雷州半岛高桥红树林沉积物中砷的分布

采用五态连续提取法(SEP)对雷州半岛高桥红树林群落内外不同深度的沉积物砷含量进行测定.结果表明,高桥红树林湿地0~60cm深处沉积物中除Al-结合态砷和Ca-结合态砷含量低,难以检出外,交换态砷、残渣态砷、Fe-结合态砷皆可检出,沉积物砷积累以残渣态砷和 Fe-结合态砷为主,总砷测定含量为7.34±0.39~10.32±0.48 mg/kg,其中以20~40cm深处沉积物总砷测含量最多;不同深度沉积物砷含量中林内与林区外裸滩呈现不同的分布规律,林外裸滩-林缘-林内的表土总砷含量的分布呈波浪式分布,以林缘为最高,总砷达9.97±1.29 mg/kg,林内显著大于林外裸滩(p值<0.05),林内沉积物对砷的吸附强度较林外裸滩高     

A comparison of Jiaojia- and Linglong-type gold deposit ore-forming fluids: Do they differ?

The Jiaodong peninsula contains the most important concentration of gold deposits in China, which can be divided into Jiaojia-type and Linglong-type deposits based on mineralization style. The former is characterized by disseminated- and stockwork-style mineralization hosted in first-order regional faults, with relatively larger tonnages and lower gold grades. The latter is characterized by massive auriferous quartz veins commonly hosted in subsidiary second- or third-order faults, with smaller tonnage but higher grade orebodies. Despite these differences, both groups of deposits have the same alteration assemblages, mineral paragenesis, element concentrations, and ore-forming ages.The mainly Jiaojia-type Luoshan gold deposit and the mainly Linglong-type Fushan gold deposit are characterized by H-O-S-Pb isotope data that indicate the ore-forming fluids have a dominantly metamorphic source. The fluids were derived during the Yanshanian orogenic event, and were most likely associated with dehydration and decarbonization processes near the top of the subducting paleo-Pacific plate. The Linglong-type ores have relatively lighter calculated δ¹⁸O compositions (−3.9 to −2.3‰) than the Jiaojia-type ores (0.3–8.0‰), possibly because of a greater degree of mixing with meteoric water. Petrographic, cathodoluminescence, microthermometric, and laser Raman spectroscopic analyses of fluid-inclusion assemblages in quartz from the two types of ores indicate fluids were similar, in both cases characterized by medium–high homogenization temperatures (211–393 °C), significant CO₂ (∼15% mol), minor CH₄ (⩽18% in the carbonic phase), and low salinity (⩽11.2 wt% NaCl eq.). The Linglong-type ores, however, have a wider range of CO₂ and CH₄ concentration and salinity than the Jiaojia-type ores. Fluid immiscibility, occurred in main ore stage of both ore types, with the trapping conditions of 77–185 MPa and 284–328 °C, although the unmixing is more intense and widespread in the Linglong-type ores. Both fluid-wallrock interaction and fluid immiscibility are important gold-deposition processes in the two types, but immiscibility is more important in the Linglong-type ores and that has led to the typical higher gold grade.In general, there is little geochemical differences between the ore-forming fluids for Jiaojia- and Linglong-type gold deposits. Both Jiaojia- and Linglong-type ores can exist in a single deposit and form in the same metallogenic event. The Linglong-type ores developed as more massive veins, because of their location in zones of more extensive extension and they lack significant post-ore cataclastic deformation.     

Exploring for heavy minerals on Cape York Peninsula,Queensland, Australia

This paper describes the results of a preliminary study of the heavy mineral (HM) potential of the northwest coast of Cape York Peninsula in far north Queensland that was funded by the Queensland Government's Future Resources Program Industry Priorities Initiative. The study found that the northwest coast may have the potential to host world-class HM deposits. All the essential ingredients in a HM mineral system are present: fertile source rocks, effective transport mechanisms and abundant potential trap sites, particularly along the well-preserved Pleistocene coast.

The source rocks are Proterozoic metamorphic and Paleozoic granitic rocks of the Coen Inlier and Mesozoic sedimentary rocks of the Laura and Carpentaria basins, all of which crop out along the spine of the Peninsula. These rocks were exposed in the early Cenozoic and were vigorously eroded by seasonally active rivers throughout the Quaternary. Most of these rivers are currently carrying HM, and the zircon content in river sediments in the region is comparatively high. It is speculated that in the late Pleistocene HM delivered by rivers to the northwest coast were transported predominantly in a southwesterly direction, and trapped in the swash zone of prograding beaches. It is further speculated that at this time the coastline was deeply embayed with cliffs and headlands formed in bauxite, and that structural trap sites formed on the northeastern side of prominent headlands.

