熔体阴离子结构团缔合过程中声子熵的研究

熔体阴离子结构团缔合过程中声子熵的研究何安明李秉新石焕文（西安地质学院，西安７１００５４）关键词熔体阴离子结构团缔合声子熵近年来，中外学者已经开始重视对岩浆熔体的物理过程和机制（如利用喇曼光谱直接测定硅酸盐熔浆的结构等）的研究工作，并取得了重要进展。...     

Fluid inclusions in mantle xenoliths

Fluid inclusions in olivine and pyroxene in mantle-derived ultramafic xenoliths in volcanic rocks contain abundant CO₂-rich fluid inclusions, as well as inclusions of silicate glass, solidified metal sulphide melt and carbonates. Such inclusions represent accidentally trapped samples of fluid- and melt phases present in the upper mantle, and are as such of unique importance for the understanding of mineral–fluid–melt interaction processes in the mantle. Minor volatile species in CO₂-rich fluid inclusions include N₂, CO, SO₂, H₂O and noble gases. In some xenoliths sampled from hydrated mantle-wedges above active subduction zones, water may actually be a dominant fluid species. The distribution of minor volatile species in inclusion fluids can provide information on the oxidation state of the upper mantle, on mantle degassing processes and on recycling of subducted material to the mantle. Melt inclusions in ultramafic xenoliths give information on silicate–sulphide–carbonatite immiscibility relationships within the upper mantle. Recent melt-inclusion studies have indicated that highly silicic melts can coexist with mantle peridotite mineral assemblages. Although trapping-pressures up to 1.4 GPa can be derived from fluid inclusion data, few CO₂-rich fluid inclusions preserve a density representing their initial trapping in the upper mantle, because of leakage or stretching during transport to the surface. However, the distribution of fluid density in populations of modified inclusions may preserve information on volcanic plumbing systems not easily available from their host minerals. As fluid and melt inclusions are integral parts of the phase assemblages of their host xenoliths, and thus of the upper mantle itself, the authors of this review strongly recommend that their study is included in any research project relating to mantle xenoliths.     

North Gondwana origin for exotic Variscan rocks in the Rhenohercynian zone of Germany

Continental margin sediments of an exotic nature, which have been thrust over the Rhenohercynian zone of Central Germany, occur mainly in olistostromes of Lower Carboniferous age. A stratigraphy compiled from the exotic rocks reflects the wide spectrum of continental shelf and adjacent basinal facies that existed at least from the Early Ordovician to the Early Carboniferous. Facies and faunal relationships are comparable with those in the Palaeozoic of the western Mediterranean region, Saxothuringia (south-east Germany) and the Barrandian area (Czech Republic), which suggests deposition at the northern margin of the Gondwana Palaeozoic supercontinent. Among the exotic rocks, a Middle Devonian to Early Carboniferous facies, referred to as Flinzkalk, contains sediments showing characteristics of contourites. They may have originated from reworked turbidites, formed under a current which flowed parallel to the North Gondwana margin, similar to the Gulf Stream flowing along eastern North America today.     

The origin of basic rocks of the Korosten AMCG complex, Ukrainian shield: Implication of Nd and Sr isotope data

