福建政和东际金-银矿床的热液蚀变特征及其勘探指示意义

福建东际金-银矿床产于中生代东坑火山岩盆地西缘的流纹质凝灰岩中,矿区及周边火山-沉积岩系遭受了广泛且强度不等的热液蚀变。本文工作采用红外反射光谱技术在东际矿区三个勘探剖面上对钻孔岩心进行系统性高密度采样分析,结果显示蚀变矿物组合及分带的大框架样式主要受原岩成分控制,具体表现为绢云母化趋向于发育于流纹质火山岩中,而绿泥石化则富集在安山质和英安质火山岩中。在更小的矿区局部空间范围内或单一岩性中,热液作用的物化条件作为次级控制因素决定着特定蚀变矿物的成分变化和蚀变类型的强度差异。从层状硅酸盐组合考虑,东际矿区热液蚀变以绢云母化和绿泥石化为最主要类型,而缺失发育良好的蒙脱石带,金-银矿化赋存在以伊利石为主的绢云母化带中,表明成矿环境属于低硫到中硫之间的浅成热液系统。含矿火山岩的热液蚀变组合和强度变化,以及金-银矿化的似层状特点,均指示成矿时流体是沿着南园组凝灰岩层内侧向流动,而蚀变分带细节显示在凝灰岩层中存在着二至三条流体主通道,金-银矿化则赋存在主通道中。流体主通道的热液蚀变标志是富铝绢云母,其与主通道之外的相对贫铝绢云母在红外光谱特征上反差明显。因此,采用红外光谱技术圈定整体热液蚀变系统的空间构型、解译成矿环境的物化条件及变化、并确定绢云母的铝含量变化用以判断成矿流体主通道位置,可以有效地缩小勘探目标和提高找矿工作的预测性。     

Effects of Deep Fluids on Hydrocarbon Generation and Accumulation in Chinese Petroliferous Basins

Deep fluids in a petroliferous basin generally come from the deep crust or mantle beneath the basin basement, and they transport deep substances(gases and aqueous solutions) as well as heat to sedimentary strata through deep faults. These deep fluids not only lead to large-scale accumulations of CO_2, CH_4, H_2, He and other gases, but also significantly impact hydrocarbon generation and accumulation through organic-inorganic interactions. With the development of deep faults and magmatic-volcanic activities in different periods, most Chinese petroliferous basins have experienced strong impacts associated with deep fluid activity. In the Songliao, Bohai Bay, Northern Jiangsu, Sanshui, Yinggehai and Pearl Mouth Basins in China, a series of CO_2 reservoirs have been discovered. The CO_2 content is up to 99%, with δ~(13)C_(CO2) values ranging from-4.1‰ to-0.37‰ and ~3He/~4He ratios of up to 5.5 Ra. The abiogenic hydrocarbon gas reservoirs with commercial reserves, such as the Changde, Wanjinta, Zhaozhou, and Chaoyanggou reservoirs, are mainly distributed in the Xujiaweizi faulted depression of the Songliao Basin. The δ~(13)CCH4 values of the abiogenic alkane gases are generally -30‰ and exhibit an inverse carbon isotope sequence of δ~(13)C_(CH4)δ~(13)C_(C2H6)δ~(13)C_(C3H8)δ~(13)C_(C4H10). According to laboratory experiments, introducing external H_2 can improve the rate of hydrocarbon generation by up to 147% through the kerogen hydrogenation process. During the migration from deep to shallow depth, CO_2 can significantly alter reservoir rocks. In clastic reservoirs, feldspar is easily altered by CO_2-rich fluids, leading to the formation of dawsonite, a typical mineral in high CO_2 partial pressure environments, as well as the creation of secondary porosity. In carbonate reservoirs, CO_2-rich fluids predominately cause dissolution or precipitation of carbonate minerals. The minerals, e.g., calcite and dolomite, show some typical features, such as higher homogenization temperatures than the burial temperature, relatively high concentrations of Fe and Mn, positive Eu anomalies, depletion of 18 O and enrichment of radiogenic ~(87)Sr. Due to CO_2-rich fluids, the development of high-quality carbonate reservoirs is extended to deep strata. For example, the Well TS1 in the northern Tarim Basin revealed a high-quality Cambrian dolomite reservoir with a porosity of 9.1% at 8408 m, and the Well ZS1 C in the central Tarim Basin revealed a large petroleum reserve in a Cambrian dolomite reservoir at ~6900 m. During the upward migration from deep to shallow basin strata, large volumes of supercritical CO_2 may extract petroleum components from hydrocarbon source rocks or deep reservoirs and facilitate their migration to shallow reservoirs, where the petroleum accumulates with the CO_2. Many reservoirs containing both supercritical CO_2 and petroleum have been discovered in the Songliao, Bohaiwan, Northern Jiangsu, Pearl River Mouth and Yinggehai Basins. The components of the petroleum trapped with CO_2 are dominated by low molecular weight saturated hydrocarbons.     

