羌塘岩带碰撞后超钾质火山岩地球化学特征及成因探讨

羌塘超钾质火山岩为板块碰撞后的产物,地球化学特征表明,其同时具有板内火山岩和俯冲带岛弧火山岩的双重地球化学特性。化学组成上富含轻稀土和大离子亲石元素而亏损Cr、Ni等相容元素。在成因上受分离结晶作用和源区混合作用共同制约。源区为受古俯冲上地壳物质和下地幔上升流体交代混合的EMII型富集地幔端元,可能富含角闪石和金云母等矿物。     

Characterisation of the Dabla Granitoids, North Khetri Copper Belt, Rajasthan, India: Evidence of Bimodal Anorogenic Felsic Magmatism

The Palaeoproterozoic Dabla granitoid pluton of the North Khetri Copper Belt is located to the east of a NNE-SSW trending lineament with numerous albite-rich intrusives, the intraplate ‘albitite line’. The Dabla pluton is essentially made up of calcic amphibole-bearing granitoids, displaying a concentric bimodal distribution of alkali-feldspar granites, comprising a microcline-albite granite and an albite-granite. The dominant rock type is pink-coloured granite, which is characterised by quartz, microcline, albite and hastingsitic hornblende, and occurs in the marginal parts of the pluton. The volumetrically subordinate albite-granite in the central part of the pluton is invariably white in colour, non-foliated and is mainly composed of quartz, albite and amphibole of actinolite to ferro-actinolite composition. The albite-granite is characterised by low K₂O (0.06-0.09%), Rb (<5 ppm) and Ba (<20 ppm), high Na₂O (7.19-7.36%) and high Na/K ratios (122.4-185.2) as compared to the granite. These rocks are not subjected to any metamorphic overprint, especially the albite-granite, which shows pristine abundances of major and trace elements. The rocks are highly evolved as reflected in their high SiO₂ (72 to 78%) contents and high DI (89.5-97) values. The Dabla granitoids are characterised by similar REE and spider patterns, displaying LREE enriched slopes, flat HREE profiles and strong negative Sr, P, Ti and Eu anomalies suggesting their comagmatic nature. Nevertheless, the granite is relatively more fractionated [(La/Yb)_N = 3.89-8.19] and show higher REE abundances (466-673 ppm) as compared to the albite-granite [(La/Yb)_N = 1.97-2.96; REE = 220-277 ppm]. Distinctive features of these rocks are their low Ca (0.21-1.53%), Mg (<0.02-0.19%), Al (11.84-12.96%) and Sr (12-46 ppm) abundances, high Zr (155-631 ppm), Y (67-156 ppm), Nb (14-91 ppm), and Ga (20-31 ppm) concentrations and high Fe*-number, high Ga/Al ratio and high agpaitic index (AI) values. These features, coupled with their ferroan, alkaline and metaluminous nature, are typical of within-plate aluminous A-type granites. The geochemical data further indicate that the Dabla magma was generated at fairly high temperature, apparently in an upper mantle region, under relatively low H₂O activities and reduced conditions and emplaced at a shallow depth in an extensional tectonic environment.     

Petrology, geochemistry and isotopic ages of eclogites from the Dulan UHPM Terrane, the North Qaidam, NW China

The Dulan eclogite–gneiss region is located in the eastern part of the North Qaidam eclogite belt, NW China. Widespread evidence demonstrates that this region is a typical ultrahigh-pressure (UHP) metamorphic terrane. Eclogites occur as lenses or layers in both granitic and pelitic gneisses. Two distinguished sub-belts can be recognized and differ in mineralogy, petrology and geochemistry. The North Dulan Belt (NDB) has tholeiitic protoliths with high TiO₂ and lower Al₂O₃ and MgO contents. REE patterns and trace element contents resemble those of N-type and E-type MORB. In contrast, eclogites in the South Dulan Belt (SDB) are of island arc protoliths with low TiO₂, high Al₂O₃ and show LREE-enriched and HFSE-depleted patterns. Sm–Nd isotope analyses give isochron ages of 458–497 Ma for eclogite-facies metamorphism for the two sub-belts. The ages are similar to those of Yuka and Altun eclogites in the western extension of the North Qaidam-Altun eclogite belt. The Dulan UHP metamorphic terrane, together with several other recently recognized eclogite-bearing terrenes within the North Qaidam-Altun HP-UHP belt, constitute the key to the understanding of the tectonic evolution of the northern Tibetan Plateau. The entire UHP belt extends for more than 1000 km from the Dulan UHP terrane in the southeast to the Altun eclogite–gneiss terrane in the west. This super-belt marks an early Paleozoic continental collision zone between the Qaidam Massif and the Qilian Massif.     

