元古代蛇绿岩及铬铁矿

本文总结了国外典型元古代蛇绿岩的岩石组合、野外产状、地球化学资料以及成矿特征,并与显生宙蛇绿岩进行了对比,继而探讨元古代板块构造演化和铬铁矿成因。资料表明,早元古代和中-新元古代均有蛇绿岩的存在,但前者较少,仅见于Canadian地盾的Cape Smith Belt中的Prutuniq蛇绿岩(2. 05～2. 0Ga)和芬兰Fennoscandian地盾的Outokumpu和Jormua蛇绿岩(时代为1. 97～1. 96Ga),而中-新元古代的蛇绿岩则见于世界许多地区,如埃及东部沙漠区(～750Ma)和非洲东北部地区(ca.900～800Ma)等。与显生宙蛇绿岩相比,这些老蛇绿岩具如下特征:(1)它们均为被肢解的蛇绿岩,大多与"弧火山岩"和(或)混杂岩伴生,经历不同程度的变形和变质(具绿片岩相-角闪岩相组合);(2)岩石组合大多较齐全,壳层组合发育,以镁铁-超镁铁岩(堆晶岩)、辉长岩、镁铁质席状岩床(墙)杂岩、火山岩为代表;层状镁铁-超镁铁岩的韵律层以及矿物的隐晶变化等均提示了岩浆多期次活动及开放岩浆房的特征;(3)元古代蛇绿岩中既有高铝型铬铁矿,也有高铬型铬铁矿,且主要寄主于纯橄岩(或蛇纹岩)中;高铝型和高铬型直接受控于熔体的熔融程度及含水流体的参与,反映了铬铁矿形成于俯冲带演化的不同阶段;铬铁矿规模均较小,且均以低TiO 2为特征,均为岩浆分异作用的产物,明显区别于显生宙熔融残余成因的豆荚状铬铁矿;(4)元古代蛇绿岩常伴有硫化物Cu-Co-Zn-Au矿,且铬铁矿含Zn较高(Zn=0. 11%～0. 18%)(如芬兰Outokumpu蛇绿岩);橄榄岩及铬铁矿中常含较高的MnO (高达1. 79%,如埃及东部的Wizer蛇绿岩);(5)元古代蛇绿岩具多种成因:主要为俯冲带成因(如埃及蛇绿岩、北东非蛇绿岩、芬兰Outokumpu蛇绿岩),少量为洋中脊成因(加拿大Purtuniq蛇绿岩)及裂谷成因(芬兰Jormua蛇绿岩)等。     

西藏多龙矿集区硅质岩岩石地球化学、Si- O同位素特征及其构造意义

多龙矿集区位于班公湖-怒江成矿带西段、羌塘地体南缘。本文通过对多龙矿集区出露的硅质岩进行系统地球化学研究,探讨硅质岩形成的沉积环境及成因。多龙硅质岩SiO_2含量为92.83%～93.97%,属于纯硅质岩;Si/Al值为48.98～49.56,MnO/TiO_2值为0.36～0.64,Al_2O_3/(Al_2O_3+Fe_2O_3)值为0.77～0.81;硅质岩ΣREE为30.83×10~(-6)～34.59×10~(-6),LREE/HREE值为6.71～6.93,球粒陨石标准化曲线为Eu负异常而Ce弱正异常的右倾型曲线,北美页岩标准化曲线为Eu和Ce均显示出弱正异常的平坦型曲线;微量元素均严重亏损,仅Cu、Pb等亲铜元素亏损幅度较对较弱,V值为7.83×10~(-6)～8.84×10~(-6),V/Y值为1.25～1.48,亦表明硅质岩形成的环境海底热液活动不强烈,沉积环境为大陆边缘环境。多龙硅质岩δ~(30) Si_(NBS-28)值为1.0‰～1.1‰,δ~(18) O_(V-SMOW)‰为20.3‰～20.8‰,表明多龙硅质岩为浅海环境中沉积形成的原生的生物成因硅质岩。综合分析认为,多龙硅质岩形成于中晚侏罗世-早白垩世早期,为形成于对稳定的洋盆闭合的大陆边缘沉积环境的生物成因硅质岩,暗示南羌塘地体南缘于中晚侏罗世-早白垩世早期处于陆缘弧环境,班公湖-怒江洋仍在北向俯冲消减,洋盆尚未完全闭合。     