The Korosten complex is a Paleoproterozoic gabbro–anorthosite–rapakivi granite intrusion which was emplaced over a protracted time interval — 1800–1737 Ma. The complex occupies an area of about 12 000 km² in the north-western region of the Ukrainian shield. About 18% of this area is occupied by various mafic rocks (gabbro, leucogabbro, anorthosite) that comprise five rock suites: early anorthositic A₁ (1800–1780 Ma), main anorthositic A₂ (1760 Ma), early gabbroic G₃ (between 1760 and 1758 Ma), late gabbroic G₄ (1758 Ma), and a suite of dykes D₅ (before 1737 Ma). In order to examine the relationships between the various intrusions and to assess possible magmatic sources, Nd and Sr isotopic composition in mafic whole-rock samples were measured. New Sr and Nd isotope measurements combined with literature data for the mafic rocks of the Korosten complex are consistent and enable construction of Rb–Sr and Sm–Nd isochronous regressions that yield the following ages: 1870 ± 310 Ma (Rb–Sr) and 1721 ± 90 Ma (Sm–Nd). These ages are in agreement with those obtained by the U–Pb method on zircons and indicate that both Rb–Sr and Sm–Nd systems have remained closed since the time of crystallisation. In detail, however, measurable differences in isotopic composition of the Korosten mafic rock depending on their suite affiliation were revealed. The oldest, A₁ rocks have lower Sr (⁸⁷Sr/⁸⁶Sr₍₁₇₆₀₎ = 0.70233–0.70288) and higher Nd (εNd₍₁₇₆₀₎ = 1.6–0.9) isotopic composition. The most widespread A₂ anorthosite and leucogabbro display higher Sr and lower Nd isotopic composition: ⁸⁷Sr/⁸⁶Sr₍₁₇₆₀₎ = 0.70362, εNd₍₁₇₆₀₎ varies from 0.2 to − 0.7. The G₃ gabbro–norite has slightly lower εNd₍₁₇₆₀₎ varying from − 0.7 to − 0.9. Finally, G₄ gabbroic rocks show relatively high initial ⁸⁷Sr/⁸⁶Sr (0.70334–0.70336) and the lowest Nd isotopic composition (εNd₍₁₇₆₀₎ varies from − 0.8 to − 1.4) of any of the mafic rocks of the Korosten complex studied to date. On the basis of Sr and Nd isotopic composition we conclude that Korosten initial melts may have inherited their Nd and Sr isotopic characteristics from the lower crust created during the 2.05–1.95 Ga Osnitsk orogeny and 2.0 Ga continental flood basalt event. Indeed, εNd₍₁₇₆₀₎ values in Osnitsk rocks vary from 0.0 to − 1.9 and from 0.2 to 3.4 in flood basalts. We suggest that these rocks being drawn into the upper mantle might melt and give rise to the Korosten initial melts. ⁸⁷Sr/⁸⁶Sr₍₁₇₆₀₎ values also support this interpretation. We suggest that the Sr and Nd isotopic data currently available on mafic rocks of the Korosten complex are consistent with an origin of its primary melts by partial melting of lower crustal material due to downthrusting of the lower crust into upper mantle forced by Paleoproterozoic amalgamation of Sarmatia and Fennoscandia.     

新疆北部的富镁火成岩

本文重点讨论的富镁安山岩(MAs)是指 SiO_2>53%,Mg~#≥55的安山岩,也包括富镁英安岩和富镁闪长岩。阿尔泰南的富锾安山岩形成于中泥盆世,东、西天山和阿拉套山的富镁安山岩形成于石炭纪。本区富镁安山岩 SiO_2 53%～65%,TiO_2含量低于1%(0.21%～1.08%),平均0.72%;MgO 平均5.90%,与国外玻安岩平均值相比,Mg 含量较低,Ti、K、Na 含量较高。稀土元素总合量低(<100×10~(-6),范围15～95×10~(-6)),相对富重稀土(La/Yb)_N0.98～6.4,多数在4±;Eu 弱亏损到无亏损(Eu/Eu~*0.65～1.15)。相容微量元素 Cr、Ni 含量高,分别为72×10~(-6)～790×10~(-6)和29×10~(-6)～276×10~(-6);高场强元素 Nb、Ta、Ti 明显亏损;相对富集流体中富集的大离子亲石元素 Rb、K、Pb;Y 含量较高(>15×10~(-6));Sr/Y 比值较低(4.4～6.2)。(~(143)Nd/~(144)Nd)_i 值变化范围较大0.51221～0.51255,ε_(Nd)(t) 0.28- 7.2,Nd 模式年龄 t_(DM)485～1220Ma;(~(87)Sr/~(86)Sr)_i 值变化范围较大0.7029～0.7065,在ε_(Nd)(t)-(~(87)Sr/~(86)Sr)_i 图解中位于第一象限。上述特点表明,本区富镁安山岩源区为复合源,包括有蚀变洋壳、弧前增生棱柱的不成熟、新生地壳物质及地幔楔橄榄岩。成岩作用具复合性,既有俯冲洋壳板片的部分熔融,又有俯冲板片熔体对地幔楔橄榄岩的熔体交代作用。形成于特殊构造环境:高地热梯度和富挥发分;导致弧前增生棱柱俯冲的俯冲剥蚀作用;由俯冲板片撕裂、断离所形成的软流圈窗或洋脊俯冲。     