Provenance analysis and tectonic setting of the Ordovician clastic deposits in the southern Puna Basin, NW Argentina

Provenance studies on Early to Middle Ordovician clastic formations of the southern Puna basin in north-western Argentina indicate that the sedimentary detritus is generally composed of reworked crustal material. Tremadoc quartz-rich turbidites (Tolar Chico Formation, mean composition Q_t89 F7 L4) are followed by volcaniclastic rocks and greywackes (Tolillar Formation, mean Q_t33 F42 L25). These are in turn overlain by volcaniclastic deposits (mean Q_t24 F30 L46) of the Diablo Formation (late Arenig–early Llanvirn) that are intercalated by lava flows. All units were deformed in the Oclóyic Orogeny during the Middle and Late Ordovician. Sandstones of the Tolar Chico Formation are characterized by Th/Sc ratios > 1, La/Sc ratios ≈ 10, whereas associated fine-grained wackes show slightly lower values for both ratios. LREE (light rare earth elements) enrichment of the arenites is ≈ 50× chondrite, Eu/Eu* values are between 0·72 and 0·92, and flat HREE (heavy rare earth elements) patterns indicate a derivation from mostly felsic rocks of typical upper crustal composition. The ε_{Nd(t = sed)} values scatter around −11 to −9. The calculated Nd-T_DM residence ages vary between 1·8 and 2·0 Ga indicating contribution by a Palaeoproterozoic crustal component. The Th/Sc and La/Sc ratios of the Tolillar Formation are lower than those of the Tolar Chico Formation. Normalized REE (rare earth elements) patterns display a similar shape to PAAS (post-Archaean average Australian shale) but with higher abundances of HREEs. Eu/Eu* values range between 0·44 and 1·17, where the higher values reflect the abundance of plagioclase and feldspar-bearing volcanic lithoclasts. Average ε_{Nd(t = sed)} values are less negative at −5·1, and Nd-T_DM are lower at 1·6 Ga. This is consistent with characteristics of regional rocks of upper continental crust composition, which most probably represent the sources of the studied detritus. The rocks of the Diablo Formation have the lowest Th/Sc and La/Sc ratios, lower LREE abundances than the average continental crust and are slightly enriched in HREEs. Eu/Eu* values are between 0·63 and 1·17. The Nd isotopes (ε_{Nd(t = sed)} = −3 to −1; T_DM = 1·2 Ga) indicate that one source component was less fractionated than both the underlying Early Ordovician and the overlying Middle Ordovician units. Synsedimentary vulcanites in the Diablo Formation show the same isotopic composition. Our data indicate that the sedimentary detritus is generally composed of reworked crustal material, but that the Diablo Formation appears to contain ≈ 80% of a less fractionated component, derived from a contemporaneous continental volcanic arc. There are no data indicating an exotic detrital source or the accretion of an exotic block at this part of the Gondwana margin during the Ordovician.     

Tectonic controls on metamorphism, partial melting, and intrusion: timing and duration of regional metamorphism and magmatism in the Ni de Massif, Turkey

Mafic high-pressure granulite, eclogite and pyroxenite xenoliths have been collected from a Mesozoic volcaniclastic diatreme in Xinyang, near south margin of the Sino-Korean Craton (SKC). The high-pressure granulite xenoliths are mainly composed of fine-grained granoblasts of Grt+Cpx+Pl+Hbl±Kfs±Q±Ilm with relict porphyritic mineral assemblage of Grt+Cpx±Pl±Rt. P–T estimation indicates that the granoblastic assemblage crystallized at 765–890 °C and 1.25–1.59 GPa, corresponding to crustal depths of ca. 41–52 km with a geotherm of 75–80 mW/m². Calculated seismic velocities (V_p) of high-pressure granulites range from 7.04 to 7.56 km/s and densities (D) from 3.05 to 3.30 g/cm³. These high-pressure granulite xenoliths have different petrographic and geochemical features from the Archean mafic granulites. Elevated geotherm and petrographic evidence imply that the lithosphere of this craton was thermally disturbed in the Mesozoic prior to eruption of the host diatreme. These samples have sub-alkaline basaltic compositions, equivalent to olivine– and quartz–tholeiite. REE patterns are flat to variably LREE-enriched (La_N/Yb_N=0.98–9.47) without Eu anomaly (Eu/Eu*=0.95–1.11). They possess 48–127 ppm Ni and 2–20 ppm Nb with Nb/U and La/Nb ratios of 13–54 and 0.93–4.75, respectively, suggesting that these high-pressure granulites may be products of mantle-derived magma underplated and contaminated at the base of the lower crust. This study also implies that up to 10 km Mesozoic lowermost crust was delaminated prior to eruption of the Cenozoic basalts on the craton.     

Surface analysis of pyrite in the No. 9 coal seam, Wuda Coalfield, Inner Mongolia, China, using high-resolution time-of-flight secondary ion mass-spectrometry