Pleistocene coastal sediments were partially reworked by Holocene coastal processes, and HM liberated by these processes may have been captured by prograding Holocene beach ridges. These Holocene beach ridges are not as extensive as the Pleistocene beach ridges but are more prominent, partly because they are less well vegetated. The Holocene coastline was probably more regular than the Pleistocene coastline, with fewer headlands to create structural traps. The modern coastline is relatively starved of river sediment because the Holocene and Pleistocene coastal sediments act as barriers to river flow.

It is recommended that ongoing exploration for HM in the region should focus on potential trap sites on the Pleistocene coast and that two sites, Vrilya Point and Jackson River, where structural traps may have been formed by coastal promontories, should be priority targets. It is also noted that if the exploration of Cape York Peninsula for HM deposits is to be effective, further research needs to be carried out into the geomorphological evolution of the west coast and, in particular, the role of cyclones in forming HM deposits in tropical climates.     

南极半岛屈韦维尔岛白垩纪中期火山岩浆作用及其构造指示:锆石U-Pb年代学和Hf同位素制约

南极半岛长期以来位于冈瓦纳古陆的西缘,是冈瓦纳古陆最后裂解的发生地。南极半岛内出露有大量的中新生代火成岩,关于其成岩期次、源区性质以及产出的动力学背景等尚存争议,从而影响到对南极半岛构造演化的认识。本文报道了南极半岛中部构造域屈韦维尔岛地区出露的安山质火山岩、闪长玢岩脉及其中闪长岩捕掳体的LA-MC-ICP-MS锆石UPb年代学和Hf同位素分析数据。其中含角砾安山质熔岩、安山质火山角砾岩、中粒闪长岩捕虏体和闪长玢岩脉4件样品的锆石U-Pb测年结果分别为103.3±1.7Ma、101.9±1.8Ma、92.0±1.2Ma和85.7±07Ma,表明该岛在白垩纪中期存在三幕火山岩浆作用事件:第一幕约为102Ma发生的强烈火山喷发;第二幕约为92Ma的闪长岩侵入作用;第三幕约为86Ma的闪长玢岩体侵入作用。锆石的Hf同位素原位分析结果表明,主要测点的εHf(t)值在+2.5~+7.9之间,平均值为+4.4,其一阶段Hf模式年龄为505~678Ma,表明白垩纪中期出露的火成岩可能由新元古代-寒武纪的亏损地幔物质部分熔融所形成。结合前人研究成果,得出本岛出露的火成岩形成于冈瓦纳古陆裂解过程所伴生的俯冲岛弧环境中,是构成南极半岛中部岩浆弧构造域的主体岩性之一。     

High resolution WRF climatic simulations for the Iberian Peninsula: Model validation

A high resolution atmospheric modelling study was done for a 20-year recent historical period. The dynamic downscaling approach adopted used the Max Planck Institute Earth System Model (MPI-ESM) to drive the WRF running in climate mode. Three online nested domains were used covering part of the North Atlantic and Europe, with a resolution 81 km, and reaching 9 km in the innermost domain which covers the Iberian Peninsula.This paper presents the validation of the WRF configuration, which is based on historic simulations between 1986 and 2005 and observational datasets of near surface temperature and precipitation for the same period. The validation was done in terms of comparison of probability distributions between model results and observations, as daily climatologies, spatially averaged inside subdomains obtained with cluster analysis of the observations, for each of the four seasons. In addition, Taylor diagrams are presented for each of the seasons and subdomains. This validation approach was repeated with the results of a new WRF simulation with the same parameterisations but forced by the ERA-Interim reanalysis. The capacity of the MPI-ESM driven WRF configuration to compare with observations and in a manner similar to the ERA-Interim driven WRF, ensures the capacity of the configuration for climate and climate change studies.Considering the difficulty to simulate extremes in long term simulations, the results showed a comfortable comparison of both models (forced by climate model and reanalysis results) with observations. This provides us confidence on the continuity of using the MPI-ESM driven WRF configuration for climate studies.     

