日照市东南部地区榴辉岩矿矿石加工技术性能及选矿工艺研究

日照市东南部岚山安东卫、虎山地区位于苏鲁榴辉岩带南西段的中部,区域内赋存大型榴辉岩矿体,榴辉岩资源较丰富。榴辉岩含有的石榴子石、绿辉石、金红石都是应用很广的矿物,但榴辉岩的选矿工艺比较复杂,特别是其中金红石的选矿分离一直难以解决。该文就日照东南部地区的榴辉岩矿石的加工技术性能及选矿工艺进行了试验和探讨研究,为今后该区榴辉岩矿的开发利用打下了一定基础。     

The formation of eclogite facies metatroctolites and a general petrogenetic grid in Na2O–CaO–FeO–MgO–Al2O3–SiO2–H2O (NCFMASH)

Eclogite facies metatroctolites from a variety of Western Alps localities (Voltri, Monviso, Lanzo, Allalin, Zermat–Saas, etc.) that preserve textural evidence of their original form as bimineralic olivine‐plagioclase rocks are considered in terms of calculated mineral equilibria in the system Na₂O‐CaO‐FeO‐MgO‐Al₂O₃‐SiO₂‐H₂O (NCFMASH). Pseudosections, based on a new petrogenetic grid for NCFMASH presented here, are used to unravel the metamorphic history of the metatroctolites, considering the rocks to consist of different composition microdomains corresponding to the original olivine and plagioclase grains. On the basis that the preservation of the mineral assemblage in each microdomain will tend to be from where on a rock's P–T path the metamorphic fluid phase is used up via rehydration reactions, P–T pseudosections contoured for water content, and P–T path‐M_H2O (amount of water) pseudosections, are used to examine fluid behaviour in each microdomain. We show that the different microdomains are likely to preserve their mineral assemblages from different places on the P–T path. For the olivine microdomain, the diagnostic mineral assemblage is chloritoid + talc (+ garnet + omphacite). The preservation of this assemblage, in the light of the closed system P–T path‐M_H2O relationships, implies that the microdomain loses its metamorphic fluid as it starts to decompress, and, in the absence of subsequent hydration, the high pressure mineral assemblage is then preserved. In the plagioclase microdomain, the diagnostic assemblage is epidote (or zoisite) + kyanite + quartz suggesting a lower pressure (of about 2 GPa) than for the olivine microdomain. In the light of P–T path‐M_H2O relationships, development of this assemblage implies breakdown of lawsonite across the lawsonite breakdown reaction, regardless of the maximum pressure reached. It is likely that the plagioclase microdomain was mainly fluid‐absent prior to lawsonite breakdown, only becoming fluid‐present across the reaction, then immediately becoming fluid‐absent again.     

苏鲁造山带池庄超高压榴辉岩中变质脉:大陆俯冲带超临界流体活动的证据

高压-超高压变质岩中的变质脉能够反映俯冲带变质流体的组成和演化。为了探究大陆俯冲带超临界流体活动及伴随的元素迁移,本文系统地研究了苏鲁造山带南部江苏东海池庄地区的超高压榴辉岩及变质脉。变质脉主要是由石英、石榴石、绿辉石、多硅白云母、蓝晶石、黝帘石、金红石和锆石等矿物组成,与寄主榴辉岩的矿物组成类似。相比于榴辉岩,脉体中的石榴石更加富集重稀土元素(HREE);黝帘石强烈富集轻稀土元素(LREE)。变质脉和榴辉岩中各主要矿物的氧同位素组成在误差范围内一致(石英的δ18O分别为2.42‰和2.79‰;石榴石为-0.30‰和0.010‰;绿辉石为0.25‰和0.071‰),说明变质脉的形成与榴辉岩释放的内部流体有关。综合已有的研究,发现大别-苏鲁造山带不同地区的变质脉和榴辉岩具有极不均一的氧同位素组成,说明在陆壳深俯冲和折返过程中,流体活动有限。利用矿物温压计得到变质脉的峰期变质温压条件为692±65℃和3.6±0.3GPa,脉体中锆石U-Pb定年结果表明锆石的形成时代为218±2.4Ma,指示变质脉形成于深俯冲陆壳折返初期的超高压变质阶段。变质脉中矿物组合和矿物的主微量元素特征说明成脉流体富集Si、Al、Ca、K、LILE、REE和HFSE等元素,表明成脉流体可能是溶解能力极强的超临界流体。     

