地质微生物地球化学作用的意义与展望

概要论述了地质微生物学、地下水微生态学、微生物地球化学作用的基本概念、研究内容、研究现状、科学意义、关键问题、发展前景和在地下水环境保护中的作用。该研究领域不仅拓宽了整个地质科学的研究范畴,而且推动了地质科学的发展,具有一定的创新性。     

Geochemical and isotopic investigation of the aquifer system in the Djerid-Nefzaoua basin, southern Tunisia

In the Djerid-Nefzaoua region, southern Tunisia, about 80% of agricultural and domestic water supply is provided by the complex terminal (CT) aquifer. However, 20% of this demand is provided by other hydraulically connected aquifers, namely the continental intercalaire (CI) and the Plio-Quaternary (PQ). Overexploitation of the CT aquifer for agricultural practices has contributed to the loss of the artesian condition and the decline of groundwater level which largely increased the downward leakage from the shallow PQ aquifer. Excess irrigation water concentrates at different rates in the irrigation channels and in the PQ aquifer itself. Then, it returns to the CT aquifer and mixes with water from the regional flow system, which contributes to the salinization of the CT groundwater. A geochemical and isotopic study had been undertaken over a 2-years period in order to investigate the origin of waters pumped from the CT aquifer with an emphasis on its hydraulic relationships with the underlying and the overlying CI and PQ aquifers. Geochemistry indicates that groundwater samples collected from different wells show an evolution of the water types from Na-Cl to Ca-SO₄-Cl. Dissolution of halite, gypsum and anhydrite-bearing rocks is the main mechanism that leads to the salinization of the groundwater. Isotopic data indicate the old origin of all groundwater in the aquifer system. Mixing and evaporation effects characterizing the CT and the PQ aquifers were identified using δ²H and δ¹⁸O relationship and confirmed by the conjunction of δ²H with chloride concentration.     

太原盆地地下水资源模拟研究

山西省太原盆地由于地下水长期超采,引发了地下水降落漏斗、地面沉降等环境地质问题。通过GMS建立地下水水流三维数值模型,基于模型预测了现状开采条件下地下水水位的变化趋势,并提出合理利用地下水资源的措施,为地下水资源的优化管理提供科学依据。     

An alternative Boussinesq equation considering the effect of hysteresis on coastal groundwater waves

This paper presents an alternative Boussinesq equation considering hysteresis effect via a third‐order derivative term. By introducing an improved moisture–pressure retention function, this equation describes, with reasonable precision, groundwater propagation in coastal aquifers subject to Dirichlet boundary condition of different oscillation frequencies. Test results confirmed that it is necessary to consider horizontal and vertical flows in unsaturated zone, because of their variable influences on hysteresis. Hysteresis in unsaturated zone can affect the water table wave number of groundwater wave motion, such as wave damping rate and phase lag. Oscillations with different periods exert different hysteresis effect on wave propagation. Truncation/shrinkage of unsaturated zones also affects the strength of hysteresis. These impacts can be reflected in the alternative Boussinesq equation by adjusting the parameter representing the variation rate of moisture associated with pressure change, as opposed to traditional computationally expensive hysteresis algorithms. The present Boussinesq equation is simple to use and can provide feasible basis for future coupling of groundwater and surface water models. Copyright © 2016 John Wiley & Sons, Ltd.     

Assessing regional‐scale spatio‐temporal patterns of groundwater–surface water interactions using a coupled SWAT‐MODFLOW model

Interaction between groundwater and surface water in watersheds has significant impacts on water management and water rights, nutrient loading from aquifers to streams, and in‐stream flow requirements for aquatic species. Of particular importance are the spatial patterns of these interactions. This study explores the spatio‐temporal patterns of groundwater discharge to a river system in a semi‐arid region, with methods applied to the Sprague River Watershed (4100 km²) within the Upper Klamath Basin in Oregon, USA. Patterns of groundwater–surface water interaction are explored throughout the watershed during the 1970–2003 time period using a coupled SWAT‐MODFLOW model tested against streamflow, groundwater level and field‐estimated reach‐specific groundwater discharge rates. Daily time steps and coupling are used, with groundwater discharge rates calculated for each model computational point along the stream. Model results also are averaged by month and by year to determine seasonal and decadal trends in groundwater discharge rates. Results show high spatial variability in groundwater discharge, with several locations showing no groundwater/surface water interaction. Average annual groundwater discharge is 20.5 m³/s, with maximum and minimum rates occurring in September–October and March–April, respectively. Annual average rates increase by approximately 0.02 m³/s per year over the 34‐year period, negligible compared with the average annual rate, although 70% of the stream network experiences an increase in groundwater discharge rate between 1970 and 2003. Results can assist with water management, identifying potential locations of heavy nutrient mass loading from the aquifer to streams and ecological assessment and planning focused on locations of high groundwater discharge. Copyright © 2016 John Wiley & Sons, Ltd.     