西藏多龙矿集区典型矿床(点)矿化特征与成矿作用对比研究

西藏多龙矿集区是近年来中国新发现的具有世界级潜力的铜金矿集区。该矿集区现已查明多不杂、波龙、拿若和铁格隆南4个大型-超大型矿床,并新发现地堡那木岗和拿顿矿点。文章对上述矿床(点)脉体、蚀变、矿化和流体特征开展了系统研究和对比。结果表明,多不杂、波龙和拿若矿床矿化类型以斑岩型为主,同时钾硅酸盐化、绢英岩化、青磐岩化等蚀变广泛发育,而铁格隆南矿床除上述蚀变类型外,还叠加有高级泥化蚀变,并发育与之相关的浅成低温热液型矿化。根据脉体特征对比和流体包裹体温压计算推测,上述4个矿床矿化类型的差异可能由剥蚀深度的差异所引起(前三者剥蚀深度约为2～3 km,后者约为1～1.5 km)。此外,地堡那木岗矿点蚀变类型以绢英岩化、泥化为主,该矿点发育与斑岩型金矿中类似的深色条带状石英脉,指示该地区可能存在斑岩型金矿。拿顿矿点为典型的高硫型浅成低温热液型矿化,铜金矿体赋存于角砾岩筒中。野外地质调查表明,上述矿点地表蚀变岩盖(Lithocaps)发育,并且蚀变岩盖空间分布位置与下伏铜金矿体表现出良好的匹配关系,可有效地指导找矿勘查工作。流体包裹体实验进一步表明,铜金元素在斑岩型矿化中的沉淀可能与温度降低和氧逸度的变化有关,而在浅成低温热液型矿化中的沉淀则受控于温度的降低和流体的不混溶作用。最后,在前人年代学研究基础上,结合本次实验结果构建了该地区与成矿作用有关的时空演化模型。     

西藏多龙矿集区水系沉积物地球化学数据定量分析与解释

位于西藏改则县的多龙矿集区是班公湖—怒江结合带最重要的斑岩型铜-金产地,具有较大的找矿潜力。本文利用MML-EM算法(Minimum Message Length-Expectation Maximization Algorithm)和ILR变换(Isometric Log-Ratio Transformation)为基础的主成分分析定量研究多龙矿集区水系沉积物化探数据的统计分布规律。混合分布筛分结果表明,Cu、Pb、Zn、Cr、Ni、Mn、Ag、Sn、W、Mo、As、Sb、Bi、Hg和Au的元素含量都服从包含两个对数正态分布的混合分布。大部分元素的高均值子分布反映了该地区多期次岩浆或热液活动。通过作ILR变换(Isometric Log-Ratio Transformation),消除了多龙地区化探数据的闭合效应,第一主成分的元素组合指示该地区的铜-金成矿潜力。多龙地区大部分铜-金矿床(点)和地表蚀变落在第一主成分得分较高的区域。根据第一主成分的得分,本文圈定了若干个成矿潜力较大的靶区。     

Geological and mineralogical study of eclogite and glaucophane schists in the Naga Hills Ophiolite,Northeast India

A variety of low‐ to high‐pressure metamorphic assemblages occur in the metabasic rocks and metachert in the Upper Cretaceous–Eocene ophiolite belt of the central part of the Naga Hills, an area in the northern sector of the Indo–Myanmar Ranges in the Indo–Eurasian collision zone. The ophiolite suite includes peridotite tectonite containing garnet lherzolite xenoliths, layered ultramafic–mafic cumulates, metabasic rocks, basaltic lava, volcaniclastics, plagiogranite, and pelagic sediments emplaced as dismembered and imbricated bodies at thrust contacts between moderately metamorphosed accretionary rocks/basement (Nimi Formation/Naga Metamorphics) and marine sediments (Disang Flysch). It is overlain by coarse clastic Paleogene sediments of ophiolite‐derived rocks (Jopi/Phokphur Formation). The metabasic rocks, including high‐grade barroisite/glaucophane‐bearing epidote eclogite and glaucophane schist, and low‐grade greenschist and prehnite–clinochlore schist, are associated with lava flows and ultramafic cumulates at the western thrust contact. Chemically, the metabasites show a low‐K tholeiitic affinity that favors derivation from a depleted mantle source as in the case of mid‐ocean ridge basalt. Thermobarometry indicates peak P–T conditions of about 20 kb and 525°C. Retrogression related to uplift is marked by replacement of barroisite and omphacite by glaucophane followed by secondary actinolite, albite, and chlorite formation. A metabasic lens with an eclogite core surrounded by successive layers of glaucophane schist and greenschist provides field evidence of retrogression and uplift. Presence of S‐C mylonite in garnet lherzolite and ‘mica fish’ in glaucophane schist indicates ductile deformation in the shear zone along which the ophiolite was emplaced.     

