攀枝花市大气降尘的地球化学特征

运用ICP-MS和ICP-OES分析了攀枝花市不同时段不同地点大气降尘中重金属元素含量,并对大气降尘中重金属的地球化学特征进行了分析,得出以下结论:①攀枝花市大气尘中As、Co、Mn、Pb、Ti、V的含量,与四川省其他城市相比均偏高,Zn的含量相对较低;②Cd、Mn、Pb主要分布在冶炼区和石灰石矿区,Co、Cu、Ti主要分布在石灰石矿区,Cr和V主要分布在冶炼区,As在仁和河富集较为富集,Zn集中在排土场附近,Fe集中在冶炼区和煤矿区;③除Pb外,其余十种元素旱季含量基本都高于雨季,而雨季Pb的含量却明显高于旱季。通过主成份分析,得出了在攀枝花市大气降尘中,重金属元素的来源主要为矿山污染和开采过程中产生的废水、废气。     

贵州郑家小洞内动物重金属含量及与土壤和水体的关系研究

通过对安顺郑家小洞内的动物和重金属污染进行调查研究,共获动物标本551号,隶属3门6纲10目20科29种（或类群）。对5个动物类群（螺类、马陆、斑灶马、蝙蝠粪和山蛩虫）、洞穴土壤和洞穴水的重金属含量进行了测定,研究了各动物类群的富集系数和洞穴土壤的污染指数并进行了评价。结果显示蝙蝠粪便中Zn的含量最高（670.5 mg/kg）,间接说明了洞穴外围环境中的Zn污染较为严重,马陆对Ni与斑灶马对Cr和Ni无富集能力。各元素在3个光带土壤中的平均值含量都超过了我国的土壤背景值,按顺序排列为Zn >Ni > Cu > Cr > Pb > As > Hg > Cd,水体为Zn > Cr > Ni > Cu> Pb > Hg > As > Cd。单项污染指数表明Hg、Ni和Zn为重污染,在3个光带中的平均值分别为5.11、3.18和3.20。从综合污染指数看,3个光带的平均值为2.17,属轻污染,说明该洞穴有重金属污染但不严重。      

浅成火山岩中石英斑晶的分离方法研究

在总结大量矿物分选的实践基础上,系统研究了用混合重液法分离石英斑晶的理论和操作方法及用折光率法间接测量混合重液的技术.发现了用折光率值为1.577~1.579的系列混合重液分离石英斑晶效果最好,分离纯度达到95%~98%,解决了从浅成火山岩中分选单晶石英的难题,极大地提高了石英的分离效率、纯度和回收率,从过去石英的富集率20茗提高到95%~98%,从人工挑选的几克增至几百克,可从挑选的40~80目扩大到120目.     

新疆喀拉喀什河金刚石找矿指示矿物原生表面特征研究

新疆喀拉喀什河水系的重砂矿物中发现了高铬铬铁矿、镁铝榴石、镁钛铁矿和铬透辉石等金刚石找矿指示矿物。结果表明,这些重消矿物不仅发育因河流和风力搬运作用形成的次生表面特征（如贝壳状断口、Ｖ形撞击坑等）,个别矿物还残留有金刚石找矿物原生表面特征,如丘状突起、三角和菱形熔坑等表面（ＳＳ）,且为轻微磨损类。这些残留有刻蚀表面（ＳＳ）的矿物形成于金伯利岩浆最后侵位阶段,结合该区水动力条件,推测它们被搬运蚀表面     

Environmental impacts from mining at Taojiang Mn ore deposit, central Hunan, China