Characterizing rainfall–groundwater dynamics in a hard‐rock aquifer system using time series,geographic information system and geostatistical modelling

The aim of this study was to investigate rainfall–groundwater dynamics over space and annual time scales in a hard‐rock aquifer system of India by employing time series, geographic information system and geostatistical modelling techniques. Trends in 43‐year (1965–2007) annual rainfall time series of ten rainfall stations and 16‐year (1991–2006) pre‐monsoon and post‐monsoon groundwater levels of 140 sites were identified by using Mann–Kendall, Spearman rank order correlation and Kendall rank correlation tests. Trends were quantified by Kendall slope method. Furthermore, the study involves novelty of examining homogeneity of pre‐monsoon and post‐monsoon groundwater levels, for the first time, by applying seven tests. Regression analysis between rainfall and post‐monsoon groundwater levels was performed. The pre‐monsoon and post‐monsoon groundwater levels for four periods – 1991–1994, 1995–1998, 1999–2002 and 2003–2006 – were subjected to geographic information system‐based geostatistical modelling. The rainfall showed considerable spatiotemporal variations, with a declining trend at the Mavli rainfall station (p‐value < 0.05). The Levene's tests revealed spatial homogeneity of rainfall at α = 0.05. Regression analyses indicated significant relationships (r² > 0.5) between groundwater level and rainfall for eight rainfall stations. Non‐homogeneity and declining trends in the groundwater level, attributed to anthropogenic and hydrologic factors, were found at 5–61 more sites in pre‐monsoon compared with post‐monsoon season. The groundwater declining rates in phyllite–schist, gneiss, schist and granite formations were found to be 0.18, 0.26, 0.21 and 0.14 m year^?1 and 0.13, 0.19, 0.16 and 0.02 m year^?1 during the pre‐monsoon and post‐monsoon seasons, respectively. The geostatistical analyses for four time periods revealed linkages between the rainfall and groundwater levels. Copyright © 2013 John Wiley & Sons, Ltd.     

Impacts of groundwater flow on the evolution of a thermokarst lake in the permafrost–dominated region on the Qinghai–Tibet plateau

As a result of global warming induced permafrost degradation in recent decades, thermokarst lakes in the Qinghai–Tibet plateau (QTP) have been regulating local hydrological and ecological processes. Simulations with coupled moisture–heat numerical models in the Beiluhe basin (located in the hinterland of permafrost regions on the QTP) have provided insights into the interaction between groundwater flow and the freeze–thaw process. A total of 30 modified SUTRA scenarios were established to examine the effects of hydrodynamic forces, permeability, and climate on thermokarst lakes. The results indicate that the hydrodynamic condition variables regulate the permafrost degradation around the lakes. In case groundwater recharges to the lake, a low–temperature groundwater flow stimulates the expansion of the surrounding thawing regions through thermal convection. The thawing rate of the permafrost underlying the lake intensifies when groundwater is discharged from the lake. Under different permeability conditions, spatiotemporal variations in the active layer thickness significantly influence the occurrence of an open talik at the lake bottom. A warmer and wetter climate will inevitably lead to a sharp decrease in the upper limit of the surrounding permafrost, with a continual decrease in the duration of open talik events. Overall, our results underscore that comprehensive consideration of the relevant hydrologic processes is critical for improving the understanding of environmental and ecological changes in cold environments.     

Groundwater – the disregarded component in lake water and nutrient budgets. Part 2: effects of groundwater on nutrients

