Triassic warm subduction in northeast Turkey: Evidence from the Ağvanis metamorphic rocks

Within the Tethyan realm, data for the subduction history of the Permo–Triassic Tethys in the form of accretionary complexes are scarce, coming mainly from northwest Turkey and Tibet. Herein we present field geological, petrological and geochronological data on a Triassic accretionary complex, the A?vanis metamorphic rocks, from northeast Turkey. The A?vanis metamorphic rocks form a SSE–NNW trending lozenge‐shaped horst, ～20 km long and ～6 km across, bounded by the strands of the active North Anatolian Fault close to the collision zone between the Eastern Pontides and the Menderes–Taurus Block. The rocks consist mainly of greenschist‐ to epidote‐amphibolite‐facies metabasite, phyllite, marble and minor metachert and serpentinite, interpreted as a metamorphic accretionary complex based on the oceanic rock types and ocean island basaltic, mid‐ocean ridge basaltic and island‐arc tholeiitic affinities of the metabasites. This rock assemblage was intruded by stocks and dikes of Early Eocene quartz diorite, leucogranodiorite and dacite porphyry. Metamorphic conditions are estimated to be 470–540°C and ～0.60–0.90 GPa. Stepwise ⁴⁰Ar/³⁹Ar dating of phengite–muscovite separates sampled outside the contact metamorphic aureoles yielded steadily increasing age spectra with the highest incremental stage corresponding to age values ranging from ～180 to 209 Ma, suggesting that the metamorphism occurred at ≥ 209 Ma. Thus, the A?vanis metamorphic rocks represent the vestiges of the Late Triassic or slightly older subduction in northeast Turkey. Estimated P–T conditions indicate higher temperatures than those predicted by steady state thermal models for average subduction zones, and can best be accounted for by a hot subduction zone, similar to the present‐day Cascadia. Contact metamorphic mineral assemblages around an Early Eocene quartz diorite stock, on the other hand, suggest that the present‐day erosion level was at depths of ～14 km during the Early Eocene, indicative of reburial of the metamorphic rocks. Partial disturbance of white‐mica Ar–Ar age spectra was probably caused by the reburial coupled with heat input by igneous activity, which is probably related to thrusting due to the continental collision between Eastern Pontides and the Menderes–Taurus Block.     

中国东部中生代岩浆岩的时空分布及其与热液型铀矿的关系

中国东部中生代岩浆活动强烈,热液型铀矿分布广泛。空间上,自北而南可划分出大兴安岭、小兴安岭-长白山、冀北-辽西、大别山北缘、长江中下游、扬子陆块东南缘、武夷-云开、东南沿海8个火山-侵入岩带和沽源-红山子、青龙-兴城、庐枞-栖霞、赣杭、武夷山、桃山-诸广、郴州-钦州、湘中、雪峰山-摩天岭9个热液型铀成矿带以及满洲里-额尔古纳、扎兰屯、伊春、金寨、天目山5个铀成矿远景带;时间上,从早到晚可划分出250~230Ma、228~205Ma、195~175Ma、165~150Ma、145~130Ma、126~115Ma、110~100Ma、97~80Ma 8个不同时期的岩浆活动和早期深源高温、晚期浅源低温两个成矿系统,深源高温成矿系统可划分出11个矿床式,浅源低温成矿系统可划分出15个矿床式。勘查成果显示,热液型铀矿对岩浆岩的岩性岩相没有选择性,但与特定时期的岩浆岩有密切的关系,其中与花岗岩有关的热液型铀矿主要赋存在三叠纪花岗岩中,与火山岩有关的热液型铀矿主要赋存在早白垩世早期高钾钙碱性流纹岩-碱性粗面岩组合中,而且晚期高侵位小岩体或火山斑岩体的内、外接触带是有利的赋矿部位。     

更新世以来南海表层水温变化及其古气候意义

南海南部2Ma以来古温度记录显示该海域更新世以来海水表层温度的不断降低,并且以冰期降低为特征,间冰期温度变化不大。南海南北经向表层海水温差的大小,反映了东亚冬季风的强弱变化,2 Ma以来的温差变化说明东亚冬季风在中更新世之前的持续强化,中更新世之后不断减弱,而在晚第四纪时又再次转为增强,同时叠加在长期变化趋势之上的是轨道时间尺度上冰期增强间冰期减弱的循环波动。青藏高原构造作用可能对中更新世时期东亚冬季风强化产生重要影响,而更新世以来东亚冬季风变化的整体趋势及轨道尺度变化主要受全球冰量变化和低纬ENSO影响。     

