＇－溴苯酯，２，４，６－三溴苯甲酸－４＇－甲基苯酯和２，４，６－三溴苯甲酸苯酯．通过对产物中碳、氢、溴元素的定量分析以及红外吸收光谱和氢核磁共振谱的研究，验证了合成产物的结构。     

环台湾岛海域半日潮波特征的三维模拟

用1997版POM海洋模式,首次应用于环台湾岛海域的潮波数值研究.得到该海域的半日潮波主要为23°N以南西太平洋传来的胁振潮.影响台湾海峡的半日潮波分别由海峡南北口传入的两支潮波,且北支强于南支.福建沿岸湄州湾-兴化湾为最强潮区,其M₂分潮最大振幅可达240cm.最强潮流区位于澎湖水道,M₂分潮最大潮流达196cm/s.环台湾岛海域潮波潮流水平结构上除海峡北部原有一个圆流点外,还发现另外存在4个新的圆流点.潮流垂直结构上主要为右偏,接近底层处为左偏.     

秋茄和榕树叶片中正构烷烃分布和单体化合物δ13C值及其光合作用

对深圳福田、阳江、海南新竹红树林秋茄Kandelia candel及海口榕树Ficusm icrocarpa叶中类脂物进行萃取,分离出正构烷烃,通过气相色谱(GC)及色谱-质谱(GC MS)分析,测出了正构烷烃的碳数分布和相对含量.气相色谱-稳定同位素比质谱仪(GC-IRMS)测定了正构烷烃单体化合物的稳定同位素组成δ13C.秋茄叶和榕树叶正构烷烃的碳数分布均为C17C33,主要集中在C23-C31(＞90%).化合物含量最高为C27的有深圳福田秋茄、海南新竹秋茄、海口榕树,而阳江秋茄为C25.单体化合物的稳定同位素δ13C深圳福田秋茄为-31.42‰-34.48‰,阳江秋茄为-31.69‰-33.62‰,海南新竹秋茄为-30.30‰-33.04‰,海口榕树为-29.92‰33.56‰;平均值分别为-32.95‰、32.67‰、31.67‰、-31.74‰.结果表明,秋茄和陆地植物榕树的光合作用都是通过C3途径,是典型C3植物.     

长江口三维潮流数值计算及动力分析

采用三维动力学数学模型对长江口潮流场进行了计算，对长江口潮流流态在一个潮周期内逐时进行了分析，并对长江口南支盐水倒灌从动力学角度进行了初步探讨。计算结果表明：文中模型较好地重演长江口潮流场，可以用于大型复杂河口工程实际中的潮流场的计算和分析。     

4-溴苯甲酸-2,3,4,5,6-五溴苯酯的合成(英文)

以苯酚和4—溴苯甲酸为原料,合成一种尚未见文献记载的新化合物——4—溴苯甲酸—2,3,4,5,6—五溴苯酯,用无水三氯化铝催化苯酚的全溴化。此产物可望在阻燃剂方面得到应用。