Magma underplating and Hannuoba present crust-mantle transitional zone composition: Xenolith petrological and geochemical evidence

Studies on the deep-seated xenoliths from global volcanoes reveal that the present petrological crust-mantle boundary between the lower crust and the upper mantle actually is a transitional layer from mainly mafic granulites to ultramafic spinel lher-zolites[1,2], i.e. a transitional zone distinctive from the seismological Moho[3]. Oceanic lithosphere crust- mantle transitional zone can be established from the study on the exposed ophiolites. However, as for the continental lithosphere, since …     

Metamorphic garnet pyroxenite from the 540-600 m main borehole of the Chinese Continental Scientific Drilling (CCSD) project

Compared to other mafic and ultramafic rocks from the CCSD main borehole as well as from the outcrops, rocks from the 540-600 m section is extraordinary in terms of its geophysical as well as geochemical properties. It consists of > 70% hematite-ilmenite garnet pyroxenite (HI-GPX) and < 30% intercalated rutile garnet pyroxenite (R-GPX). Whole-rock geochemical data show that HI-GPXs have: (1) relatively high V with an average of 606 ppm, but lower Nb and Ta; (2) highest TFeO, Fe₂O₃/FeO ratio, and highly variable but strong positive Eu anomalies with Eu/Eu? up to 2.9; (3) anomalously high V/Sc ratios ranging from 8.39 to 43.23, average 15.03; and (4) high amounts of hematite-ilmenite solid solutions with a very fine intergrowth structure down to nanometer scale. V/Sc ratios in the CCSD garnet pyroxenites are correlated negatively with MgO, but positively with Fe₂O₃/FeO ratios. Both suites of pyroxenites have similar rare earth elements and high field strength elements geochemistry. These features demonstrate that these pyroxenites were formed from metamorphism of high-Fe and/or -Ti gabbroic cumulates. This can account not only for low high field strength elements (HFSE) and rare earth elements (REE) but also low Nb/Ta and Zr/Hf ratios in these rocks. Seemingly negative correlation between Nb/Ta and Zr/Hf in the CCSD metabasites, not significantly affected by UHP metamorphism, is also consistent with the silicate differentiation trend in a basaltic magma chamber.     

滇东南建水地区高镁火山岩包体的成因和构造背景

在滇东南建水地区发现产于峨眉山玄武岩中的高镁火山岩包体,这对于地幔柱的形成演化具有重要研究意义.对这些包体进行了锆石U-Pb年代学、地球化学和岩矿分析.高镁火山岩包体具斑状结构,致密块状构造,斑晶主要为贵橄榄石和透辉石.13颗锆石U-Pb LA-ICP-MS加权平均年龄为259±2Ma(MSWD=1.9),显示与寄主岩石同期形成.包体岩石具有高镁(Mg~#=68～75)、低硅(SiO_2=45.11%～45.93%)特征,轻稀土元素(LREE)、高场强元素(HFSE)富集而重稀土元素(HREE)亏损,属于亚碱性、拉斑玄武岩系列,具有板内玄武岩(IPB)特征.火山岩包体的原始岩浆起源于石榴子石二辉橄榄岩低程度部分熔融的产物,岩浆演化过程中发生了橄榄石和单斜辉石的分离结晶作用,在侵位上升过程中未受明显的地壳混染作用.该高镁火山岩的存在,显示地幔柱除了垂直上升运动外,在地球深部不同的边界还有多次侧向扩展移动,表明滇东南晚二叠世存在峨眉山地幔柱的一个分支-地幔枝活动.     

