吉林省香炉碗子金矿床矿化特征及成因机理探讨

香炉碗子金矿床产于中生代形成的隐爆角砾岩体中，隐爆岩体又受脆韧性剪切带控制，金矿化与铁铁绢英岩化关系密切，本文论述了矿床的矿体，矿化及矿石等特征，并探讨了矿床成因和成矿机理。     

Mobility of rare-earth elements and copper during shear-zone-related retrograde metamorphism

In Mid Proterozoic crystalline rocks of the Mount Isa Inlier, around Cloncurry, Australia, 2000 km² of alteration and brecciation are the product of high-temperature (> 450 °C) concentrated saline solution activity. During retrogression, this fluid was locally responsible for mobility of V, Y, Nb and light rare-earth elements (15 × enrichment). Copper and S were leached during alteration and this may have been a significant source of components in nearby Cu-Au deposits. Similar rare-earth-element behaviour has been observed in the hematite breccias which host Cu-sulfides at the giant Olympic Dam Cu-Au deposit.     

Geochemistry of shallow sediments in Guaymas Basin, gulf of California: hydrothermal gas and oil migration and effects of mineralogy

Offset of prograde hydrothermal alterations by retrograde reactions is evident in sediments from a piston core (PC6, 8 m long) from the Guaymas Basin, Gulf of California. Geochemical and mineralogical analyses of sediments and pore fluids show superimposed geochemical signals that indicate currently active reactions are modifying previously formed secondary solids. Hydrothermal barite was formed in a previously active flow channel between 150 and 250 cm depth. Hydrothermal gypsum is presently dissolving at depths > 780 cm, below which hydrothermal fluid flow is channeled by a secondary dolomite layer. Thermal stress of organic matter generates hydrothermal gas and petroleum having wide ranges of compositions and maturities. A significant amount of hydrothermally generated oil has been transported laterally through a porous debris flow (approx. 240 cm subbottom), overwhelming the indigenous bituminous matter. Water soluble petroleum constituents have disseminated throughout the cored sediments. From 400 to 700 cm depth the immature organic matter continues to experience thermally-enhanced diagenesis, and an even higher thermal stress has occurred at the bottom of the core. Enhanced bacterial degradation of organic matter has led to depletion of pore water sulfate and enrichment of ammonium (NH₄⁺) in both pore fluid and sediment, resulting in formation of NH₄⁺ bearing secondary clay minerals at depths below 780 cm.     

汉寿高仑山石英岩矿床地质特征及开发前景

高仑山沉积-变质石英岩矿床产于岩坝桥岩体北东外蚀变带,是省内新型硅石矿床类型。它系灯影组硅质岩受岩体热液蚀变形成。矿石矿物成分98—99％为石英。大型矿床规模。原矿经破碎水洗法选矿后,精矿含SiO_2 99.16％,质量达优质型砂。目前产品暂应用于铸造行业,经数家精铸厂试验,能铸出合格钢铸件。该矿床开采条件优越,潜在经济价值巨大,开发利用前景广阔。     

褐帘石及其次生物的研究

褐帘石发生蚀变后,其次生物的化学成分变化很大,除SiO_2外,A1、Ce~(4+)增高一倍以上,而Fe、Ti、Mg、Ca及多种稀土成分几乎全部消失。另外,其次生物在物相上也发生了转化,生成高岭石、埃洛石、方饰石和铁质等集合体。在湿热多雨、植被茂密地段,岩体中褐帘石的大量存在并发生次生成矿作用,是形成湖南姑婆山风化壳型稀土矿床的有利地带。     

西藏甲玛斑岩矿床系统地质、蚀变、矿化的三维地质模型

甲玛矿床位于西藏冈底斯成矿带东段,是公益性与商业性勘查结合取得的重要成果。目前已累计探明和控制铜资源量超过700万吨,共伴生钼、铅锌、金、银资源量均达到大型以上规模。本文在充分收集、整理甲玛矿床最新勘查资料、研究成果的基础上,运用MICROMINE软件三维建模及可视化技术,遵循点→线→面→体的构建原则,进行人机交互分析,构建了甲玛矿床地质、蚀变、矿体三维实体模型,并根据不同矿体品位分布变化的实际情况,对矿体模块模型进行克里格法或距离反比加权法品位插值,构建各种元素的矿化模型。并综合国内外对斑岩、矽卡岩矿床的研究新趋向对模型进行了地质解译,认为甲玛斑岩矿床是由斑岩钼铜矿体、矽卡岩铜多金属矿体、角岩铜钼矿体以及破碎带中独立金矿体构成的"四位一体"典型斑岩成矿系统产物,其中矽卡岩主要有接触带近端矽卡岩、层间构造中的远端矽卡岩以及受控于推滑覆构造产出的矽卡岩三种产出型式,由岩浆热液沿层间构造和推滑覆构造扩散交代大理岩和角岩形成;研究认为甲玛斑岩矿床具有典型的斑岩矿床蚀变系统,但蚀变分带有所差异,钾化带与青磐岩化带是在相对碱性条件下形成,而绢英岩化带与泥化带趋向于在相对酸性条件下形成。此外,大规模的角岩、矽卡岩对寻找深部斑岩矿体具有指示意义,甲玛斑岩矿体、角岩矿体仍具巨大的找矿潜力。因此,本研究构建的甲玛三维模型直观地展示了矿区地层、岩体、构造分布情况、赋矿层位、矿化品位分布规律以及蚀变分带特征,为甲玛矿床的成因、成矿规律总结、找矿勘查、矿山生成开发等综合研究提供重要的科学依据。     