Robust inferences on climate change patterns of precipitation extremes in the Iberian Peninsula

This work presents a methodology to make statistical significant and robust inferences on climate change from an ensemble of model simulations. This methodology is used to assess climate change projections of the Iberian daily-total precipitation for a near-future (2021–2050) and a distant-future (2069–2098) climates, relatively to a reference past climate (1961–1990).Climate changes of precipitation spatial patterns are estimated for annual and seasonal values of: (i) total amount of precipitation (PRCTOT), (ii) maximum number of consecutive dry days (CDD), (iii) maximum of total amount of 5-consecutive wet days (Rx5day), and (iv) percentage of total precipitation occurred in days with precipitation above the 95th percentile of the reference climate (R95T). Daily-total data were obtained from the multi-model ensemble of fifteen Regional Climate Model simulations provided by the European project ENSEMBLES. These regional models were driven by boundary conditions imposed by Global Climate Models that ran under the 20C3M conditions from 1961 to 2000, and under the A1B scenario, from 2001 to 2100, defined by the Special Report on Emission Scenarios of the Intergovernmental Panel on Climate Change.Non-parametric statistical methods are used for significant climate change detection: linear trends for the entire period (1961–2098) estimated by the Theil-Sen method with a statistical significance given by the Mann-Kendall test, and climate-median differences between the two future climates and the past climate with a statistical significance given by the Mann-Whitney test. Significant inferences of climate change spatial patterns are made after these non-parametric statistics of the multi-model ensemble median, while the associated uncertainties are quantified by the spread of these statistics across the multi-model ensemble. Significant and robust climate change inferences of the spatial patterns are then obtained by building the climate change patterns using only the grid points where a significant climate change is found with a predefined low uncertainty.Results highlight the importance of taking into account the spread across an ensemble of climate simulations when making inferences on climate change from the ensemble-mean or ensemble-median. This is specially true for climate projections of extreme indices such CDD and R95T. For PRCTOT, a decrease in annual precipitation over the entire peninsula is projected, specially in the north and northwest where it can decrease down to 400 mm by the middle of the 21st century. This decrease is expected to occur throughout the year except in winter. Annual CDD is projected to increase till the middle of the 21st century overall the peninsula, reaching more than three weeks in the southwest. This increase is projected to occur in summer and spring. For Rx5day, a decrease is projected to occur during spring and autumn in the major part of the peninsula, and during summer in northern Iberia. Finally, R95T is projected to decrease around 20% in northern Iberia in summer, and around 15% in the south-southwest in autumn.     

Recent trends of extreme precipitation indices in the Iberian Peninsula using observations and WRF model results

Spatial and temporal distributions of the trends of extreme precipitation indices were analysed between 1986 and 2005, over the Iberian Peninsula (IP). The knowledge of the patterns of extreme precipitation is important for impacts assessment, development of adaptation and mitigation strategies. As such, there is a growing need for a more detailed knowledge of precipitation climate change.This analysis was performed for Portuguese and Spanish observational datasets and results performed by the Weather Research and Forecast (WRF) model forced by the ERA-Interim reanalysis. Extreme precipitation indices recommended by the Expert Team for Climate Change Detection Monitoring and Indices were computed, by year and season. Then, annual and seasonal trends of the indices were estimated by Theil-Sen method and their significance was tested by the Mann-Kendal test. Additionally, a second simulation forced by the Max Planck Institute Earth System Model (MPI-ESM), was considered. This second modelling configuration was created in order to assess its performance when simulating extremes of precipitation.The annual trends estimated for the 1986–2005, from the observational datasets and from the ERA-driven simulation reveal: 1) negative statistically significant trends of the CWD index in the Galicia and in the centre of the IP; 2) positive statistically significant trends of the CDD index over the south of the IP and negative statistically significant trends in Galicia, north and centre of Portugal; 3) positive statistically significant trends of the R75p index in some regions of the north of the IP; 4) positive statistically significant trends in the R95pTOT index in the Central Mountains Chain, Leon Mountains and in the north of Portugal.Seasonally, negative statistically significant trends of the CWD index were found in Galicia, in winter and in the south of the IP, in summer. Positive statistically significant trends of the CWD index were identified in the Leon Mountains, in spring, and in Galicia, in autumn. For the CDD index, negative statistically significant trends were seen in Valencia, in the spring, and, in Galicia and Portugal (north and centre), in summer. Positive statistically significant trends of the CDD index were found: in the east of the IP, in the winter; in the Cantabrian Mountain, in the spring; and, in the south of the IP, in summer. Regarding to the R75p index, negative statistically significant trends were found in Galicia, in winter and positive statistically significant trends in the north of Portugal, in spring and in the Central Mountains Chain and north of Portugal, in autumn. For the R95pTOT index, negative statistically significant trends were found over the Sierra Cuenca and Sierra Cazorla, in winter and positive statistically significant trends were found over the Sierra Cebollera, in winter and in Castile-la Mancha region, in spring.The results of the annual and seasonal trends of the extreme precipitation indices performed for observational datasets and the simulation forced by ERA-Interim, are similar. The results obtained for the simulation forced by MPI-ESM are not satisfactory, and can be a source of criticism for the use of simulation forced by MPI-ESM in this type of climate change studies. Even for the relatively short period used, the WRF model, when properly forced is a useful tool due to the similar results of Portuguese and Spanish observational datasets and the simulation forced by ERA-Interim.     

