Illawarra Reversal: The fingerprint of a superplume that triggered Pangean breakup and the end-Guadalupian (Permian) mass extinction

The Permian magnetostratigraphic record demonstrates that a remarkable change in geomagnetism occurred in the Late Guadalupian (Middle Permian; ca. 265 Ma) from the long-term stable Kiaman Reverse Superchron (throughout the Late Carboniferous and Early-Middle Permian) to the Permian–Triassic Mixed Superchron with frequent polarity changes (in the Late Permian and Triassic). This unique episode called the Illawarra Reversal probably reflects a significant change in the geodynamo in the outer core of the planet after a 50 million years of stable geomagnetism. The Illawarra Reversal was likely led by the appearance of a thermal instability at the 2900 km-deep core–mantle boundary in connection with mantle superplume activity. The Illawarra Reversal and the Guadalupian–Lopingian boundary event record the significant transition processes from the Paleozoic to Mesozoic–Modern world. One of the major global environmental changes in the Phanerozoic occurred almost simultaneously in the latest Guadalupian, as recorded in 1) mass extinction, 2) ocean redox change, 3) sharp isotopic excursions (C and Sr), 4) sea-level drop, and 5) plume-related volcanism. In addition to the claimed possible links between the above-listed environmental changes and mantle superplume activity, I propose here an extra explanation that a change in the core's geodynamo may have played an important role in determining the course of the Earth's surface climate and biotic extinction/evolution. When a superplume is launched from the core–mantle boundary, the resultant thermal instability makes the geodynamo's dipole of the outer core unstable, and lowers the geomagnetic intensity. Being modulated by the geo- and heliomagnetism, the galactic cosmic ray flux into the Earth's atmosphere changes with time. The more cosmic rays penetrate through the atmosphere, the more clouds develop to increase the albedo, thus enhancing cooling of the Earth's surface. The Illawarra Reversal, the Kamura cooling event, and other unique geologic phenomena in the Late Guadalupian are all concordantly explained as consequences of the superplume activity that initially triggered the breakup of Pangea. The secular change in cosmic radiation may explain not only the extinction-related global climatic changes in the end-Guadalupian but also the long-term global warming/cooling trend in Earth's history in terms of cloud coverage over the planet.     

Integrated “plume winter” scenario for the double-phased extinction during the Paleozoic–Mesozoic transition: The G-LB and P-TB events from a Panthalassan perspective

