济阳坳陷桩海地区中生界同位素年代地层学研究

济阳坳陷中生界分布广泛,具有油气成藏的基本地质条件,并取得了一定的勘探发现,但其勘探程度和研究程度相对较低,包括地层划分、沉积体系、储层特征、控藏因素等。特别是地层时代、分层与分界等基本的地质问题尚存在不同的观点和认识。根据区内14口井的10个火山岩全岩样品和79个小于2μm的泥岩自生伊利石样品,开展K-Ar法同位素年代地层学测定,分别确定了中生界的坊子组、蒙阴组、三台组和西洼组的绝对年龄值,将坊子组划归下侏罗统,蒙阴组为中侏罗统,缺失上侏罗统,并明确了各组的接触关系。     

Magmatic activity and its geological significance in Early Jurassic in Mangui area of Inner Mongolia

By investigating the U-Pb zircon isotope geochronology and petrogochemistry of the major magmatic rocks in Mangui area, the authors in this paper discussed the forming era, tectonic background and geological significance. A large amount of intrusive rocks and a small amount of medium-acid volcanic rocks in Early Jurassic were found in this area. U-Pb dating by LA-ICP-MS method shows that the ages are from (199±1)Ma to (184±1)Ma and the rock types can be divided into fine-medium-grained quartz diorite, medium-grained granodiorite, fine-medium-grained monzogranite, medium-fine-grained macrophenocryst monzogranite, rhyolite, dacite and andesite, which didn’t ouur in Neoprotezoic-Paleozoic period as previous researchers thought, revealing the tectonic and magmatic activities during the Early Mesozoic period. The geochemical results show that the rocks are Ⅰ-type magmatic rocks of subluminous-peraluminous high-K calc-alkaline series. The fractionation between light and heavy rare-erath elements((La/Yb)_N= 3.42~32.96) and the Eu depletion degree is not complied with the evaluation from basic to acidic. The large ion lithophile element Ba is relatively rich and Rb, Sr are relatively delicient. The high field strength elements Th and U are relatively rich and Nb, Ti, Y are relatively deficient. The magma origin and tectonic setting show that quartz diorite and medium-fine-grained macrophenocryst monzogranite come from crust-mantle mixed magma, while the medium-acid volcanic rocks, granodiorite and fine-medium-grained monzogranite are from the partial melting of crustal materials, whose formation is connected with the evolution of Mongol-Okhotsk Suture Zone. The geology and geochemistry of the Early Mesozoic magmatic rocks indicate that the middle part of Mongol-Okhotsk Ocean might begin subduction at the end of the middle Triassic and close the Early Jurassic. The peak collision might take place at the Early Jurassic, not in the Late Triassic as previous thought. The Mohe over-thrust nappe system might form in the remote effect of southward extrusion during the closing process of the eastem part of Mongol-Okhotsk Ocean. The middle and eastern Mongol-Okhotsk Ocean closing age is of great importance to reveal the basin-range tectonic formation during the Middle Jurassic to the Late Cretaceous in Northeast China.     

Age of Gimli beach of Lake Agassiz based on new OSL dating

Gimli beach in Manitoba is one of the lowest elevation beaches in the southern Lake Agassiz basin, and is a distinct ridge composed of bedded sand and gravel that rises above the lake plain and extends for more than 40 km. Ten new optically stimulated luminescence (OSL) ages from Gimli beach yield ages mostly ranging from 9.7 ± 0.7 to 10.5 ± 0.8 ka (average 10.3 ± 0.5 ka), which is older by 0.6 to >1.0 ka than age estimates of previous researchers. Two of our new OSL ages are notably older than the others, dating to ~11.3 ± 0.8 and 13.9 ± 1.0 ka, which we attribute to poorly bleached sands. We ascribe an age of about 10 ka to Gimli beach, which is several centuries before overflow from Lake Agassiz and its vast drainage basin shifted from the western Great Lakes to glacial Lake Ojibway and the St. Lawrence Valley.     

Geochronology and geochemistry of the Hekoulinchang Sn-Pb-Zn-Ag polymetallic deposit (73240 t) in Heilongjiang Province,China

The Hekoulinchang Sn-Pb-Zn-Ag polymetallic deposit(20000 t Sn at 0.27%,236 t Ag at 122.89 g/t,15000 t Pb at 0.84%,and 38000 t Zn at 1.43%)is located in the Wandashan Terrane of the easternmost segment of the Central Asian Orogenic Belt.The timing of Sn-Pb-Zn-Ag polymetallic mineralization remains unclear due to a lack of precise isotope dating directly conducted on ore minerals.The authors herein report that the LA-ICP-MS U-Pb ages of cassiterite and zircon from the granite porphyry in the Hekoulinchang Sn-Pb-Zn-Ag polymetallic deposit are 101.4±7.9 Ma and 115.4±1.0 Ma,respectively,indicating that Sn mineralization and magmatism occurred during the Early Cretaceous.The granite porphyry belongs to the subalkaline series peraluminous I-type granites that are depleted in Nb,Ta,and Ti and enriched in Rb,Th,U,and Pb.TheεHf(t)values of the granite porphyry range from 0.9 to 7.4,with an average of about 5.6 and two-stage model ages(T_DM2)of 705–1116 Ma,with an average age of 819 Ma.The ε_Nd(t)values of the apatites are–1.60–0.45,with an average of–0.9,and two-stage model ages(T_DM2)of 872–1040 Ma,with an average age of 983 Ma.The Nd-Hf isotope data indicate that the magma may have been derived from the partial melting of juvenile crustal material.     

