Environmental aspects of selected trace metals in soils and waters surrounding Singaran Nala, Raniganj Coalfield

The Raniganj Coalfield is the oldest coalfield in India that has been continuously and extensively mined since the late eighteenth century. The present study reports a geochemical investigation and environmental quality assessment using soil and water in the area surrounding a stream, locally known as Singaran Nala （Nala means storm water drains in Bengali）, in the Raniganj Coalfield. Soil （top soil, mud, silty clay and laterite） and rock samples （sandstone and shale） were collected from the study area and were analyzed for trace metals （Cr, Cu, Fe, Mn, Ni and Zn）. Surface waters from the stream and the Damodar River as well as ground waters from hand pumps and underground mine pits were collected. Water samples were analyzed for major ions （Na^＋, Ca^2＋, Mg^2＋, Cl^-, HNO3^- and SO4^2-） and trace metals （Cu, Fe, Mn, Ni, and Zn）. Trace metal concentrations in soil samples are found higher than the average world soil composition. Nevertheless, trace metal （Cr, Cu, Ni and Zn） concentrations in soils exceed or reach the maximum allowable concentrations （MAC） proposed by the European Commission for agricultural soils. In particular, Ni concentrations exceed the typical value for cultivated soils. Chromium, Cu and Ni concentrations in laterite and Cr concentration in topsoil exceed the ecotoxicological limit.     

北京地区湿地高等植物区系分析

根据工作需要,在北京4个水系的主要河流的平原地段和山区的上、中游地段,选取不同生境的典型样地,以及城区的人工湖泊共设立了35个采集点,采用样方法和样带法相结合,共调查样方355个,采集样本4 152个。在该调查资料的基础上,运用区系学原理对北京地区湿地高等植物区系的种类组成、地理成分(科、属、种3个层次)等进行了系统的分析。结果表明,北京地区湿地高等植物共有108科311属552种(含山区湿地),占北京植物总数的近1/3。其中苔藓植物(B ryohyto)有9科15属18种;蕨类植物(Pteridophgta)5科5属8种;裸子植物(Gymnosperm ae)3科5属6种;被子植物(Angiosperm ae)91科286属520种。种子植物中含20种以上的有5科,共210种;含5种以上的属有14个属,共114种。北京地区湿地植物的分布(即地理成分)较复杂。北京湿地种子植物属的分布区类型有15个类型,9个变型,温带地区类型占主导,温带成分较丰富(属数、种类、比例均占首位)。本区植物区系的主要特征为:①草本植物发达;②温带成分占优势地位;③区系起源古老;④特有属、种匮乏;⑤分布区类型具多样性。     

Soil quality changes in land degradation as indicated by soil chemical, biochemical and microbiological properties in a karst area of southwest Guizhou, China

Not only the nutritional status and biological activity but also the soil ecological functioning or soil health has been impacted profoundly by land degradation in the karst area of southwest China where the karst ecosystems are generally considered as extremely vulnerable to land degradation under intensified land-use changes. The objectives of this study are to elucidate the changes in overall soil quality by a holistic approach of soil nutritional, biological activity, and soil health indicators in the karst area as impacted by intense cultivation and vegetation degradation. Topsoil samples were collected on selected eco-tesserae in a sequence of land degradation in a karst area of southwest Guizhou in 2004. The soil nutrient pools of organic carbon (C_org), extractable extracellular carbon (C_ext), total soil nitrogen (N_t), alkali-hydrolyzable nitrogen (N_ah), total phosphorus (P_t), available phosphorus (P_a) were analyzed by wet soil chemistry. The soil biological properties were studied by means of measurements of microbial biomass carbon (both by fumigation–extraction, FE-C_mic, and by calculation from substrate-incubation respiration, SIR-C_mic) of respiration [respiration without addition of substrates, basal respiration (BR), and potential respiration (PR) with substrate-incubation] and of soil enzyme activities (invertase, urease, and alkaline phosphatase). Soil health status was assessed by simple indices of C_mic/C_org and BR/C_mic in conjunction with bacterial community structures determined by polymerase chain reaction and denaturing gradient gel electrophoresis. While the nutritional pool parameters, such as C_org and C_ext, described basically the changes in soil life-supporting capacity with cultivation interference and vegetation declined, those parameters of biological activity such as FE-C_mic, SIR, and SIR-C_mic as well as bacterial community structures measured by molecular method evidenced well the changes in soil functioning for ecosystem health with the land degradation.     

