Occurrence of Phthalates in Sewage Sludge from Three Wastewater Treatment Plants in Istanbul,Turkey

Phthalates are considered priority pollutants because of their potential adverse effects on ecosystems and human health. The objectives of this study were to determine the occurrence of five phthalates (DMP, DEP, DBP, BBP, and DEHP) in sewage sludge and to determine the seasonal variability of these contaminants at three (Bahçe?ehir, Pa?aköy, and Tuzla) full‐scale municipal and domestic wastewater treatment plants (WWTP) in Istanbul, Turkey. Mass balance was also calculated for DEHP at Tuzla WWTP sludge treatment units. DMP, DEP, DBP, BBP, and DEHP concentrations in sewage sludge ranged from 1.4 to 2.7 mg/kg dry weight (dw), 1.1 to 2.8, 0.6 to 4.6, 2.8 to 6.2, 18 to 490 mg/kg dw, respectively. Phthalate concentrations from the Bahçe?ehir and Pa?aköy WWTPs met the limit (100 mg/kg dw) of Turkey national sludge regulation and the Europe Union draft of sludge directive for land application, whereas phthalate concentrations from Tuzla WWTP exceeded the maximum permissible concentration. Phthalate concentrations did not show seasonal variations for Bahçe?ehir and Pa?aköy WWTPs, which receive mainly household wastewater while some fluctuations were observed DEP, DBP, and DEHP at Tuzla WWTP which has a lot of industrial wastewater contribution. The mass balance showed that approximately 17% of DEHP in the primary and secondary sludge was removed by anaerobic digestion, while 43% returned back to the beginning of the WWTP and 40% remained in the dewatered sludge. This study suggests that phthalates in sludge from WWTPs with industrial wastewater contribution may limit the use of sludge for land application.     

A new Likelihood Ratio for supervised classification of fully polarimetric SAR data: An application for sea ice type mapping

One of the potential applications of polarimetric Synthetic Aperture Radar (SAR) data is the classification of land cover, such as forest canopies, vegetation, sea ice types, and urban areas. In contrast to single or dual polarized SAR systems, full polarimetric SAR systems provide more information about the physical and geometrical properties of the imaged area. This paper proposes a new Bayes risk function which can be minimized to obtain a Likelihood Ratio (LR) for the supervised classification of polarimetric SAR data. The derived Bayes risk function is based on the complex Wishart distribution. Furthermore, a new spatial criterion is incorporated with the LR classification process to produce more homogeneous classes. The application for Arctic sea ice mapping shows that the LR and the proposed spatial criterion are able to provide promising classification results. Comparison with classification results based on the Wishart classifier, the Wishart Likelihood Ratio Test Statistic (WLRTS) proposed by Conradsen et al. (2003) and the Expectation Maximization with Probabilistic Label Relaxation (EMPLR) algorithm are presented. High overall classification accuracy of selected study areas which reaches 97.8% using the LR is obtained. Combining the derived spatial criterion with the LR can improve the overall classification accuracy to reach 99.9%. In this study, fully polarimetric C-band RADARSAT-2 data collected over Franklin Bay, Canadian Arctic, is used.     

山东金刚石碳同位素组成的二次离子质谱显微分析

华北克拉通山东金刚石晶体生长的多阶段性及碳同位素组成已被人们关注,但很少有人对不同阶段金刚石及其内部的碳同位素组成变化进行分析。本文利用二次离子质谱(SIMS)微区分析技术对山东金刚石晶体内部不同阶段生长的δ13C进行了原位测试分析,得出山东金刚石δ13C的变化范围在-5.6‰～-2.01‰,平均值为-3.63‰,与前人对华北克拉通金刚石碳同位素组成测试值(δ13C在-14.71‰～-0.46‰,主要集中在-9‰～-4‰之间)大致相同,位于全球橄榄岩型金刚石及幔源碳同位素组成主要范围(-8‰～-2‰)内。结合金刚石生长环带阴极发光图像,认为金刚石自核心部位至边缘,在同一期生长环带内,其δ13C值呈变重趋势;在多期复杂生长环带之间,δ13C值因结晶时的地质环境不同而存在差异。δ13C值的这种变化揭示了该地区金刚石复杂的生长环境,为解析华北克拉通地幔碳循环提供了定量数据。     