The event across the Paleozoic–Mesozoic transition involved the greatest mass extinction in history together with other unique geologic phenomena of global context, such as the onset of Pangean rifting and the development of superanoxia. The detailed stratigraphic analyses on the Permo-Triassic sedimentary rocks documented a two-stepped nature both of the extinction and relevant global environmental changes at the Guadalupian–Lopingian (Middle and Upper Permian) boundary (G-LB, ca. 260 Ma) and at the Permo-Triassic boundary (P-TB, ca. 252 Ma), suggesting two independent triggers for the global catastrophe. Despite the entire loss of the Permian–Triassic ocean floors by successive subduction, some fragments of mid-oceanic rocks were accreted to and preserved along active continental margins. These provide particularly important dataset for deciphering the Permo-Triassic paleo-environments of the extensive superocean Panthalassa that occupied nearly two thirds of the Earth’s surface. The accreted deep-sea pelagic cherts recorded the double-phased remarkable faunal reorganization in radiolarians (major marine plankton in the Paleozoic) both across the G-LB and the P-TB, and the prolonged deep-sea anoxia (superanoxia) from the Late Permian to early Middle Triassic with a peak around the P-TB. In contrast, the accreted mid-oceanic paleo-atoll carbonates deposited on seamounts recorded clear double-phased changes of fusuline (representative Late Paleozoic shallow marine benthos) diversity and of negative shift of stable carbon isotope ratio at the G-LB and the P-TB, in addition to the Paleozoic minimum in ⁸⁷Sr/⁸⁶Sr isotope ratio in the Capitanian (Late Guadalupian) and the paleomagnetic Illawarra Reversal in the late Guadalupian. These bio-, chemo-, and magneto-stratigraphical signatures are concordant with those reported from the coeval shallow marine shelf sequences around Pangea. The mid-oceanic, deep- and shallow-water Permian records indicate that significant changes have appeared twice in the second half of the Permian in a global extent. It is emphasized here that everything geologically unusual started in the Late Guadalupian; i.e., (1) the first mass extinction, (2) onset of the superanoxia, (3) sea-level drop down to the Phanerozoic minimum, (4) onset of volatile fluctuation in carbon isotope ratio, 5) ⁸⁷Sr/⁸⁶Sr ratio of the Paleozoic minimum, (6) extensive felsic alkaline volcanism, and (7) Illawarra Reversal.The felsic alkaline volcanism and the concurrent formation of several large igneous provinces (LIPs) in the eastern Pangea suggest that the Permian biosphere was involved in severe volcanic hazards twice at the G-LB and the P-TB. This episodic magmatism was likely related to the activity of a mantle superplume that initially rifted Pangea. The supercontinent-dividing superplume branched into several secondary plumes in the mantle transition zone (410–660 km deep) beneath Pangea. These secondary plumes induced the decompressional melting of mantle peridotite and pre-existing Pangean crust to form several LIPs that likely caused a “plume winter” with global cooling by dust/aerosol screens in the stratosphere, gas poisoning, acid rain damage to surface vegetation etc. After the main eruption of plume-derived flood basalt, global warming (plume summer) took over cooling, delayed the recovery of biodiversity, and intensified the ocean stratification. It was repeated twice at the G-LB and P-TB.A unique geomagnetic episode called the Illawarra Reversal around the Wordian–Capitanian boundary (ca. 265 Ma) recorded the appearance of a large instability in the geomagnetic dipole in the Earth’s outer core. This rapid change was triggered likely by the episodic fall-down of a cold megalith (subducted oceanic slabs) from the upper mantle to the D″ layer above the 2900 km-deep core-mantle boundary, in tight association with the launching of a mantle superplume. The initial changes in the surface environment in the Capitanian, i.e., the Kamura cooling event and the first biodiversity decline, were probably led by the weakened geomagnetic intensity due to unstable dipole of geodynamo. Under the low geomagnetic intensity, the flux of galactic cosmic radiation increased to cause extensive cloud coverage over the planet. The resultant high albedo likely drove the Kamura cooling event that also triggered the unusually high productivity in the superocean and also the expansion of O₂ minimum zone to start the superanoxia.The “plume winter” scenario is integrated here to explain the “triple-double” during the Paleozoic–Mesozoic transition interval, i.e., double-phased cause, process, and consequence of the greatest global catastrophe in the Phanerozoic, in terms of mantle superplume activity that involved the whole Earth from the core to the surface biosphere.     

Occurrence of Phthalates in Sewage Sludge from Three Wastewater Treatment Plants in Istanbul,Turkey

Phthalates are considered priority pollutants because of their potential adverse effects on ecosystems and human health. The objectives of this study were to determine the occurrence of five phthalates (DMP, DEP, DBP, BBP, and DEHP) in sewage sludge and to determine the seasonal variability of these contaminants at three (Bahçe?ehir, Pa?aköy, and Tuzla) full‐scale municipal and domestic wastewater treatment plants (WWTP) in Istanbul, Turkey. Mass balance was also calculated for DEHP at Tuzla WWTP sludge treatment units. DMP, DEP, DBP, BBP, and DEHP concentrations in sewage sludge ranged from 1.4 to 2.7 mg/kg dry weight (dw), 1.1 to 2.8, 0.6 to 4.6, 2.8 to 6.2, 18 to 490 mg/kg dw, respectively. Phthalate concentrations from the Bahçe?ehir and Pa?aköy WWTPs met the limit (100 mg/kg dw) of Turkey national sludge regulation and the Europe Union draft of sludge directive for land application, whereas phthalate concentrations from Tuzla WWTP exceeded the maximum permissible concentration. Phthalate concentrations did not show seasonal variations for Bahçe?ehir and Pa?aköy WWTPs, which receive mainly household wastewater while some fluctuations were observed DEP, DBP, and DEHP at Tuzla WWTP which has a lot of industrial wastewater contribution. The mass balance showed that approximately 17% of DEHP in the primary and secondary sludge was removed by anaerobic digestion, while 43% returned back to the beginning of the WWTP and 40% remained in the dewatered sludge. This study suggests that phthalates in sludge from WWTPs with industrial wastewater contribution may limit the use of sludge for land application.     