New Generation of Probabilistic Seismic Hazard Assessment for the Area Cologne/Aachen Considering the Uncertainties of the Input Data

A new earthquake catalogue for central, northern and northwestern Europe with unified M_w magnitudes, in part derived from chi-square maximum likelihood regressions, forms the basis for seismic hazard calculations for the Lower Rhine Embayment. Uncertainties in the various input parameters are introduced, a detailed seismic zonation is performed and a recently developed technique for maximum expected magnitude estimation is adopted and quantified. Applying the logic tree algorithm, resulting hazard values with error estimates are obtained as fractile curves (median, 16% and 84% fractiles and mean) plotted for pga (peak ground acceleration; median values for Cologne 0.7 and 1.2 m/s² for probabilities of exceedence of 10% and 2%, respectively, in 50 years), 0.4 s (0.8 and 1.5 m/s²) and 1.0 s (0.3 and 0.5 m/s²) pseudoacclerations, and intensity (I₀ = 6.5 and 7.2). For the ground motion parameters, rock foundation is assumed. For the area near Cologne and Aachen, maps show the median and 84% fractile hazard for 2% probability of exceedence in 50 years based on pga (maximum median value about 1.5 m/s²), and 0.4 s (>2 m/s²) and 1.0 s (about 0.8 m/s²) pseudoaccelerations, all for rock. The pga 84% fractile map also has a maximum value above 2 m/s² and shows similarities with the median map for 0.4 s. In all maps, the maximum values fall within the area 6.2–6.3° E and 50.8–50.9° N, i.e., east of Aachen.     

Karst groundwater protection in the Kupa River catchment area and sustainable development

One of the most significant water resources in the Republic of Croatia is the catchment area of the Kupa River, located in the region bordering the Republic of Slovenia. About 88% of the total amount of water in this catchment originates in Croatia and just 12% from Slovenia; therefore, the largest part of the catchment area (about 1000 km²) is on the Croatian side of the border. It is a typical karst area of the Dinarides with aquifers characterized by a relatively rapid water exchange, high groundwater flow velocities and aquifers open to human impact from the surface. Consequently, the aquifers are highly vulnerable and at risk. Due to the availability of large quantities of high-quality spring water (about 6 m³/s), the entire area has a strategic importance within the context of any future development strategy pertaining to the western part of Croatia. The catchment area on the Croatian side was investigated using a wide range of research methods that included a classical hydrogeological approach, the detailed hydrologic calculation of water balance to the hydrogeochemical analyses and modelling. The objective was to determine protection zones and protection measures for the whole area. The difficulties are increased due to the fact that the karst catchment area is crossed by major traffic corridors, oil pipelines and a railway and that many settlements and a highly developed wood industry are present. The combination of protecting water resources with adequate prevention measures and necessary remedial activities that should satisfy the very strict requirements necessary for the protection of the karst aquifers while still allowing for present and future human activities is difficult – but not impossible – to achieve. One good example is the present highway with a closed dewatering system and waste water treatment before the water passes into the karst underground system.     

