全文获取类型
收费全文 | 343篇 |
免费 | 46篇 |
国内免费 | 99篇 |
专业分类
大气科学 | 2篇 |
地球物理 | 50篇 |
地质学 | 363篇 |
海洋学 | 24篇 |
综合类 | 18篇 |
自然地理 | 31篇 |
出版年
2023年 | 1篇 |
2022年 | 9篇 |
2021年 | 7篇 |
2020年 | 13篇 |
2019年 | 7篇 |
2018年 | 11篇 |
2017年 | 12篇 |
2016年 | 11篇 |
2015年 | 16篇 |
2014年 | 17篇 |
2013年 | 18篇 |
2012年 | 14篇 |
2011年 | 15篇 |
2010年 | 16篇 |
2009年 | 10篇 |
2008年 | 25篇 |
2007年 | 25篇 |
2006年 | 30篇 |
2005年 | 15篇 |
2004年 | 18篇 |
2003年 | 17篇 |
2002年 | 30篇 |
2001年 | 19篇 |
2000年 | 19篇 |
1999年 | 15篇 |
1998年 | 22篇 |
1997年 | 18篇 |
1996年 | 25篇 |
1995年 | 7篇 |
1994年 | 5篇 |
1993年 | 4篇 |
1992年 | 4篇 |
1991年 | 4篇 |
1990年 | 2篇 |
1989年 | 2篇 |
1987年 | 3篇 |
1985年 | 1篇 |
1979年 | 1篇 |
排序方式: 共有488条查询结果,搜索用时 15 毫秒
31.
为了解不同类型含金属沉积物在物质组成和元素赋存状态的差异,对东太平洋海隆13°N洋中脊两侧表层含金属沉积物(站号:E271和E53)进行了矿物学、地球化学分析,顺序提取实验,并与前人对轴部表层沉积物(站号:17A-EPR-TVG1)的研究结果作了对比分析。研究结果表明, E271和E53是远端含金属沉积物,由非浮力热液羽状流中颗粒物沉降所形成的;17A-EPR-TVG1沉积物是近喷口含金属沉积物,由黑烟囱或者热液硫化物丘状体崩塌、堆积,或者由热液羽状流中Fe-Mn氧化物和硫化物快速沉淀而形成的,近喷口沉积物比远端沉积物更富集Fe、Cu和Zn等元素。元素在两种含金属沉积物中的赋存状态基本相同,除了Fe,Cu,Zn,Mo和稀土元素(REE)等元素在远端沉积物中主要存在于Fe-Mn氧化物相,在近喷口沉积物中主要在残留相中。远端沉积物中REE页岩标准化配分模式与海水相似,表明REE主要来自海水,而近喷口沉积物中REE配分模式与热液流体相似,说明REE以高温热液流体来源为主。相关研究结果加深了对热液沉积作用研究的认识。 相似文献
32.
《水文科学杂志》2013,58(2)
Abstract Abstract The MASONW (MACRO + SOILN + Watershed) model describing nitrogen leaching in watersheds was developed and tested. The model is based on the MACRO and SOILN models. The dual-porosity model MACRO simulates water flow on the field scale. The SOILN model describes turnover and leaching of nitrogen. Two main features of a watershed have been added into these two models: (a) the existence of a river system, and (b) variable thickness of the aeration zone within a watershed. Good agreement between the output of the MASONW model and observed data for water discharge and nitrate concentrations were achieved in the Odense watershed (496 km2) in Denmark. 相似文献
33.
A highly sensitive and specific enzyme immunoassay (EIA) is described for the detection of the atrazine metabolite hydroxyatrazine. Polyclonal antibodies were raised in rabbits by immunization with a hapten-bovine serum albumin (BSA) conjugate containing 8 hapten residues per molecule of BSA. An EIA with a horseradish peroxidase (HRP) hapten tracer was optimized in microtitre plates. A concentration of 50% B/B0 was found at 0.10 μg/L for hydroxyatrazine. A limit of determination for hydroxyatrazine was reached at approximately 0.01 μg/L, i.e. well below the maximum concentration permitted by the EU guidelines for drinking water and the drinking water ordinance of the FRG. The assay did not require concentration or clean-up steps for drinking water or ground water samples. Validation experiments confirmed a good accuracy and precision. Hydroxyatrazine is reported to be the main atrazine metabolite found in soil samples. As organic solvents are usually employed for soil extraction, the influence of methanol as representative organic solvent on the assay was examined. Up to a concentration of 5% (v/v) methanol, the organic solvent did not affect the assay. 相似文献
34.
