A predictive numerical model for potential mapping of the gas hydrate stability zone in the Gulf of Cadiz

This paper presents a computational model for mapping the regional 3D distribution in which seafloor gas hydrates would be stable, that is carried out in a Geographical Information System (GIS) environment. The construction of the model is comprised of three primary steps, namely: (1) the construction of surfaces for the various variables based on available 3D data (seafloor temperature, geothermal gradient and depth-pressure); (2) the calculation of the gas function equilibrium functions for the various hydrocarbon compositions reported from hydrate and sediment samples; and (3) the calculation of the thickness of the hydrate stability zone. The solution is based on a transcendental function, which is solved iteratively in a GIS environment.The model has been applied in the northernmost continental slope of the Gulf of Cadiz, an area where an abundant supply for hydrate formation, such as extensive hydrocarbon seeps, diapirs and fault structures, is combined with deep undercurrents and a complex seafloor morphology. In the Gulf of Cadiz, the model depicts the distribution of the base of the gas hydrate stability zone for both biogenic and thermogenic gas compositions, and explains the geometry and distribution of geological structures derived from gas venting in the Tasyo Field (Gulf of Cadiz) and the generation of BSR levels on the upper continental slope.     

Distinct activity phases during the recent geologic history of a Gulf of Mexico mud volcano

Laser line scan imaging and chirp sub-bottom profiling were used to detail the morphology of a submarine mud volcano and brine-filled crater at 652 m water depth in the northern Gulf of Mexico. The mud volcano has a relief of 6 m and a basal diameter of about 80 m. The feature comprises a central, brine-filled crater (253 m²) surrounded by a continuous bed of methanotrophic mussels (Bathymodiolus childressi) covering 434 m² and a patchy bed covering an additional 214 m² of the periphery. The brine pool was mostly <2 m deep, but there were two holes of >28 m and 12 m deep, respectively at the northern end of the pool which emitted continual streams of small clear bubbles. Sub-bottom profiles indicated three distinct strata beneath the present surface of the mud volcano. Integration of 17 profiles shows that the mud volcano has been built in at least three successive stages: the lowest stage deposited 35,400 m³, while the middle and upper stages deposited 7700 and 20,400 m³, respectively. Piston cores were taken at the northern edge of the mussel bed and a site ∼100 m southwest of the pool. Mussel and lucinid shells were recovered from the closer core, lucinid shells from the distant core. A mussel shell from 3.4 m sub-bottom had a Δ¹⁴C age of 16.2 ka. Mixture of modern carbon with “carbon dead” reservoir material would produce actual ages ∼2 ka less than the radiocarbon ages.     

The thermal structure of the Dvurechenskii mud volcano and its implications for gas hydrate stability and eruption dynamics

The sediment temperature distribution at mud volcanoes provides insights into their activity and into the occurrence of gas hydrates. If ambient pressure and temperature conditions are close to the limits of the gas hydrate stability field, the sediment temperature distribution not only limits the occurrence of gas hydrates, but is itself influenced by heat production and consumption related to the formation and dissociation of gas hydrates. Located in the Sorokin Trough in the northern Black Sea, the Dvurechenskii mud volcano (DMV) was in the focus of detailed investigations during the M72/2 and M73/3a cruises of the German R/V Meteor and the ROV Quest 4000 m in February and March 2007. A large number of in-situ sediment temperature measurements were conducted from the ROV and with a sensor-equipped gravity corer. Gas hydrates were sampled in pressurized cores using a dynamic autoclave piston corer (DAPC). The thermal structure of the DMV suggests a regime of fluid flow at rates decreasing from the summit towards the edges of the mud volcano, accompanied by intermittent mud expulsion at the summit. Modeled gas hydrate dissociation temperatures reveal that the gas hydrates at the DMV are very close to the stability limits. Changes in heat flow due to variable seepage rates probably do not result in changes in sediment temperature but are compensated by gas hydrate dissociation and formation.     

Tectonically-driven mud volcanism since the late Pliocene on the Calabrian accretionary prism,central Mediterranean Sea

Mud volcanoes recently discovered on the offshore Calabrian Arc are investigated at two sites 60 km apart, in water depths of 1650--2300 m, using swath bathymetry, 2D&3D multichannel seismic and cores. The seabed and subsurface data provide information on their formation and functioning in relation to tectonic activity during the rapid Plio-Quaternary advance of the accretionary prism. Fore-arc extension and thrust-belt compression are seen to have involved two main phases of activity, separated by a regional unconformity recording a mid-Pliocene (3.5–3.0 Ma) tectonic reorganization. The two sites of mud volcanism lie in contrasting tectonic settings (inner fore-arc basin vs central fold-and-thrust belt) and record differing forms of seabed extrusive activity (twin mud cones and a caldera vs a broad mud pie). At both sites, subsurface data show that mud volcanism took place throughout the second tectonic phase, since the late Pliocene; differing forms of mud extrusion were accompanied by subsidence to form depressions beneath and within extrusive edifices up to 1.5 km thick. The basal subsidence depressions point to sources within the succession of thrusts underlying the inner to central Arc, consistent with microfossils within cored mud breccias from both sites that are derived from strata as old as Late Cretaceous.     