西准噶尔包古图Ⅴ号岩体围岩蚀变的特征及ETM+蚀变信息的提取

以新疆西准噶尔包古图Ⅴ号岩体为例,系统论述了包古图Ⅴ号含矿岩体的围岩蚀变分带和蚀变期次。结合ETM+数据的特征,选择多种遥感图像预处理方法组合,建立了基于典型蚀变矿物的特征光谱拟合技术的多光谱遥感蚀变信息提取模型,即遥感数据的归一化处理(Calibration )+掩膜(Mask)+混合像元分解(Endmember Unmixing)+波谱拟合(Spectral Feature Fitting)+ SAM+分类(分割)的CES模型。据此模型对岩体进行信息提取,并与化探资料叠加验证了该方法的可行性,取得了较满意的效果。     

Deriving Optimal Exploration Target Zones on Mineral Prospectivity Maps

This paper describes a quantitative methodology for deriving optimal exploration target zones based on a probabilistic mineral prospectivity map. The methodology is demonstrated in the Rodalquilar mineral district in Spain. A subset of known occurrences of mineral deposits of the type sought was considered discovered and then used as training data, and a map of distances to faults/fractures and three band ratio images of hyperspectral data were used as layers of spatial evidence in weights-of-evidence (WofE) modeling of mineral prospectivity in the study area. A derived posterior probability map of mineral deposit occurrence showing non-violation of the conditional independence assumption and having the highest prediction rate was then put into an objective function in simulated annealing in order to derive a set of optimal exploration focal points. Each optimal exploration focal point represents a pixel or location within a circular neighborhood of pixels with high posterior probability of mineral deposit occurrence. Buffering of each optimal exploration focal point, based on proximity analysis, resulted in optimal exploration target zones. Many of these target zones coincided spatially with at least one occurrence of mineral deposit of the type sought in the subset of cross-validation (i.e., presumed undiscovered) mineral deposits of the type sought. The results of the study showed the usefulness of the proposed methodology for objective delineation of optimal exploration target zones based on a probabilistic mineral prospectivity map.     

Genesis of Tertiary Magnetite–Apatite Deposits,Southeast of Zanjan,Iran

Magnetite–apatite deposits in the Alborz volcano–plutonic belt, southeast Zanjan, in Iran, have blade, lenzoid, and vein forms, which extend in an E‐W direction. There are many magnetite–apatite veins and veinlets in this region, and some of them are economically important, such as Zaker, Morvarid, Sorkheh–Dizaj, and Aliabad. The sizes of the vein orebodies vary between 2 and 16 m in width, 10–100 m in length, and 5–40 m in depth. Microscopic examination of thin sections and polishes indicate that they are composed of magnetite and apatite, with minor amounts of goethite, hematite, actinolite, quartz, muscovite–illite, talc, dolomite, and calcite. The geochemistry and mineralogy of the granitic host rock reveals that it is calc‐alkaline and I‐type. Field observations, mineral paragenesis, the composition of the orebodies, and the composition of the fluid inclusions in the apatite minerals with low salinity (less than 20 wt.% NaCl equivalent) indicate that these magnetite veins were hydrothermally generated at about 200–430°C and are not related to silica–iron oxide immiscibility, as are the major Precambrian magnetite deposits in central Iran.     