The Taojiang Mn ore deposit was exploited in the early 1960s, and waste rocks were developed since then. Because the Mn ores were hosted within the metal-enriched black shales （Peng et al., 2004）, the continuous mining has led to the exposure of an immense quality of black shales, which might cause serious impacts on environments. The present study deals with this environmental issue with samples from the waste rocks, and from the surrounding soils and surface water. The mineralogy of the waste rock was studied using EMPA, then a large number of elements in all waste rock, soil, and water samples were analyzed at a wide range of concentrations with high accuracy using an Elan6000 ICP-MS machine at Guangzhou Institute of Geochemistry, Chinese Academy of Sciences. The waste rock is composed mostly of black shales, with minor Mn carbonates. Both black shales and Mn carbonates of the waste rock contain many sulfide minerals, mainly pyrite, with minor galena, sphalerite, chalcopyrite, and others. The waste rocks are enriched in many metals including Sc, V, Cr, Co, Ni, Fe, Mn, Cu, Zn, Pb, Th, U, Mo, Sb, Sn, Tl, and others, and the metals are mostly hosted within the sulfides. Weathering of waste rocks might cause emission of the following metals： V, Cd, Ni, Th, U, Mo, Sb, Tl, Sc, Cr, Cu, Zn, Sn, and minor Co, and Pb. The surrounding soils are highly enriched in Cr, Co, Cu, Zn, Mn, Mo, Cd, Tl, and Pb, with the enrichment factors of 2.67.3.8, 7.26, 7.27, 8.2, 5.7, 13, and 5.4, respectively. The element ratios （Rb/Cs, Fe/Mn, Nb/Zr, Hf/Zr, and Ba/Sr） and REE distribution patterns of the soils are similar to those of the waste rocks and bedrocks.     

Heavy metal contamination in the sediment of the Second Songhua River

The Second Songhua River was subjected to a large amount of untreated effluent from petrochemical industries in Jilin City in the 1960s to the 1970s. The objectives of this study were to investigate the mercury and other heavy metal contamination in the sediment of the river. The river bottom sediment was sampled from the river segment between Jilin City to Haerbin City in 2005. Total concentrations of Hg, Cd, Cu, Cr, Pb, Zn, Ni, As, Sc, and major cations （A1, Fe, Mg, Ca, K, Na） in the sediment were measured by atomic fluorescence spectrometer, ICP-MS, and ICP-OES, respectively, following digestion with various acids. We found the concentrations of most elements in the uncontaminated sediment were significantly correlated to those of Sc.     

重矿物分析在古地理研究中的应用——以准噶尔盆地南缘中段古近系紫泥泉子组紫三段为例

通过对准噶尔盆地南缘中段紫泥泉子组紫三段(E1-2Z3)的166件重矿物样品分析,综合古近纪紫泥泉子期的区域构造、气候、沉积物特征等因素,提出古近纪紫三段沉积期的古地理环境为:干燥气候条件下,发育同方向、多河道、间歇性辫状河,水浅、源多、坡缓的古地理环境.多条河流平行发育和迁移,河道垂直岸线伸展、各种沉积相带却平行岸线展布,相带宽度较大.     

凹凸棒石与Zn^2＋的长期作用研究

以凹凸棒石与Zn2＋为例研究粘土矿物与重金属离子长期作用过程,并运用高分辨透射电镜和X射线衍射分析粘土矿物与重金属离子长期作用的次生物相。结果表明：Zn2＋与凹凸棒石的长期作用是一个二阶段的过程,初始阶段为快速吸附作用,其后表现为慢速沉淀反应。高分辨透射电镜和X射线衍射分析表明,凹凸棒石与Zn2＋的长期作用过程中,具有纳米矿物特性的凹凸棒石表面快速水化,提高了悬浮液的pH值,诱导Zn2＋水解沉淀。而后,凹凸棒石缓慢溶解释放Al3＋和SiO44-与Zn（OH）2沉淀反应,形成Zn-A1双氢氧化物和异极矿。这一结果对认识土壤环境中重金属与粘土矿物的作用及重金属的归宿具有重要意义。     

Mobility of heavy metals from tailings to stream waters in local zinc smelting activities contaminated site

It has been found that stream waters were severely contaminated with wastes from a long-time smelting factory in Hezhang, Guizhou, China. The main sources of contamination are the smelting wastes stored in the open air and abandoned in the vicinity of stream. A method of lead isotope was adopted in order to identify relations between tailings and water contamination. Representative samples of tailings and stream sediments were collected. Mineralogical characterizations were conducted using XRD and TEM/SEM, while acid digestion was carried out for determining metal contents. BCR sequential leaching tests were performed in order to assess metal mobility. The tremendous ‘actual＇ and ‘potential＇ mobility of heavy metals indicates that the smelting waste and stream sediments present a considerable threat to the environment. Besides the chemical remobilization of heavy metals from the sediments and the reworking of riverbed sediments act as a secondary source of pollution. Also groundwater and stream water were sampled in specific locations and were measured.