A new Likelihood Ratio for supervised classification of fully polarimetric SAR data: An application for sea ice type mapping

One of the potential applications of polarimetric Synthetic Aperture Radar (SAR) data is the classification of land cover, such as forest canopies, vegetation, sea ice types, and urban areas. In contrast to single or dual polarized SAR systems, full polarimetric SAR systems provide more information about the physical and geometrical properties of the imaged area. This paper proposes a new Bayes risk function which can be minimized to obtain a Likelihood Ratio (LR) for the supervised classification of polarimetric SAR data. The derived Bayes risk function is based on the complex Wishart distribution. Furthermore, a new spatial criterion is incorporated with the LR classification process to produce more homogeneous classes. The application for Arctic sea ice mapping shows that the LR and the proposed spatial criterion are able to provide promising classification results. Comparison with classification results based on the Wishart classifier, the Wishart Likelihood Ratio Test Statistic (WLRTS) proposed by Conradsen et al. (2003) and the Expectation Maximization with Probabilistic Label Relaxation (EMPLR) algorithm are presented. High overall classification accuracy of selected study areas which reaches 97.8% using the LR is obtained. Combining the derived spatial criterion with the LR can improve the overall classification accuracy to reach 99.9%. In this study, fully polarimetric C-band RADARSAT-2 data collected over Franklin Bay, Canadian Arctic, is used.     

山东金刚石碳同位素组成的二次离子质谱显微分析

华北克拉通山东金刚石晶体生长的多阶段性及碳同位素组成已被人们关注,但很少有人对不同阶段金刚石及其内部的碳同位素组成变化进行分析。本文利用二次离子质谱(SIMS)微区分析技术对山东金刚石晶体内部不同阶段生长的δ13C进行了原位测试分析,得出山东金刚石δ13C的变化范围在-5.6‰～-2.01‰,平均值为-3.63‰,与前人对华北克拉通金刚石碳同位素组成测试值(δ13C在-14.71‰～-0.46‰,主要集中在-9‰～-4‰之间)大致相同,位于全球橄榄岩型金刚石及幔源碳同位素组成主要范围(-8‰～-2‰)内。结合金刚石生长环带阴极发光图像,认为金刚石自核心部位至边缘,在同一期生长环带内,其δ13C值呈变重趋势;在多期复杂生长环带之间,δ13C值因结晶时的地质环境不同而存在差异。δ13C值的这种变化揭示了该地区金刚石复杂的生长环境,为解析华北克拉通地幔碳循环提供了定量数据。     

ArcSDE压缩二进制存储格式的研究与改进

ArcSDE压缩二进制是ArcSDE在关系型数据库(RDBMS)中保存地理信息中二进制几何图形的存储格式,这种格式采用将浮点几何数据整形化的方法进行数据压缩,减少了数据存储空间,同时也加快了数据在网络上传输的速度。本文通过对ArcSDE压缩二进制存储格式的研究与分析,指出了这种格式在存取和处理效率上的不足之处,并提出了更为高效的改进方法。     

Critical adaptation to hurricanes in the Mexican Caribbean: Development visions, governance structures, and coping strategies