南天山榆树沟遭受麻粒岩相变质改造的蛇绿岩套研究

 新疆南天山榆树沟高压麻粒岩地体的原岩是一层序基本完整的蛇绿岩套。该岩套主要由变质橄榄岩、超镁铁质-镁铁质堆晶岩、下部洋脊拉斑玄武岩、以及上部洋脊拉斑玄武岩等四个岩石单元构成。其岩石学和REE与相对惰性微量元素的地球化学特征表明,该蛇绿岩中的玄武岩属洋脊型;结合区域地质背景分析,初步认为榆树沟蛇绿岩可能形成于具相当规模的洋盆构造环境。锆石U-Pb年龄表明其形成时代为早古生代中晚期,证实西南天山早古生代蛇绿岩确已延伸至库米什一带。榆树沟麻粒岩相蛇绿岩套的确定以及对其独特的形成和俯冲-折返过程进行深入研究,不仅对进一步探讨天山构造带的形成和演化有重要意义,而且对发展大陆动力学理论也具重要参考价值。     

Petrology of an ophiolitic cumulate sequence from Pindos,Greece

The ophiolitic sequence which crops out along the Aspropotamos Valley, Northern Pindos, Greece is composed from the bottom to the top of cumulates, dolerites, basaltic lavas, upper pillow lavas with basaltic/andesitic composition, and scarce basaltic dykes. The intrusive sequence, which is the subject of the present paper, exhibits magmatic layering more pronounced at the bottom than at the top where isotropic gabbros occur; they grade into the overlying dolerites. Troctolites with rare ultramafites prevail in the lower section and olivine gabbros in the upper section; at the top two-pyroxene gabbros appear. The rocks are mainly adcumulates and mesocumulates with subordinate heteradcumulates. The cumulus phases separated in the order: olivine and Cr-spinel, plagioclase, clinopyroxene, orthopyroxene. Olivine, plagioclase and pyroxenes frequently exhibit adeumulus overgrowth. Intercumulus phases may be plagioclase, clinopyroxene, orthopyroxene, pale brown amphibole and magnetite. Where pore material is present, it is composed of plagioclase, clinopyroxene, orthopyroxene, hornblende and ores. Cr-spinel occurs mainly at the bottom of the sequence (Cr₂O₃ between 30·5 and 39·8 per cent), while magnetite appears as a very rare phase in the upper section. Olivine, orthopyroxene, clinopyroxene exhibit slight cryptic variation (Mg × 100/(Mg + Fe) in the range 90–79, 90–70, 93–72 respectively). The investigated dolerites are non-cumulus rocks where clinopyroxene may be more magnesian than in the uppermost gabbros. The cumulate sequence and dolerites underwent variable but generally slight spilitization, in contrast to the overlying lavas. The sequence was generated through crystal accumulation probably from periodic pulses of tholeiitic magma; newly injected magma batches mixing with magma fractions already differentiated in the magma chamber. The high fluid pressure evidenced by the fluid inclusions in plagioclase and the whole chemical trend of the cumulate sequence are consistent with a genesis above a subduction zone, as already hypothesized for the overlying lavas.     

青藏高原两个斑岩-浅成低温热液矿床成矿亚系列及其"缺位找矿"之实践

斑岩_浅成低温热液型铜金矿床是西藏最新发现的组合矿床类型,其具有巨大的找矿潜力。笔者在西藏多龙矿集区铁格隆南铜金矿床、雄村矿集区主要矿体系统地质编录、综合研究的基础上,对其矿床地质背景、矿体形态产状、矿物组合、蚀变特征、成岩成矿年龄等进行了系统的总结,在前人研究的基础上,提出班怒成矿带与早白垩世岛弧型中_酸性火山岩_浅成岩组合有关的铜、金、银、铅锌矿床成矿亚系列,以及冈底斯成矿带与早侏罗世—晚侏罗世岛弧型中_酸性火山岩_浅成岩组合有关的铜、金、银、铅锌矿床成矿亚系列,是西藏最重要的寻找斑岩型_浅成低温热液型铜金矿的矿床成矿系列。依据"缺位找矿"理论,预测多龙矿集区尕尔勤、地堡那木岗、铁格隆山是浅成低温热液型铜金矿床的进一步勘查评价区,色那、拿顿角砾岩筒是寻找独立高硫化型浅成低温热液金矿床的重要靶区。铁格隆南浅成低温热液矿体叠加在斑岩型矿体之上,高硫化型浅成低温热液矿床浅部发育多孔状硅帽和明矾石_地开石_高岭石蚀变组合,金属矿物以硫砷铜矿_铜蓝_蓝辉铜矿_黝铜矿_黄铜矿_斑铜矿_黄铁矿等铜硫二元体系矿物组合为主,其中黄铁矿_黄铜矿_斑铜矿形成较早,矿床规模可突破1200万吨。雄村铜金矿集区发育低硫化型浅成低温热液多金属金矿体,矿体呈脉状,或在火山机构边缘构造中独立产出,或叠加于斑岩型铜金矿体之上产出,以绢云母化、叶蜡石化、伊利石化发育,闪锌矿、黝铜矿、磁黄铁矿_黄铁矿为主要金属矿物组合为特征,洞嘎、普钦木_哑达是低硫化型浅成低温热液矿床的勘查评价区,深部有找到斑岩型铜金矿的可能。上述2套矿床成矿系列亚系列都与燕山期斑岩铜金矿床的流体演化有关,具有特殊的蚀变矿物、金属矿物组合,寻找独立的浅成低温热液型金矿是下一步需要重视的找矿方向。     