Lacustrine groundwater discharge (LGD) transports nutrients from a catchment to a lake, which may fuel eutrophication, one of the major threats to our fresh waters. Unfortunately, LGD has often been disregarded in lake nutrient studies. Most measurement techniques are based on separate determinations of volume and nutrient concentration of LGD: Loads are calculated by multiplying seepage volumes by concentrations of exfiltrating water. Typically low phosphorus (P) concentrations of pristine groundwater often are increased due to anthropogenic sources such as fertilizer, manure or sewage. Mineralization of naturally present organic matter might also increase groundwater P. Reducing redox conditions favour P transport through the aquifer to the reactive aquifer‐lake interface. In some cases, large decreases of P concentrations may occur at the interface, for example, due to increased oxygen availability, while in other cases, there is nearly no decrease in P. The high reactivity of the interface complicates quantification of groundwater‐borne P loads to the lake, making difficult clear differentiation of internal and external P loads to surface water. Anthropogenic sources of nitrogen (N) in groundwater are similar to those of phosphate. However, the environmental fate of N differs fundamentally from P because N occurs in several different redox states, each with different mobility. While nitrate behaves essentially conservatively in most oxic aquifers, ammonium's mobility is similar to that of phosphate. Nitrate may be transformed to gaseous N₂ in reducing conditions and permanently removed from the system. Biogeochemical turnover of N is common at the reactive aquifer‐lake interface. Nutrient loads from LGD were compiled from the literature. Groundwater‐borne P loads vary from 0.74 to 2900 mg PO₄‐P m^?2 year^?1; for N, these loads vary from 0.001 to 640 g m^?2 year^?1. Even small amounts of seepage can carry large nutrient loads due to often high nutrient concentrations in groundwater. Large spatial heterogeneity, uncertain areal extent of the interface and difficult accessibility make every determination of LGD a challenge. However, determinations of LGD are essential to effective lake management. Copyright © 2014 John Wiley & Sons, Ltd.     

Varying water utilization of Haloxylon ammodendron plantations in a desert‐oasis ecotone

Haloxylon ammodendron is a desert shrub used extensively in China for restoring degraded dry lands. An understanding of the water source used by H. ammodendron plantations is critical achieving sustainable vegetation restoration. We measured mortality, shoot size, and rooting depth in 5‐, 10‐, 20‐, and 40‐year‐old H. ammodendron plantations. We examined stable isotopic ratios of oxygen (δ¹⁸O) in precipitation, groundwater, and soil water in different soil layers and seasons, and in plant stem water to determine water sources at different shrub ages. We found that water acquisition patterns in H. ammodendron plantations differed with plantation age and season. Thus, the main water source for 5‐year‐old shrubs was shallow soil water. Water sources of 10‐year‐old shrubs shifted depending on the soil water conditions during the season. Although their tap roots could absorb deep soil water, the plantation main water sources were from soil water, and about 50% of water originated from shallow and mid soil. This pattern might occur because main water sources in these plantations were changeable over time. The 20‐ and 40‐year‐old shrubs acquired water mainly from permanent groundwater. We conclude that the main water source of a young H. ammodendron plantation was soil water recharged by precipitation. However, when roots reached sufficient depth, water originated mainly from the deep soil water, especially in the dry season. The deeply rooted 20‐ and 40‐year‐old shrubs have the ability to exploit a deep and reliable water source. To achieve sustainability in these plantations, we recommend a reduction in the initial density of H. ammodendron in the desert‐oasis ecotone to decelerate the consumption of shallow soil water during plantation establishment.     

Likely effects of climate change on groundwater availability in a Mediterranean region of Southeastern Spain

Groundwater resources are typically the main fresh water source in arid and semi‐arid regions. Natural recharge of aquifers is mainly based on precipitation; however, only heavy precipitation events (HPEs) are expected to produce appreciable aquifer recharge in these environments. In this work, we used daily precipitation and monthly water level time series from different locations over a Mediterranean region of Southeastern Spain to identify the critical threshold value to define HPEs that lead to appreciable aquifer recharge in this region. Wavelet and trend analyses were used to study the changes in the temporal distribution of the chosen HPEs (≥20 mm day^?1) over the observed period 1953–2012 and its projected evolution by using 18 downscaled climate projections over the projected period 2040–2099. The used precipitation time series were grouped in 10 clusters according to similarities between them assessed by using Pearson correlations. Results showed that the critical HPE threshold for the study area is 20 mm day^?1. Wavelet analysis showed that observed significant seasonal and annual peaks in global wavelet spectrum in the first sub‐period (1953–1982) are no longer significant in the second sub‐period (1983–2012) in the major part of the ten clusters. This change is because of the reduction of the mean HPEs number, which showed a negative trend over the observed period in nine clusters and was significant in five of them. However, the mean size of HPEs showed a positive trend in six clusters. A similar tendency of change is expected over the projected period. The expected reduction of the mean HPEs number is two times higher under the high climate scenario (RCP8.5) than under the moderate scenario (RCP4.5). The mean size of these events is expected to increase under the two scenarios. The groundwater availability will be affected by the reduction of HPE number which will increase the length of no aquifer recharge periods (NARP) accentuating the groundwater drought in the region. Copyright © 2016 John Wiley & Sons, Ltd.