The chemical composition of pyrite in coal can be used to investigate its geological and mineralogical origin. In this paper, high-resolution time-of-flight secondary ion mass spectrometry (TOF-SIMS) was used to study the chemical composition of various pyrite forms in the No. 9 coal seam (S_t,d=3.46%) from the Wuda Coalfield, Inner Mongolia, northern China. These include bacteriogenic, framboidal, massive, cell-filling, fracture-filling, and nodular pyrites. In addition to Fe⁺ (⁵⁴Fe⁺, ⁵⁶Fe⁺, ⁵⁷Fe⁺), other fragment ions were detected in bacteriogenic pyrites, such as ²⁷Al⁺, Si⁺ (²⁸Si⁺, ²⁹Si⁺, ³⁰Si⁺), ⁴⁰Ca⁺, Cu⁺ (⁶³Cu⁺, ⁶⁵Cu⁺), Zn⁺ (⁶⁴Zn⁺, ⁶⁶Zn⁺, ⁶⁷Zn⁺, ⁶⁸Zn⁺), Ni⁺ (⁵⁸Ni⁺, ⁶⁰Ni⁺, ⁶²Ni⁺), and C₃H₇⁺. TOF-SIMS images show bacteriogenic pyrites are relatively rich in Cu, Zn, and Ni, suggesting that bacteria probably play an important role in the enrichment of Cu, Zn, and Ni during their formation. Intense positive secondary ion fragments from framboidal aggregates, such as ²⁷Al⁺, ²⁸Si⁺, ²⁹Si⁺, AlO⁺, CH₂⁺, C₃H₃⁺, C₃H₅⁺, and C₄H₇⁺, indicate that formation of the framboidal aggregates may have occurred together with clay mineral and organic matter, which probably serve as the binding substance. The intense ions of ²⁸Si⁺ and ²⁷Al⁺ from massive pyrites also suggest that their pores incorporated clay minerals during crystallization. Together with the lowest ²⁸Si⁺/²³Na⁺ value, the intense organic positive secondary ion peaks from cell-filling pyrites, such as C₃H₃⁺, C₃H₅⁺, C₃H₇⁺, and C₄H₇⁺, indicate that pyrite formation may have accompanied dissolution or disintegration of the cell. The intense P⁺ peak was observed only in the fracture-filling pyrite and the highest ²⁸Si⁺/²³Na⁺ value of fracture-filling pyrite reflects its epigenetic origin. Together with XRD and REEs data, the stronger ⁴⁰Ca⁺ in nodular pyrite than other pyrite forms shows seawater influence during its formation.     

A late quaternary record of eolian silt deposition in a maar lake, St. Michael Island, western Alaska

Recent stratigraphic studies in central Alaska have yielded the unexpected finding that there is little evidence for full-glacial (late Wisconsin) loess deposition. Because the loess record of western Alaska is poorly exposed and not well known, we analyzed a core from Zagoskin Lake, a maar lake on St. Michael Island, to determine if a full-glacial eolian record could be found in that region. Particle size and geochemical data indicate that the mineral fraction of the lake sediments is not derived from the local basalt and is probably eolian. Silt deposition took place from at least the latter part of the mid-Wisconsin interstadial period through the Holocene, based on radiocarbon dating. Based on the locations of likely loess sources, eolian silt in western Alaska was probably deflated by northeasterly winds from glaciofluvial sediments. If last-glacial winds that deposited loess were indeed from the northeast, this reconstruction is in conflict with a model-derived reconstruction of paleowinds in Alaska. Mass accumulation rates in Zagoskin Lake were higher during the Pleistocene than during the Holocene. In addition, more eolian sediment is recorded in the lake sediments than as loess on the adjacent landscape. The thinner loess record on land may be due to the sparse, herb tundra vegetation that dominated the landscape in full-glacial time. Herb tundra would have been an inefficient loess trap compared to forest or even shrub tundra due to its low roughness height. The lack of abundant, full-glacial, eolian silt deposition in the loess stratigraphic record of central Alaska may be due, therefore, to a mimimal ability of the landscape to trap loess, rather than a lack of available eolian sediment.     

铂族元素迁移富集机理的新探

在岩浆及高温热液中，拍族元素以纳米液态铂族元素单质、铂族元素与其它金属元素的纳米液态合金、纳米液态铂族元素的硫、砷化物迁移。在中、低温热液及表生条件下，除呈上述固态纳米铂族矿物随流体迁移外，还呈配合物形式迁移。然后它们在合适的条件下沉淀富集形成矿床。此外，还讨论了铂族元素与金地球化学条件的异同。     

滇东早寒武世梅树村期浅色粘土岩层的地球化学特征和地质意义

滇东早寒武世梅树村期含磷岩系中出现的十多层浅色粘土岩层为酸性火山灰蚀变而成的变斑脱岩，它们是火山喷发事件和事件地层对比的标志。这些浅色粘土岩层中稳定微量元素Ｈｆ、Ｎｂ、Ｙ、Ｔｈ、Ｚｒ含量高于非火山成因的粘土，而Ｆｅ、Ｎｉ、Ｃｏ、Ｃｒ含量低于筇竹寺组泥岩。ＴｉＯ２／Ａｌ２Ｏ３、Ｚｒ／Ｈｆ、Ｔｉ／Ｔｈ比值属于酸性岩浆范围，球粒标准化稀土元素配分模式和具中至大的Ｅｕ负异常类似于花岗岩稀土配分模式。岩浆判别图指示了梅树村期变斑脱岩具板内花岗岩位置的亚碱性流纹岩和粗面岩岩浆亲缘性。变斑脱岩在地层序列上和区域上分布表明扬子地台西缘早寒武世初期火山活动频繁，火山喷发事件与古大陆解体和板内拉张构造运动有关。