ArcSDE压缩二进制存储格式的研究与改进

ArcSDE压缩二进制是ArcSDE在关系型数据库(RDBMS)中保存地理信息中二进制几何图形的存储格式,这种格式采用将浮点几何数据整形化的方法进行数据压缩,减少了数据存储空间,同时也加快了数据在网络上传输的速度。本文通过对ArcSDE压缩二进制存储格式的研究与分析,指出了这种格式在存取和处理效率上的不足之处,并提出了更为高效的改进方法。     

Critical adaptation to hurricanes in the Mexican Caribbean: Development visions, governance structures, and coping strategies

The need to tackle climate hazards and development efforts simultaneously is widely acknowledged. However, the possibility of alternative visions of development is seldom contemplated. Instead, adaptation research usually assumes monolithic claims about development constructed from the status quo of global capitalism. This paper outlines a critical approach to adaptation and explores the interplay between visions of development, governance structures, and strategies to cope with hurricanes in the Mexican Caribbean, a region at the ‘front line’ of both globalization and climatic extreme phenomena. Critical adaptation formulates the experiencing of hazards as essentially political and tied to contingent development paths, which may eventually become hegemonic. Over a hundred semi-structured and open interviews were held in Cancun, Mahahual, Playa del Carmen, and Tulum including academics, businesspeople, bureaucrats, journalists, non-governmental organizations and tourism workers in order to characterize development visions in the Mexican Caribbean. Findings show a prevalent hegemonic vision supporting mass tourism growth which encourages hurricane coping strategies based on effective evacuation and attracting investments for rapid economic recovery. The actual implementation of this vision increases social inequalities, degrades ecosystems, and amplifies overall exposure to extreme events. Mass tourism is enforced by undemocratic governance structures sustained by a coalition of government and tourism corporations (a government-capital bloc in Gramsci's sense). Some weak signs of counter-hegemony were identified in Playa del Carmen, Tulum and Mahahual. These isolated episodes of resistance might have triggered alternative coping strategies despite having little effect in altering the overall course of development. Further critical research is needed to unveil the socio-political foundations of development visions and their influence on capacities to cope with climatic extreme events.     

The Seasonal Variations of Aerosols over East Asia as Jointly Inferred from MODIS and OMI

Data on aerosol optical thickness(AOT) and single scattering albedo(SSA) derived from Moderate Resolution Imaging Spectrometer(MODIS) and Ozone Monitoring Instrument(OMI) measurements,respectively,are used jointly to examine the seasonal variations of aerosols over East Asia.The seasonal signals of the total AOT are well defined and nearly similar over the land and over the ocean.These findings indicate a natural cycle of aerosols that originate primarily from natural emissions. In contrast,the small-sized aerosols represented by the fine-mode AOT,which are primarily generated over the land by human activities,do not have evident seasonalscale fluctuations.A persistent maximum of aerosol loadings centered over the Sichuan basin is associated with considerable amounts of fine-mode aerosols throughout the year.Most regions exhibit a general spring maximum. During the summer,however,the aerosol loadings are the most marked over north central China.This occurrence may result from anthropogenic fine particles,such as sulfate and nitrate.Four typical regions were selected to perform a covariation analysis of the monthly gridded AOT and SSA.Over southwestern and southeastern China,if the aerosol loadings are small to moderate they are composed primarily of the highly absorptive aerosols. However,more substantial aerosol loadings probably represent less-absorptive aerosols.The opposite covariation pattern occurring over the coastal-adjacent oceans suggests that the polluted oceanic atmosphere is closely correlated with the windward terrestrial aerosols.North central China is strongly affected by dust aerosols that show moderate absorption.This finding may explain the lower variability in the SSA that accompanies increasing aerosol loadings in this region.     

喜马拉雅山中东段蒙达扛日冰川水文与物质平衡观测研究

2007年7—9月,在喜马拉雅山中东段蒙达扛日冰川进行了水文和物质平衡的同步观测.结果表明：观测期间,蒙达扛日冰川表现为物质负平衡,冰川消融集中在7月和8月中上旬.观测的70 d内,花杆区冰川物质平衡量为-435～-711 mm,日平均值为-6.2～-10.2 mm.d-1,冰川的总物质平衡量为-355 mm.蒙达扛日...     