The need to tackle climate hazards and development efforts simultaneously is widely acknowledged. However, the possibility of alternative visions of development is seldom contemplated. Instead, adaptation research usually assumes monolithic claims about development constructed from the status quo of global capitalism. This paper outlines a critical approach to adaptation and explores the interplay between visions of development, governance structures, and strategies to cope with hurricanes in the Mexican Caribbean, a region at the ‘front line’ of both globalization and climatic extreme phenomena. Critical adaptation formulates the experiencing of hazards as essentially political and tied to contingent development paths, which may eventually become hegemonic. Over a hundred semi-structured and open interviews were held in Cancun, Mahahual, Playa del Carmen, and Tulum including academics, businesspeople, bureaucrats, journalists, non-governmental organizations and tourism workers in order to characterize development visions in the Mexican Caribbean. Findings show a prevalent hegemonic vision supporting mass tourism growth which encourages hurricane coping strategies based on effective evacuation and attracting investments for rapid economic recovery. The actual implementation of this vision increases social inequalities, degrades ecosystems, and amplifies overall exposure to extreme events. Mass tourism is enforced by undemocratic governance structures sustained by a coalition of government and tourism corporations (a government-capital bloc in Gramsci's sense). Some weak signs of counter-hegemony were identified in Playa del Carmen, Tulum and Mahahual. These isolated episodes of resistance might have triggered alternative coping strategies despite having little effect in altering the overall course of development. Further critical research is needed to unveil the socio-political foundations of development visions and their influence on capacities to cope with climatic extreme events.     

The Seasonal Variations of Aerosols over East Asia as Jointly Inferred from MODIS and OMI

Data on aerosol optical thickness(AOT) and single scattering albedo(SSA) derived from Moderate Resolution Imaging Spectrometer(MODIS) and Ozone Monitoring Instrument(OMI) measurements,respectively,are used jointly to examine the seasonal variations of aerosols over East Asia.The seasonal signals of the total AOT are well defined and nearly similar over the land and over the ocean.These findings indicate a natural cycle of aerosols that originate primarily from natural emissions. In contrast,the small-sized aerosols represented by the fine-mode AOT,which are primarily generated over the land by human activities,do not have evident seasonalscale fluctuations.A persistent maximum of aerosol loadings centered over the Sichuan basin is associated with considerable amounts of fine-mode aerosols throughout the year.Most regions exhibit a general spring maximum. During the summer,however,the aerosol loadings are the most marked over north central China.This occurrence may result from anthropogenic fine particles,such as sulfate and nitrate.Four typical regions were selected to perform a covariation analysis of the monthly gridded AOT and SSA.Over southwestern and southeastern China,if the aerosol loadings are small to moderate they are composed primarily of the highly absorptive aerosols. However,more substantial aerosol loadings probably represent less-absorptive aerosols.The opposite covariation pattern occurring over the coastal-adjacent oceans suggests that the polluted oceanic atmosphere is closely correlated with the windward terrestrial aerosols.North central China is strongly affected by dust aerosols that show moderate absorption.This finding may explain the lower variability in the SSA that accompanies increasing aerosol loadings in this region.     

喜马拉雅山中东段蒙达扛日冰川水文与物质平衡观测研究

2007年7—9月,在喜马拉雅山中东段蒙达扛日冰川进行了水文和物质平衡的同步观测.结果表明：观测期间,蒙达扛日冰川表现为物质负平衡,冰川消融集中在7月和8月中上旬.观测的70 d内,花杆区冰川物质平衡量为-435～-711 mm,日平均值为-6.2～-10.2 mm.d-1,冰川的总物质平衡量为-355 mm.蒙达扛日...     

南黄海西部36°N断面生态环境特征及其季节变化

重点研究了南黄海西部36°N断面水文、生源要素的四季变化特征,阐明了该断面诸参数四季变化的主控因素,并以此反映和指示了与其相关海域的生态环境特征.结果表明:黄海冷水团及黄海暖流具有季节性演替变化规律;秋季跃层以下水体是一部分夏季冷水团残留水和黄海暖流水的混合水;断面西侧在四季均存在小范围的低盐冷水现象(即青岛冷水团),...