对新疆北部蛇绿岩及相关问题的思考和认识

蛇绿岩是作为大陆古板块划分及洋壳存在的重要佐证,同时也是许多地质问题争论的焦点之一。关于新疆北部地区大地构造单元的划分,尽管从不同理论、不同专业角度进行了许多研究和论述,但也因对区内蛇绿岩的认识不同而仍存在诸多争议。本文针对以区内蛇绿岩形成时代来确定洋盆出现所存在的一些可变因素的阐述,提出在新疆北部地区于震旦纪-石炭纪期间可能只存在一个水域相通的统一大洋～准噶尔-天山洋的认识。并以此为基点,对新疆北部地区的构造单元进行了初步划分,划分出两个被动陆缘带和三个弧盆带,同时将其构造演化概括为陆壳拉张(Z—C)、洋盆形成(O-S)及洋盆消减(D—C)三个阶段。     

祁连造山带玉石沟地幔橄榄岩中挥发分的流体化学和稳定同位素组成及古大洋岩石圈演化意义

Fluid inclusions in olivine and orthopyroxene of mantle peridotites from the Yushigou ophiolite can be divided into three types based on decrepitation temperature,shape and distribution.Type-1 fluid inclusions are characterized by oval or negative crystal shapes and small size(<5μm across).They occur in the cores and mantles of the host crystals,and decrepitated at>840℃.Type- 2 fluid inclusions have irregular or tabular shapes with relatively large size(10～100μm in length).They occur in irregular or circular healed micro-fractures in the host crystals,and decrepitated at 612～710℃.Type-3 fluid inclusions have size and shape,similar to type-2 fluid inclusions but occur in micro-fractures restricted to the margins of the host crystals,and decrepitated at much lower temperature from 190℃to 340℃.The three different types of fluid inclusions are interpreted to represent primary,metasomatic (pseudo-secondary)and secondary inclusions,respectively.Stepwise heating reveals three concentration peaks of volatiles at 200～400℃,400～800℃and 800～1200℃released from olivine and orthopyroxene in harzburgite and dunite from the Yushigou ophiolite, which are considered to correspond to the decrepitation of secondary,metasomatic and primary fluid inclusions at similar temperature ranges.CO2 is a major constituent in the volatiles released at three different temperature intervals.Trace amounts of H_2 and N_2 are present in the volatiles released at<800℃and trace amounts of H_2O and SO_2 are mainly present in the volatiles at 400～800℃.TheδD(-95.2‰,-306.3‰)of H_2O and theδ~(13)C(-15.5～-12.5‰)andδ~(18)O values(1.4～1.9‰)of CO_2 released at<800℃are lower than normal mantle values and suggest the mixing origin of crustal fluids( sedimentary organic)with ocean water,implying that Yushigou AOLM had undergone an intensive metasomatism by a fluid composed of CO_2.H_2O and SO_2,and followed by degassing. In contrast,the volatiles released at 800～1200℃are characterized by trace amounts of H_2 and CO in dunite and SO_2 in harzburgite, much lighterδ~(13)C(-29.1‰～-19.5‰),heavierδ~(13)O(8.8‰)of CO_2 and positive relationship between these isotopic ratios and the concentration of CO_2.Such features can be best explained by mixing of significant terrestrial crustal(organic)and minor mantle volatiles.We proposed that the Yishigou peridotites are more likely to have derived from a continental lithosphere instead of an oceanic lithosphere comprising the Yishigou gabbros and pillowed basalts.A supra-subduction tectonic setting is thus inferred for the Yushigou ophiolite.