A screening method for heavy metals in aqueous extracts of soil is presented which is based on inhibition of the enzymes urease and alcohol dehydrogenase. The method is suitable to detect cupric and mercury ions in concentrations below 0.01 mg/L and several other heavy metal ions in 1000 fold higher concentration. It is shown that the test may be used for screening of mercury ion concentrations exceeding 0.03 mg/L in aqueous solution when copper chelators are added to the test system. The usefulness of the presented tests to detect heavy metals eluted from soil was verified with samples from ore mining waste. The concentration of copper, lead, and zinc eluted from these samples to different amount was determined by atomic absorption spectrometry and was in good agreement with the enzyme inhibition data obtained with these samples. 相似文献
35.
36.
影响浸铀细菌活性的因素初探 总被引:3,自引:0,他引:3
微生物浸铀技术可以大幅度提高难浸铀矿石的浸出率 ,其关键技术是培养高活性的菌种。为了培养能适应多种恶劣条件的高活性菌种 ,必须对影响浸铀微生物活性的各种因素进行研究。通过实验室对浸铀细菌硫杆菌属中的氧化亚铁硫杆菌的活性因素的研究 ,并结合实际对从江西山南矿区的野外矿样中分离筛选出的菌株的活性的影响因素作了初步探讨 ,认为pH值为 1 8、温度为 30℃、接种量为 2 0 %及 90r/min的充气条件是该硫杆菌最佳的培养条件。通过对磷、铀两种元素在不同浓度下对细菌活性影响的试验 ,得出高浓度的磷、铀对细菌有明显的抑制作用 ,但通过驯化可以降低及弱化这种抑制作用。 相似文献
37.
Variations in chemical compositions of the eolian dust in Chinese Loess Plateau over the past 2.5 Ma and chemical weathering in the Asian inland 总被引:5,自引:0,他引:5
Major and trace elements as well as strontium isotopic composition have been analyzed on the acid-insoluble (AI) phase of
the loess-paleosol sequence from Luochuan, Shaanxi Province, China. Results show that the chemical composition of AI phase
of loess and paleosols is distinctive to the average composition of upper continental crust (UCC), characterized by depletion
of mobile elements Na, Ca and Sr. The distribution pattern of elements in AI phase reveals that initial dust, derived from
a vast area of Asian inland, has suffered from Na- and Ca-removed chemical weathering compared to UCC. Some geochemical parameters
(such as CIA values, Na/K, Rb/Sr and87Sr/86Sr ratios) display a regular variation and evolution, reflecting that the chemical weathering in the source region of loess
deposits has decreased gradually since 2.5 Ma with the general increase of global ice volume. This coincidence reflects that
the aridity of Asian inland since the Quaternary is a possible regional response to the global climate change. 相似文献
38.
Development of an Enzyme Immunoassay for the Detection of Mecoprop in Drinking Water and Groundwater Based on Antibodies Raised in Chicken Egg Yolk Antibodies against mecoprop were isolated from egg yolk of immunized hens and were used for the development of an enzyme-linked immunosorbent assay. We tested assay parameters (pH and concentration of buffer, incubation temperature, kind of enzyme tracer) to optimize the standard curve for mecoprop. By decreasing the pH, the detection limit was reached at a concentration of 0.35 μg/L mecoprop. The concentration for 50% inhibition (50% B/B0) was 2.8 μg/L. Dichlorprop and the methyl esters of both mecoprop and dichlorprop showed high crossreactivity (165%, 400% and 233%). Antibodies against mecoprop separated from egg yolk were compared to antibodies raised in rabbit for both sensitivity and specificity. Chicken immunoglobulins were found to be less sensitive and specific than the mammalian IgG's. 相似文献
39.
40.
在陆相古火山角砾岩筒中由火山热液蚀变产生的含黄铁矿次生石英岩中的硫化物,在特别干旱的条件下生成了以毛矾石及黄钾铁钒为主的13种钒类矿物组成的硫化矿床氧化带,并在其中聚集了毛矾石矿体。毛钒石矿是由反复进行的氧化-渗透淋滤作用而富集形成的。 相似文献