Scleractinian cold-water corals in the Gulf of Cádiz—First clues about their spatial and temporal distribution

This paper presents the first compilation of information on the spatial distribution of scleractinian cold-water corals in the Gulf of Cádiz based on literature research and own observations (video footage, sediment samples). Scleractinian cold-water corals are widely distributed along the Spanish and Moroccan margins in the Gulf of Cádiz, where they are mainly associated with mud volcanoes, diapiric ridges, steep fault escarpments, and coral mounds. Dendrophyllia cornigera, Dendrophyllia alternata, Eguchipsammia cornucopia, Madrepora oculata and Lophelia pertusa are the most abundant reef-forming species. Today, they are almost solely present as isolated patches of fossil coral and coral rubble. The absence of living scleractinian corals is likely related to a reduced food supply caused by low productivity and diminished tidal effects. In contrast, during the past 48 kyr scleractinian corals were abundant in the Gulf of Cádiz, although their occurrence demonstrates no relationship with main climatic or oceanographic changes. Nevertheless, there exists a conspicuous relationship when the main species are considered separately. Dendrophylliids are associated with periods of relatively stable and warm conditions. The occurrence of L. pertusa mainly clusters within the last glacial when bottom current strength in the Gulf of Cádiz was enhanced and long-term stable conditions existed in terms of temperature. Madrepora oculata shows a higher tolerance to abrupt environmental changes.     

CCSD HP-UHP变质岩石英脉和东海水晶中有机包裹体的发现及其意义

荧光显微镜下观察、激光拉曼和显微红外测试,首次在CCSDHP-UHP变质岩石英脉和东海水晶中发现了含有沥青和烃类的有机包裹体,进一步证实大别-苏鲁超高压变质带曾经历了快速的俯冲与折返过程,俯冲板块沉积物中的有机质未能充分地演化和成熟。俯冲板块在进变质过程中强烈脱水,释放出含烃流体,并被在板块抬升及其伴随的减压重结晶和退变质过程中形成的石英脉和水晶体所俘获。     

厚松散层钻探工艺技术

在厚松散层中进行钻孔施工较常规钻孔存在一些技术难题,按照常规方法达不到钻孔目的或者花费较大的人力和物力。本文通过分析松散层钻孔正常钻进的影响因素,采用正循环钻孔施工技术进行施工,提出钻孔防偏和纠偏措施,最后给出了厚松散层钻孔施工技术措施,对厚松散层钻探技术具有一定的指导意义。     

Late Cretaceous planktonic foraminifera from Kerguelen Plateau (ODP Leg 183): new data to improve the Southern Ocean biozonation

An almost complete Upper Cretaceous sedimentary sequence recently recovered on the Kerguelen Plateau (southern Indian Ocean) during ODP Leg 183 was analysed for planktonic foraminifera in order to refine and integrate the zonal schemes previously proposed for the Southern Ocean area. Detailed biostratigraphic analysis carried out on holes 1135A, 1136A and 1138A (poleward of 50°S palaeolatitude during Late Cretaceous time) has allowed recognition of low and mid–high latitude bioevents, useful for correlation across latitudes, in addition to known Austral bioevents. The low latitude biozonation can be applied to Turonian sediments, because of the occurrence of Helvetoglobotruncana helvetica, which marks the boundary between Whiteinella archaeocretacea and Helvetoglobotruncana helvetica zones. The base of the Whiteinella archeocretacea Zone falls within the uppermost Cenomanian–Turonian black shale level in Hole 1138A. The stratigraphic interval from upper Turonian to uppermost Santonian can be resolved using bioevents recognized in the mid–high latitude sections. They are, in stratigraphic order: the last occurrence of Falsotruncana maslakovae in the Coniacian, the first occurrence of Heterohelix papula at the Coniacian/Santonian boundary, the extinction of the marginotruncanids in the late Santonian, and the first occurrence of Globigerinelloides impensus in the latest (?) Santonian. The remainder of the Late Cretaceous fits rather well in the Austral zonal scheme, except that Globigerinelloides impensus exhibits a stratigraphic range in agreement with its record at the mid–high latitude sections and extends further downwards than previously recorded at southern sites. Therefore, despite the poor recovery in certain intervals and the presence of several hiatuses of local and regional importance as revealed by correlation among holes, a more detailed zonal scheme has been obtained (mainly for the less resolved Turonian–Santonian interval). Remarks on some species often overlooked in literature are also provided.     

大洋钻探与地层学——高分辨率磁性生物年代地层格架

深海钻探计划（ＤＳＤＰ）和大洋钻探计划（ＯＤＰ）实施以来促进了地层学的发展。通过对大洋沉积物的研究，利用生物属，种的始，末现面事件建立起了晚中生代－新生代高精度的钙质超微化石，有孔虫，放射虫以及沟鞭藻的化石带，综合利用这些基准面事件，可使地层划分精度达１０万年以内。使用液压活塞取心技术，建立起了完整，连续的中，新生代磁性地层剖面，加之放射性年龄的测定，确定了数百个生物属，种始，末现面的绝对年龄值，     

大洋钻探与全球变化(二)——从海洋角度研究第四纪古全球变化

海洋在第四纪全球气候和环境的变化中起着至关重要的作用，一方面，海洋沉积记录了大量第四纪古全球变化的信息，特别是可提供古球变化中高分辨率的短期气候事件的记录，另一方面，无论是全球性大洋环流，生物和化学的变化，还是区域性西太平洋边缘海浅水陆架的出没，这些海洋事件都可能是许多第四纪古全球变化现象的原因之所在。因此，从海洋角度研究第四纪古全球变化，已成为当前古全球变化和国际古海洋学研究的重点。在这方面，深