内蒙古扎鲁特旗伊和布拉格多金属矿地球物理、地球化学特征及找矿预测

内蒙古自治区扎鲁特旗伊和布拉格多金属矿位于额济纳旗-大兴安岭成矿区之突泉-林西华力西燕山期铁（锡）铜、铅、锌、银、铌（钽）成矿带。区内共发现7条矿化蚀变带,土壤地球化学测量圈定了元素组合异常4个。矿化蚀变带受NE-SW向断裂构造控制,其中Ⅲ号矿化蚀变带、Ⅴ号矿化蚀变带位于该区近东西向和近南北向断裂带的交汇处。矿化蚀变主要产于下二叠统或上侏罗统,成矿作用与燕山中晚期岩浆侵入活动相关。矿化蚀变带与地球化学异常及低电阻率,高极化激电异常均相关性,其中Ⅲ号蚀变带深部已见多层银铅锌矿体。从地质、物化探资料分析并与有关同类型的矿床类比,区内多条矿化蚀变带均具有寻找中-大型银铅锌多金属矿潜力。     

朱诺斑岩型铜矿床外围遥感找矿预测

基于ETM+遥感数据源,利用ENVI遥感图像处理软件对云、雪被、第四系、水体、阴影等进行了掩膜;采用特征主成分分析技术对西藏自治区朱诺斑岩型铜矿床及其外围地区开展遥感羟基和铁染矿化蚀变信息提取,并进行了地质解译。据此圈定找矿远景区,为朱诺铜矿床外围地区开展找矿工作提供了先决条件。     

Characterizing hydrothermal alteration zones in Hamama area in the central Eastern Desert of Egypt by remotely sensed data

Abstract

Remote sensing techniques provide meaningful information to mineral exploration by identifying the hydrothermally altered minerals and the fracture/fault systems. In this article, Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) data were processed to detect the hydrothermal alteration zones in Hamama area in the central part of the Eastern Desert of Egypt. Band ratios and principal component analyses successfully revealed the extent and the geometry of the hydrothermal alteration zones that trend in an NE–SW direction. Matching pixel spectrum derived from Minimum Noise Fraction, Pixel Purity Index, and n-dimensional visualization with reference spectra allowed characterizing key hydrothermal alteration minerals, including chlorite, kaolinite-smectite, muscovite, and haematite, in a successive alteration pattern. Field investigations and X-Ray Diffraction analysis validated the results revealed by ASTER data. In addition, the present prospects of significant gold and massive sulphide mineralizations are consistent with the detected hydrothermal alteration zone.     

四川省尖尖石金矿成矿规律探讨

尖尖石金矿成因类型为与岩浆岩有关的混合热液充填交代型金矿床。区内侵入岩主要为晋宁期闪长岩、石英闪长岩、斜长花岗岩以及混合质花岗岩。区内主要控矿构造为近南北一北西向的逆断层,断层性质为压扭断层,总体走向近南北向。断裂构造为矿质运移和矿质充填提供了通道和赋存空间。     

青海省兴海县赛什塘铜矿的斑岩型矿化特征及其找矿前景

青海省兴海县赛什塘铜矿床中局部具斑岩型矿化的特征,该矿区中酸性侵入岩发育并具明显的多期次和多类型.该类铜矿化发生于中-酸性岩浆侵入活动末期的闪长玢岩、花岗闪长斑岩、斜长花岗斑岩、石英斑岩、爆破角砾岩中,围岩蚀变强烈且具分带性.加强对蚀变闪长玢岩、花岗闪长斑岩、斜长花岗斑岩、石英斑岩、爆破角砾岩发育地段的找矿工作,有望实现本区找矿新突破.