桂东北均洞花岗岩体的锆石U-Pb年龄、地球化学特征及其构造意义

均洞花岗岩体出露于钦杭结合带西南部,对揭示桂东北构造演化具有重要意义,其岩石组合为石英黑云母闪长岩、黑云母二长花岗岩和黑云母二长岩.文章运用LA-ICP-MS锆石U-Pb测年方法,获得均洞岩体的结晶年龄为423～430 Ma,为加里东期造山作用的产物.均洞岩体的SiO2含量较低(55.47～62.95 wt％);其中一...     

难熔元素和代表性放射性同位素体系分析技术的进展、问题和应用展望

Pt-Os、Re-Os和Hf-W同位素体系的母体和子体Pt、Os、Re、Hf和W以及其它铂族元素（PGE）化学性质上都是难熔的,我们将这些元素和相关同位素称为难熔元素和难熔元素放射性同位素体系。难熔元素及其放射性同位素体系不仅可以直接测定金属矿床、油气藏和沉积岩系的年龄,而且还可以有效示踪地球深部的核幔反应等过程,这是其它地球化学工具不可替代的。本文评述了当前Pt-Os、Re-Os和Hf-W同位素体系和PGE元素分析技术的研究进展,指出：（1）目前Re-Os同位素定年误差仍较大,迫切需要优化改进分析技术,大幅提高Re-Os同位素定年的准确度和成功率;（2）Pt-Re-Os和W同位素的分析技术需要简化繁琐的化学分离流程和提高仪器分析的效率,同时探索建立新的化学分离和仪器分析方法,进一步提高分析精度,实现对更低Pt、Re、Os和W含量样品的准确分析,才能更有效地示踪地球深部物质循环过程;（3）PGE的元素分析技术尚需改进,分析精度仍需要进一步提升。我们预期随着进一步提升难熔元素和代表性放射性同位素的分析精度,显著降低同位素定年误差,其将在核-幔、幔-幔和壳-幔物质循环过程示踪、金属矿床精细定年和成因机制、复杂含油气系统的定年和示踪以及中元古代环境变化等研究中得到更广泛的应用。

     

格陵兰岛西南部Nassaq地区辉钼矿Re-Os年龄及意义

格陵兰矿产资源丰富,种类繁多,目前已探明的金属矿点(床)有800多个,具有巨大的找矿潜力,世界主要矿业公司多数对格陵兰的找矿与开发表现出积极态度。因此,选择典型地区开展深入研究对进一步找矿有重要的理论指导意义。格陵兰西南部的那萨克(Nassaq)地区交通较为便利,本文在对该地区系统的野外地质特征研究基础上,采集了含辉钼矿斜长角闪岩样品,并从中选择代表性样品,进行辉钼矿Re-Os年代学研究,为其成矿作用及相关问题的研究提供基本依据。该地区辉钼矿的形成年龄为2553 Ma,为新太古界末期的产物,其矿化是Qorqut花岗岩侵入时(2550Ma)所形成,在格陵兰西南部应重视Qorqut花岗岩有关的辉钼矿的找矿与评价工作。     

北秦岭德河黑云二长花岗片麻岩体的成岩时代--TIMS和SHRIMP锆石U-Pb同位素年代学

德河黑云母二长花岗片麻岩体侵位于秦岭造山带北秦岭前寒武纪变质岩系内,遭受了强烈的变形作用改造,具有典型S型花岗岩的矿物组成特征。TIMS和SHRIMP法锆石U-Pb同位素年龄测定结果分别为(964.4±5.2)Ma和(943±18)Ma,两者在误差范围内是一致的。鉴于SHRIMP法锆石微区测年具有更好的代表性,建议以(943±18)Ma代表德河黑云母二长花岗片麻岩的侵位时代。     

晚第四纪MIS6以来柴达木盆地成盐作用对冰期气候的响应

气候是控制柴达木盆地盐类沉积的主要因素之一,但是其作用机制尚待明确。作者以柴达木盆地察汗斯拉图盐湖的3个含盐剖面为研究对象,采用多接收电感耦合等离子质谱(MC-ICP-MS)铀系测年测定其沉积时代,并通过X射线粉晶衍射(XRD)分析测定其盐类矿物种类。铀系测年显示D18剖面石盐和芒硝层的沉积时代为13.1±2.0 ka BP～15.9±2.5 ka BP,其中芒硝沉积年代属于末次冰期MIS2晚期;MXK2剖面芒硝层的沉积时代分别为131.7±39.5 ka BP和158.3±10.8 ka BP,D12剖面芒硝层的沉积时代分别为166.6±20.2 ka BP和198.0±20.6 ka BP,可以对应于倒数第二次冰期MIS6。XRD分析确定了3个剖面的盐类矿物主要为芒硝、石盐和石膏。综合多个盐湖晚第四纪成盐数据,本文认为倒数第二次冰期MIS6和末次冰期MIS2是柴达木盆地晚第四纪重要的成盐期,冰期的冷干气候有利于石盐和芒硝等盐类沉积。柴达木盆地"冰期成盐"的根本原因,是由于冰期环境下盆地周边山体冰川规模的扩张以及干冷的冰期气候,共同造成了盐湖补给水量的减少。此外,晚第四纪MIS6和MIS2的冰期降温也是导致盆地中冷相盐类沉积的直接原因。