Regional disparity in the changes of agricultura land use intensity in China during 1980-2002

Based on the cost-benefit data （1980-2002） of farm products and China Agriculture Yearbooks, this paper studies the regional disparity in the changes of the agricultural land use in China during the period 1980-2002 from three aspects such as the degree of intensity, the sown area and the abandoned farmland. The results show that： （1） The degree of intensity of land use in the westena region during 1980-2000 has a strong uptrend, but in the eastern and central regions the degree of intensity descends obviously and has shown a continuous downtrend since 1997. （2） The total sown area shrinks notably in the eastern region, while it enlarges constantly in the western region. （3） The sown area in the eastern, central and western regions has gone through a similar cyclic process： down （1980-1985）-up （1985-1991）-down （1991-1994）-up （1994-1999）-down （1999-2002）. However, there are obvious differences in amplitude variation and tendency among them. The sown area has shrunk in the eastern region and expanded in the central and western regions especially before 1999. （4） The most cases of abandoned farmland are reported in the central region, the second in the eastern region and the least in the western region. The abandonment phenomena chiefly occurred during 1992-1995 in the eastern region, and during 1998-2002 in the central region.     

紫色丘陵区不同侵蚀沉积地段土壤结构特征

以中国科学院盐亭紫色土农业生态试验站小流域为例，研究不同土壤侵蚀沉积地段（斜坡和沟谷不同部位）的土壤结构特征，以了解侵蚀沉积对土壤结构的影响。结果表明，在植被覆盖较好的坡体顶部，土壤侵蚀较弱，团聚度达到30．1％，MWD变化为3．4mm，土壤结构良好；沟谷底部由于沉积而有较多细土物质并具有适宜的水分条件，有利于土壤团聚体的形成，结构状况亦较好，团聚度达到50．3％，结构保持率为35．4％；而坡腰侵蚀较严重，团聚度仅为13．6％，结构保持率为14．1％，土壤结构状况较差。     

Factors influencing the presence or absence of tributary-junction fans in the Iberian Range, Spain

This paper analyses the factors which influence the presence or absence of tributary-junction fans in the Iberian Range, northern Spain. Two valleys were selected, both characterised by wide variations in lithology, altitude, land use and plant cover. Two groups of factors were studied: those related to the internal characteristics of the drainage basins, which particularly control sediment generation; and those related to the characteristics of the depositional area which control accommodation space and main river power. Among the internal factors, the development of alluvial fans was related to: (i) the capacity of the basin to yield large volumes of sediment, (ii) the occurrence of intense human pressure until recent times, a good indicator of sediment yield, and (iii) the capacity of the basin to quickly increase discharge during rainstorms (discharge density and torrentiality). It is suggested that the areas that were intensively cultivated in the past, and have therefore been affected by intense erosion, have played a decisive role on the development of alluvial fans. This would imply that many of these alluvial fans have a relatively recent origin, perhaps related to the beginning of a widespread deforestation. The basins without alluvial fans are characterised by relatively steep hillslope gradients (that is, slopes that never were subjected to historical cultivation), low drainage densities and dense forest and shrub cover, mostly coinciding with high altitude basins composed of quartzite and shale bedrocks. Regarding the external factors, the shape, size and longitudinal gradient of the main river to which the fans are tributary are the most relevant conditioning factors determining the development of alluvial fans.     

Permeability of Hydraulic Fills and Barricade Bricks

Permeability is one of the most important parameters in the design of hydraulic backfilling of mine stopes. A simple and reproducible method was developed for preparing reconstituted hydraulic fill sample in the laboratory, that is representative of the hydraulic fill in the mine stope, replicating the slurry sedimentation process taking place in the mine. Constant head and falling head permeability tests were carried out on the samples, giving consistent results. A brick permeameter was developed to study the flow characteristics of the porous barricade bricks under one-dimensional flow, simulating the flow conditions in the mine. Three different methods were used to determine the permeability of the brick and the results showed very good agreement. This is the first rational attempt to measure the permeability of the porous barricade bricks that are used to close the horizontal access drives in the mines, thus retaining the hydraulic fill. The measurements show that the permeability of the barricade brick is about two to three orders of magnitude greater than that of the hydraulic fill.