南黄海西部36°N断面生态环境特征及其季节变化

重点研究了南黄海西部36°N断面水文、生源要素的四季变化特征,阐明了该断面诸参数四季变化的主控因素,并以此反映和指示了与其相关海域的生态环境特征.结果表明:黄海冷水团及黄海暖流具有季节性演替变化规律;秋季跃层以下水体是一部分夏季冷水团残留水和黄海暖流水的混合水;断面西侧在四季均存在小范围的低盐冷水现象(即青岛冷水团),...     

Inter-basin movements of Mediterranean sperm whales provide insight into their population structure and conservation

The sperm whale is one of the very few deep diving mammal species in the Mediterranean Sea. Following a rare mass stranding of male sperm whales in the Adriatic Sea in December 2009, photo-identification methods were used in order to investigate previous sightings of the stranded whales in the region. Fluke photos of the stranded whales were compared with those of 153 and 128 free-ranging individuals photographed in the western and eastern Mediterranean basins, respectively. Three out of the seven stranded whales had been previously photo-identified and some of them more than once. To reach the stranding place, two of these re-identified whales performed long-range inter-basin movements of about 1600-2100 km (in a straight line) either through the Strait of Sicily or the Strait of Messina. In addition, comparisons among all whales photographed in the two Mediterranean basins revealed that one more individual first photographed in the western basin (1991) was re-identified 13 years later in the eastern basin (2004). These three cases provide the first conclusive evidence of inter-basin movement of sperm whales in the Mediterranean Sea. Inter-basin gene flow is important for the survival of the small and endangered Mediterranean sperm whale population. Mitigating the disturbance created by human activities in the straits area is crucial for its conservation.     

Spatial variability and temporal dynamics of surface water pCO2, ��O2/Ar and dimethylsulfide in the Ross Sea, Antarctica

We report results from two surveys of pCO₂, biological O₂ saturation (??O₂/Ar) and dimethylsulfide (DMS) in surface waters of the Ross Sea polynya. Measurements were made during early spring (November 2006-December 2006) and mid-summer (December 2005-January 2006) using ship-board membrane inlet mass spectrometry (MIMS) for high spatial resolution (i.e. sub-km) analysis. During the early spring survey, the polynya was in the initial stages of development and exhibited a rapid increase in open water area and phytoplankton biomass over the course of our ∼3 week occupation. We observed a rapid transition from a net heterotrophic ice-covered system (supersaturated pCO₂ and undersaturated O₂) to a high productivity regime associated with a Phaeocystis-dominated phytoplankton bloom. The timing of the early spring phytoplankton bloom was closely tied to increasing sea surface temperature across the polynya, as well as reduced wind speeds and ice cover, leading to enhanced vertical stratification. There was a strong correlation between pCO₂, ??O₂/Ar, DMS and chlorophyll a (Chl a) during the spring phytoplankton bloom, indicating a strong biological imprint on gas distributions. Box model calculations suggest that pCO₂ drawdown was largely attributable to net community production, while gas exchange and shoaling mixed layers also exerted a strong control on the re-equilibration of mixed layer ??₂ with the overlying atmosphere. DMS concentrations were closely coupled to Phaeocystis biomass across the early spring polynya, with maximum concentrations exceeding 100 nM.During the summer cruise, we sampled a large net autotrophic polynya, shortly after the seasonal peak in phytoplankton productivity. Both diatoms and Phaeocystis were abundant in the phytoplankton assemblages during this time. Minimum pCO₂ was less than 100 ppm, while ??O₂/Ar exceeded 30% in some regions. Mean DMS concentrations were ∼2-fold lower than during the spring, although the range of concentrations was similar between the two surveys. There was a significant correlation between pCO₂, ??O₂/Ar and Chl a across the summer polynya, but the strength of these correlations and the slope of O₂ vs. CO₂ relationship were significantly lower than during the early spring. Summertime DMS concentrations were not significantly correlated to phytoplankton biomass (Chl a), pCO₂ or ??O₂/Ar. In contrast to the early spring time, there were no clear temporal trends in summertime gas concentrations. Rather, small-scale spatial variability, likely resulting from mixing and localized sea-ice melt, was clearly evident in surface gas distributions across the polynya. Analysis of length-scale dependent variability demonstrated that much of the spatial variance in surface water gases occurred at scales of <20 km, suggesting that high resolution analysis is needed to fully capture biogeochemical heterogeneity in this system.