Intrusion of ultramafic magmatic bodies into the continental crust: Numerical simulation

Intrusions of ultramafic bodies into the lower density continental crust are documented for a large variety of tectonic settings spanning continental shields, rift systems, collision orogens and magmatic arcs. The intriguing point is that these intrusive bodies have a density higher by 300-500 kg m⁻³ than host rocks. Resolving this paradox requires an understanding of the emplacement mechanism. We have employed finite differences and marker-in-cell techniques to carry out a 2D modeling study of intrusion of partly crystallized ultramafic magma from sublithospheric depth to the crust through a pre-existing magmatic channel. By systematically varying the model parameters we document variations in intrusion dynamics and geometry that range from funnel- and finger-shaped bodies (pipes, dikes) to deep seated balloon-shaped intrusions and flattened shallow magmatic sills. Emplacement of ultramafic bodies in the crust lasts from a few kyr to several hundreds kyr depending mainly on the viscosity of the intruding, partly crystallized magma. The positive buoyancy of the sublithospheric magma compared to the overriding, colder mantle lithosphere drives intrusion while the crustal rheology controls the final location and the shape of the ultramafic body. Relatively cold elasto-plastic crust (T_Moho = 400 °C) promotes a strong upward propagation of magma due to the significant decrease of plastic strength of the crust with decreasing confining pressure. Emplacement in this case is controlled by crustal faulting and subsequent block displacements. Warmer crust (T_Moho = 600 °C) triggers lateral spreading of magma above the Moho, with emplacement being accommodated by coeval viscous deformation of the lower crust and fault tectonics in the upper crust. Strong effects of magma emplacement on surface topography are also documented. Emplacement of high-density, ultramafic magma into low-density rocks is a stable mechanism for a wide range of model parameters that match geological settings in which partially molten mafic-ultramafic rocks are generated below the lithosphere. We expect this process to be particularly active beneath subduction-related magmatic arcs where huge volumes of partially molten rocks produced from hydrous cold plume activity accumulate below the overriding lithosphere.     

Melting of hydrous pyroxenites with alkali amphiboles in the continental mantle: 1. Melting relations and major element compositions of melts

Melting experiments on ultramafic rocks rich in the hydrous minerals phlogopite or phlogopite + K-richterite, some including 5% of accessory phases, have been conducted at 15 and 50 kbar. The assemblages represent probable source components that contribute to melts in cratonic regions, but whose melt compositions are poorly known. A main series of starting compositions based on MARID xenoliths consisted of a third each of clinopyroxene (CPX), phlogopite (PHL) and K-richterite (KR) with or without 5% ilmenite, rutile or apatite. Additional experiments were run without KR and with higher proportions of accessory phases. Melt traps were used at near-solidus temperatures to facilitate accurate analysis of well-quenched melts, for which reversal experiments demonstrate equilibrium.Results show that KR melts rapidly and completely within 50 °C of the solidus, so that melts reflect the composition of the amphibole and its melting reaction. Melts have high SiO₂ and especially K₂O but low CaO and Al₂O₃ relative to basaltic melts produced from peridotites at similar pressures. They have no counterparts amongst natural rocks, but most closely resemble leucite lamproites at 15 kbar. KR and PHL melt incongruently to form olivine (OL) and CPX at 15 kbar, promoting SiO₂ contents of the melt, whereas orthopyroxene OPX is increasingly stable at lower lithosphere pressures, leading to an increase in MgO and decrease in SiO₂ in melts, which resemble olivine lamproites. Melts of mica pyroxenites without KR are richer in CaO and Al₂O₃ and do not resemble lamproites. These experiments show that low CaO and Al₂O₃ in igneous rocks is not necessarily a sign of a depleted peridotite source. Accessory phases produce melts exceptionally rich in P₂O₅ or TiO₂ depending on the phases present and are unlike any melts seen at the Earth’s surface, but may be important agents of metasomatism seen in xenoliths. The addition of the 5% accessory phases ilmenite, rutile or apatite result in melting temperatures a few ten of degrees lower; at least two of these appear essential to explain the compositions of many alkaline igneous rocks on cratons.Melting temperatures for CPX + PHL + KR mixtures are close to cratonic geotherms at depths > 130 km: minor perturbations of the stable geotherm at >150 km will rapidly lead to 20% melting. Melts of hydrous pyroxenites with a variety of accessory phases will be common initial melts at depth, but will change if reaction with wall-rocks occurs, leading to volcanism that contains chemical components of peridotite even though the temperature in the source region remains well below the melting point of peridotite. At higher temperatures, extensive melting of peridotite will dilute the initial alkaline melts: this is recognizable as alkaline components in basalts and, in extreme cases, alkali picrites. Hydrous pyroxenites are, therefore, components of most mantle-derived igneous rocks: basaltic rocks should not be oversimplified as being purely melts of peridotite or of mixtures of peridotite and dry pyroxenite without hydrous phases.     