高光谱蚀变矿物提取在地质找矿中的应用——以吉林某斑岩型钼矿为例

国内外已广泛使用高光谱方法提取和识别岩石和矿物的技术。本文利用这个技术,在地面光谱测试、数据处理和光谱特征分析的基础上,提取和识别出斑岩钼矿区的蚀变矿物,通过分析与钼矿化蚀变的相关性,从12种主要蚀变矿物中优选出5种在矿区具有代表性的蚀变矿物:绢云母、蒙脱石、伊利石化绢云母、高岭石(结晶差)和铁镁绿泥石。结合其空间分布和分带特征,分析了与钼矿化的关系,进而划分出内、中和外三个蚀变带,预测了矿区的找矿方向,并提供了一种新的找矿思路。     

Hyperspectral interpretation of selected drill cores from orogenic gold deposits in central Victoria,Australia

HyLogger hyperspectral data obtained from seven orogenic gold deposits in central Victoria, including Bendigo, Ballarat, Maldon, Fosterville, Costerfield, Castlemaine and Wildwood, are presented. The data demonstrate that fresh diamond drill core displays substantial mineralogical variation that can be attributed to the effects of cryptic hydrothermal alteration that might not otherwise be recognised. The most significant hyperspectral response lies in the white mica compositions, which vary in a systematic manner between high-Al muscovitic zones (Al–OH absorption around 2208 nm) that define a phyllic alteration halo around mineralised structures, and low-Al phengitic–chlorite zones (Al–OH absorption >2014 nm) inferred to represent either more distal alteration or possibly regional metamorphic background. An extensive ferroan dolomite alteration halo overlaps the phyllic and sulfidic alteration zones and extends beyond the sampled core in most instances. This ferroan dolomite halo has previously been defined petrographically, geochemically and using carbonate staining techniques, and is further characterised using thermal infrared hyperspectral data in drill core from the Ballarat goldfield. The mineralogical trends identified by the hyperspectral data are best developed in diamond drill core from the Costerfield, Fosterville and Ballarat goldfields, and are less pronounced at the other deposits. At Bendigo and Castlemaine the reasons for this are not immediately clear, but may be related to the close timing of gold mineralisation relative to peak metamorphism. The Maldon area lies within the contact aureole of the Harcourt Batholith and so has been thermally overprinted leading to the recrystallisation of earlier hydrothermal assemblages. The Wildwood deposit is similar to the Magdala deposit at Stawell and differs from the other goldfields in its geological setting, host rock lithologies and style of hydrothermal alteration, with the development of Fe-rich chlorite closely associated with gold mineralisation. The results demonstrate how hyperspectral data can be used to define large hydrothermal alteration footprints associated with orogenic gold mineralisation in central Victoria that are of direct benefit to mineral explorers, as well as independently characterising lithological variations in drill core.     

蚀变矿物近红外光谱特征对地质找矿的指示意义——以甘肃岗岔金矿为例

甘肃岗岔金矿位于秦岭造山带之碌曲-成县逆冲推覆构造带的西段北侧,是典型的构造蚀变岩型金矿床,目前储量可达中型。在矿区地质填图的基础上,采用BJKF-1型近红外矿物分析仪对矿区7号勘探线ZK07-4钻孔、8号勘探线ZK08-6钻孔及27号勘探线的ZK27-1、ZK27-3、ZK27-4钻孔岩心进行蚀变特征研究,识别出的主要蚀变矿物为伊利石、云母类、地开石、高岭石等。蚀变矿物分布及含量变化特点表明,与矿化有关的蚀变主要是绢英岩化,其中已探明矿体多位于采用近红外分析技术圈出的绢英岩化带内。此外,伊利石反射光谱特征参数计算结果表明,伊利石结晶度和Al-OH特征吸收峰形态呈现有规律的变化,即含矿段和近矿段伊利石结晶度大(SWIR-IC值5.5~5.7),Al-OH吸收峰尖锐;远矿段和无矿段伊利石结晶度小(SWIR-IC值1.3~1.5),Al-OH吸收峰平缓,显示含矿段伊利石形成温度较高。上述结果表明,矿区内绢英岩化蚀变及伊利石结晶度、Al-OH峰形是有利找矿标志,对找矿具有实际指导意义。