东喜马拉雅构造结泥质高压麻粒岩的锆石和独居石定年与地质意义

东喜马拉雅构造结的南迦巴瓦杂岩含有广泛分布的高压麻粒岩,但由于以前获得了许多不同的年龄,对这些麻粒岩的变质与深熔时代、持续时间和成因存在不同认识。本文对泥质高压麻粒岩（蓝晶石榴黑云片岩）中的锆石和独居石进行了系统的内部结构、U-（Th）-Pb定年和微量元素分析,以求揭示这些岩石是否具有相同的演化过程。所研究的6个蓝晶石榴黑云片岩由石榴石、蓝晶石、黑云母、石英、钾长石、斜长石、夕线石、白云母、石墨和副矿物金红石、钛铁矿、锆石和独居石组成,峰期矿物组合是石榴石+蓝晶石+斜长石+钾长石+黑云母+石英+金红石。6个样品中的锆石均由继承碎屑核+变质（深熔）幔+变质（深熔）边组成。其中3个样品中的锆石幔和边较宽,均可进行原位定年,幔部给出了类似的较老年龄范围（39.6~31.6Ma、40.8~32.0Ma和38.1~31.3Ma）,而边部给出了类似的较年轻年龄范围（26.8~17.3Ma、28.3~18.6Ma和28.4~18.8Ma）。另外3个样品的锆石幔部较窄,不能进行分析,其边部给出了与前3个样品锆石边部类似的年轻年龄范围（22.0~17.0Ma、20.9~16.9Ma和22.2~16.6Ma）。一个片岩样品中的独居石给出了与其锆石幔部+边部年龄类似的较宽年龄范围（38.1~17.5Ma）,而另外3个样品中的独居石获得了与其锆石边部年龄相似的年轻年龄范围（26.0~18.8Ma、22.3~16.9Ma和26.4~19.4Ma）。随着年龄的减小,锆石和独居石的Th/U比值增大,Eu/Eu^*减小,独居石的HREE和Y含量减小。基于这些分析结果,笔者认为所研究的6个片岩记录了相同的、从~41Ma持续到~17Ma的进变质与深熔过程。但是,由于某些样品中的锆石和独居石在早期变质和深熔过程中形成的结晶域（锆石幔部）很窄,无法定年,导致不同的样品获得了不同的年龄范围。结合现有研究成果,笔者推测南迦巴瓦杂岩中的高压麻粒岩经历了相似的长期进变质与深熔过程。     

新疆东准噶尔老鸦泉富碱花岗岩型锡矿床地质及成矿流体

老鸦泉碱性花岗岩位于新疆北部东准噶尔地区。老鸦泉碱性花岗岩体及其内卡姆斯特、干梁子锡矿床的矿石和岩石的岩矿鉴定、稀土元素以及流体包裹体的系统研究表明,老鸦泉碱性花岗岩及其内的花岗斑岩及含矿石英岩、云英岩化锡矿体、石英脉锡矿体,实际上是富碱花岗质岩浆逐渐分异演化的同源和最终产物,锡成矿流体为中-高温、低盐度。碱性岩浆晚期分异的大量气水热液富锡、富硅、富碱、富含F、Cl、SO²₄离子及离子团,其氧逸度高、酸度高、温度高,这种热液引起花岗岩体的硅化、云英岩化等自变质作用,在该作用中随温度、压力的降低及CH₄等还原性气体及CO₂气体的逃逸,改变了成矿流体的氧化-还原环境,流体向相对还原及碱性条件转化,在新的氧化还原、酸碱度界面条件下,其携带的锡的络合物不稳定而分解,锡沉淀成矿。     

NUMERICAL SIMULATION OF SSTA IMPACTS UPON THE INTERDECADAL VARIATION OF THE CROSS-EQUATORIAL FLOWS IN EASTERN HEMISPHERE

Impacts of regional sea surface temperature(SST)anomalies on the interdecadal variation of the cross-equatorial flows(CEFs)in Eastern Hemisphere are studied using numerical simulations with a global atmospheric circulation model(NCAR CAM3)driven with 1950-2000 monthly SSTs in different marine areas(the globe,extratropics,tropics,tropical Indian Ocean-Pacific,and tropical Pacific)and ERA-40reanalysis data.Results show that all simulations,except the one driven with extratropical SSTs,can simulate the interdecadal strengthening of CEFs around Somali,120oE,and 150oE that occurred in the midand late-1970s.Among those simulated CEFs,the interdecadal variability in Somali and its interdecadal relationship with the East Asian summer monsoon are in better agreement with the observations,suggesting that changes in the SSTs of tropical oceans,especially the tropical Pacific,play a crucial role in the interdecadal variability of CEFs in Somali.The interdecadal change of CEFs in Somali is highly associated with the interdecadal variation of tropical Pacific SST.As the interdecadal warmer(colder)SST happens in the tropical Pacific,a"sandwich"pattern of SST anomalies,i.e."+,-,+"("-,+,-"),will occur in the eastern tropical Pacific from north to south with a pair of anomalous anticyclone(cyclone)at the lower troposphere;the pair links to another pair of anomalous cyclone(anticyclone)in the tropical Indian Ocean through an atmospheric bridge,and thus strengthens(weakens)the CEFs in Somali.     