Reproductive and recruitment traits as indicators of the invasive potential of Kalanchoe daigremontiana (Crassulaceae) and Stapelia gigantea (Apocynaceae) in a Neotropical arid zone

Populations of two ornamental exotic species, Kalanchoe daigremontiana and Stapelia gigantea, have been recently detected inside a protected area containing arid ecosystems in Venezuela. We indirectly tested their invasive potential by characterizing their reproductive biology and recruitment patterns and comparing our estimates against Baker's Law and reproductive profiles reported for invasive plants. K. daigremontiana is autogamous, produces >16,000 seeds per plant and also reproduces clonally. Despite low seed viability (17.9%) and germination rates (11.9%), seeds were present in the seed bank. Plantlets of asexual origin showed high survival (75–100%) compared to seedlings of sexual origin (10%). S. gigantea is self-incompatible, xenogamous and produces close to 1500 seeds per m² of plant tissue. Seed viability (77%) and germination rates (62%) were high, but this species is not represented in the seed bank. It has a vegetative growth. A combination of reproductive and recruitment attributes, which match those considered in Baker's Law and others reported for invasive plants, confer K. daigremontiana and S. gigantea the potential to invade Neotropical arid zones; the former mainly through selfing and production of numerous asexual plantlets, and the latter through an association with a locally abundant pollinator and production of wind dispersed seeds.     

块状榴辉岩920℃开放体系脱水部分熔融过程及熔体成分研究

选取江苏省东海青龙山含钠云母的石英榴辉岩块状样品,在0.1 GPa、920 ℃恒温加热4 h的条件下,进行了开放体系的脱水部分熔融实验.样品中含有钠云母、蓝闪石和绿辉石退变形成的后成合晶中的角闪石等含水矿物.该榴辉岩的熔融可以划分为3个阶段:含水矿物的脱水暗化、部分熔融和几乎全部熔融阶段.熔融从含水矿物的脱水暗化开始,玻璃质熔体首先出现在含水矿物边界.在不同的局部熔融体系内,熔体成分从基性到酸性,受到局部熔融体系内部物质组成的控制,与全岩化学成分无关.     

Melt inclusions from the deep Slave lithosphere: implications for the origin and evolution of mantle-derived carbonatite and kimberlite

Melt inclusions in clinopyroxenes from lherzolitic xenoliths from the deep lithospheric mantle beneath the Slave Craton (Lac de Gras area, Canada) reveal multiple origins for carbonatitic melts. One type of inclusions consists of a series of silicate–carbonate–silicate concentric layers, interpreted to have unmixed under disequilibrium conditions during rapid ascent to the surface. Bulk major- and trace-element compositions are typical of Group 1 kimberlites and quantitative nuclear microprobe imaging of the globules reveals fractionation of related elements (e.g. F–Br, Nb–Ta) between the silicate and carbonate components. The globules probably formed by partial melting of carbonated peridotite, consistent with results of melting experiments and some models for the generation of kimberlite magmas. They provide evidence for a genetic relationship between some carbonate-rich magmas and ultramafic silicate magmas, and for the possibility of unmixing processes of these melts during their evolution.

The second inclusion type comprises carbonate-rich globules interpreted as samples of Mg-carbonatite melt that quenched on ascent to the surface. Bulk major- and trace-element compositions indicate that the melts were derived from a carbonate-rich source and oxygen, carbon, and strontium isotope data are consistent with the involvement of recycled crustal material and suggest that some mantle-derived carbonatites are unrelated to kimberlites.