Thermal Structure and Rheology of the Upper Mantle beneath Guangdong and Hainan Provinces, China

１．Ｉｎｔｒｏｄｕｃｔｉｏｎ　　Ｔｈｅｔｈｅｒｍａｌｓｔａｔｅａｎｄｒｈｅｏｌｏｇｙｏｆｔｈｅｕｐｐｅｒｍａｎｔｌｅａｒｅｏｆｇｒｅａｔｉｍｐｏｒｔａｎｃｅｉｎｕｎｄｅｒｓｔａｎｄｉｎｇｔｈｅｓｔｒｕｃｔｕｒｅａｎｄｄｙｎａｍｉｃｓｏｆｔｈｅｌｉｔｈｏｓｐｈｅｒｅ,ａｎｄｅｖｅｎｆｏｒｉｔｓ３ｄｉｍｅｎｓｉｏｎａｌｏｒ４ｄｉｍｅｎｓｉｏｎａｌｍａｐｐｉｎｇ（Ｏ’ＲｅｉｌｌｙａｎｄＧｒｉｆｆｉｎ,１９８５;Ｏ’Ｒｅｉｌｌｙｅｔａｌ．,１９９６;Ｘｕｅｔａｌ．１９９５;Ｘｕｅｔａｌ．,１９９…     

吉林龙冈火山群金龙顶子火山喷发物中幔源包体的基本特征及其地质意义

龙冈火山群金龙顶子火山喷发发生在距今1500年前,其火山喷发物中所含的幔源橄榄岩包体是我国在最新火山喷发物中所发现的幔源包体。这些包体以普遍含有韭闪石为特征。包体的结构和位错构造反映这些包体在上地幔条件下经历过一定程度的变形作用。包体的平衡温度大多数集中在800～950℃之间,只有个别样品温度达到1050℃;平衡压力大多数集中在1.0～1.5 GPa之间。由包体平衡温度、压力得到的上地幔地温线稍低于中国东部由新第三纪包体得到的上地幔地温线,但接近第四纪包体得到的地温线。包体在上地幔条件下变形时的差异应力在30～44MPa,应变速率为10-18s-110-15s-1。角闪石的出现反映上地幔流体的渗透及交代作用。金龙顶子火山发的玄武岩浆直接来自35～50km的上地幔顶部。     

浙江新昌地幔岩捕虏体中的硫化物包裹体初步研究

浙江新昌一带晚第三纪碱性玄武岩中地幔岩（二辉橄榄岩）捕虏体内存在大量硫化物熔体包裹体。电子探针分析表明,硫化物相成分主要为镍黄铁矿,次为磁共铁矿。硫化物包裹体的Ｎｉ／Ｆｅ值与寄主地幔岩的橄榄石含量呈正相关。同一包裹体的硫化物相成分不均一,自中心至边缘硫化物的Ｎｉ／Ｆｅ、（Ｆｅ＋Ｎｉ）／Ｓ值和Ｎｉ呈均呈增加趋势。通过与中国汉诺坝、德国ＷｅｓｔＥｉｆｅｌ东欧Ｎｏｇｒａｄ－Ｇｏｍｏｒ地区资料的综合分析,     

碱性玄武岩中幔源岩石包体内尖晶石成分特征及其岩石学成因意义

通过对我国东部北起黑龙江省南至海南省３１个产地的新生代碱性玄武岩中橄榄岩类 （纯橄岩、方辉橄榄岩及二辉橄榄岩） 包体和辉石岩类包体中的１６０ 多个尖晶石电子探针分析数据, 论述了尖晶石的Ｃｒ－Ａｌ, Ｆｅ－Ｍｇ, Ｎｉ－Ｍｇ 主元素及有关比值和端员组分之间的关系, 分析研究了不同岩类包体中尖晶石的颜色、成分及成因之间的联系。并利用所分析的有关橄榄石、斜方辉石、单斜辉石共生矿物的电子探针分析数据, 采用新的、较合理的Ｂｒｅｙ－Ｋｏｈｌｅｒ温度计及Ｋｏｈｌｅｒ－Ｂｒｅｙ 压力计和Ｂａｌｌｈａｕｓ ｅｔａｌ． 氧逸度计算方法进行了计算, 探讨了尖晶石成分与其形成温度、压力和氧逸度状态的关系, 指出了尖晶石成分所反映的地幔亏损程度及部分熔融程度的变化规律及尖晶石 （相） 稳定的温度、压力和氧逸度范围。