雷州半岛土壤渗透性及其与地下水补给关系

对雷州半岛土壤渗透性进行了分析,并结合地形地貌、降雨入渗补给情况,识别地下水潜在补给区。雷州半岛土壤渗透性空间差异较大,饱和渗透系数变化范围为 0.04~8.83 m/d。总体而言,半岛南部、遂溪西北部渗透性较好,中部较差。土壤渗透系数受到土地利用类型、土壤粒径、土壤有机质等的影响。随着土壤中值粒径和有机质含量的增加,土壤渗透系数增加。不同土地利用类型,其土壤平均渗透性优劣表现为：荒地＞桉树林＞甘蔗＞菜地＞菠萝＞其他林地＞香蕉＞苗圃＞坡稻＞水稻田。降雨入渗补给系数南北高、中间低,随着土壤渗透系数增加而提高。半岛南部石茆岭和石板岭一带,地势高,坡度较缓,同时土壤渗透性和降雨入渗补给系数相对较高,为雷州半岛地下水潜在补给区。     

东南亚中南半岛地区黑色金属矿床谱系

东南亚中南半岛地区位于特提斯-喜马拉雅成矿带与环太平洋成矿带的交汇部位,具有丰富的富铁、优质锰、铬铁矿、钛铁矿等黑色金属资源。在系统收集和整理该区矿产地数据的基础上,建立了中南半岛5国（越南、老挝、柬埔寨、缅甸和泰国）的矿产地数据库,初步厘定了黑色金属矿床谱系,并对其找矿潜力进行了简要分析。     

Dune field development,interactions and boundary conditions for crescentic and stellate megadunes of the Al Liwa Basin,the Empty Quarter

Within the greater Ar Rub' al Khali (Empty Quarter) sand sea lies an internal depocentre, the Al Liwa Basin, which comprises a variety of mega‐scale dune types. Crescentic dunes dominant the north of the basin while megadunes of stellate or star form are a major landform of the south‐eastern reaches. Their development into dune fields is determined by the style and rate of dune–dune interactions, the boundary conditions imposed by a multi‐modal wind regime, fluctuating groundwater levels, and sediment availability under an assortment of climatic conditions throughout the Quaternary. As a result, dune field patterns are a collective response to these perturbations in space, time and environment. The R‐statistic is a collective measure of these responses, and is a metric capable of identifying the degree of pattern maturity or self‐organization of the aeolian system, and the pathways from which patterns evolve. The spatial signature of the southerly located star dunes is characterized by two definitive patterns of organization: the first, one of complete spatial randomness, the second, a low degree of spatial uniformity. In isolation, these results appear to be unrelated to those for crescentic dunes of the region in which a significantly higher degree of pattern dispersion is the norm. However, when spatial statistical measures are integrated with the theoretical understanding of dune–dune interactions and the involvement of environmental agents, the complex morphodynamic pathways and linkages between regional dune fields is better understood. In this case, both constructive (e.g. merging, lateral linking) and regenerative activity (e.g. calving) have played important roles in the development of dune size, and associated adjustments in spacing, and dune numbers, and subsequently dune field patterns. Synergetic patterns are emblematic of this vast dunescape, whereby transitional geographic, morphologic, dimensional and environmental modifications exist between the mega‐crescentic and mega‐stellate dunes of the Empty Quarter. Copyright © 2012 John Wiley & Sons, Ltd.