Geochemical Eccentricity of Ground Water Allied to Weathering of Basalts from the Deccan Volcanic Province,India: Insinuation on CO<Subscript>2</Subscript> Consumption

Analyses of 72 samples from Upper Panjhara basin in the northern part of Deccan Plateau, India, indicate that geochemical incongruity of groundwater is largely a function of mineral composition of the basaltic lithology. Higher proportion of alkaline earth elements to total cations and HCO₃>Cl + SO₄ reflect weathering of primary silicates as chief source of ions. Inputs of Cl, SO₄, and NO₃ are related to rainfall and localized anthropogenic factors. Groundwater from recharge area representing Ca + Mg–HCO₃ type progressively evolves to Ca + Na–HCO₃ and Na–Ca–HCO₃ class along flow direction replicates the role of cation exchange and precipitation processes. While the post-monsoon chemistry is controlled by silicate mineral dissolution + cation exchange reactions, pre-monsoon variability is attributable chiefly to precipitation reactions + anthropogenic factors. Positive correlations between Mg vs HCO₃ and Ca + Mg vs HCO₃ supports selective dissolution of olivine and pyroxene as dominant process in post-monsoon followed by dissolution of plagioclase feldspar and secondary carbonates. The pre-monsoon data however, points toward the dissolution of plagioclase and precipitation of CaCO₃ supported by improved correlation coefficients between Na + Ca vs HCO₃ and negative correlation of Ca vs HCO₃, respectively. It is proposed that the eccentricity in the composition of groundwater from the Panjhara basin is a function of selective dissolution of olivine > pyroxene followed by plagioclase feldspar. The data suggest siallitization (L < R and R _k) as dominant mechanism of chemical weathering of basalts, stimulating monosiallitic (kaolinite) and bisiallitic (montmorillonite) products. The chemical denudation rates for Panjhara basin worked out separately for the ground and surface water component range from 6.98 to 36.65 tons/km²/yr, respectively. The values of the CO₂ consumption rates range between 0.18 × 10⁶ mol//km²/yr (groundwater) and 0.9 × 10⁶ mol/km²/yr (surface water), which indicates that the groundwater forms a considerable fraction of CO₂ consumption, an inference, that is, not taken into contemplation in most of the studies.     

Fractionation of phosphorus in the sediments of a tropical estuary

Fractionation of phosphorus in the sediments of the Cochin estuary situated along the southwest coast of India was studied by applying sequential chemical extraction. The different forms of phosphorus were estimated seasonally (premonsoon, monsoon, and postmonsoon) under eight different schemes. The major forms of phosphorus analyzed were exchangeable P, anion exchangeable P, carbonate-bound P, labile and resistant organic P, Fe and Al P, calcium-bound P, and hydrolyzable surplus P. Quantitatively, the above fractions in isolation or in combination vary in content due to chemoestuarine variability and seasonal fluctuations. Changes in speciation have been noted in association with salinity variations in the waterway, especially following enhanced river runoff during the monsoon. The chemical forms of the sediment-bound phosphorus in the northern parts of this estuary have been shown to be modified by nonpoint sources. Sediment P fractionation defines the role of chemical speciation of phosphates (as nutrients) and is indicative of the processes controlling the pathways of P into the coastal waters. The changes in the exchangeable P, together with marked regional variations in calcium-bound P, exemplify the complex estuarine variability of phosphorus. Enhanced amounts of exchangeable P mark its appearence in high saline waters, signifying the presence of biologically available nutrient phosphorus. The calcium-bound P and hydrolyzable surplus P show significant relation with sediment organic carbon and Fe whereas other forms do not exhibit any marked covariation. The Ca and Na NTA extraction scheme is very specific in its selectivity.     

GEOCHRONOLOGY OF ~(Ar)/~(39)Ar DATING IN THE BASEMENT ROCKS IN EASTERN KUNLUN MOUNTAINS AND ITS TECTONIC IMPLICATIONS

GEOCHRONOLOGY OF ~(Ar)/~(39)Ar DATING IN THE BASEMENT ROCKS IN EASTERN KUNLUN MOUNTAINS AND ITS TECTONIC IMPLICATIONS     

Fractal analysis of quartz grain boundary sutures in a granite (Malanjkhand,Central India) — Implications to infer regional tectonics

In the present paper the intensity of serration of quartz grain boundary sutures in the Palaeoproterozoic age Malanjkhand granite (Central India) is quantified using the ruler method of fractal analyses. The northern margin of the granite has proximity to the Central Indian Suture (CIS) that forms the southernmost part of Central Indian Tectonic Zone (CITZ) along which amalgamation of the northern and southern Indian shields took place. The fractal dimension (D) of the quartz sutures is calculated in 13 samples collected at varying distance from the CIS. D values are noted to increase in samples towards the CIS. This demonstrates the influence of the tectonic events along the CIS on fabric development in the Malanjkhand granite. Magmatic fabric defined by preferentially oriented feldspar laths and high-T solid-state deformation fabrics are observed in areas distant from the CIS. In contrast, mylonites and low-T fabrics such as bulging quartz grain boundaries occur in proximity to the CIS. It is inferred that the emplacement and high-T fabric development in the Malanjkhand granite was synchronous with regional accretionary processes that occurred in the region during the Palaeoproterozoic. Two different possibilities, one involving a single tectonic event and the other involving multiple tectonic events are discussed to explain the superimposition of low-T over high-T fabric due to which intensity of quartz grain boundary serration increases towards the CIS.