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11.
气相色谱指纹法在海上油污染源鉴别中的应用 总被引:4,自引:0,他引:4
通过一个具体案例,探讨了气相色谱指纹法在海上油污染源鉴别中的应用。该鉴别方法基于样品的正构烷烃气相色谱指纹分析,选择既能表征油种固有特性,又受风化影响较小的正十七烷(n-C17)、正十八烷(n-C18)、姥鲛烷(phy)、植烷(phy)和正二十烷(n-C20)等特征烷烃作为判据,可信度大,而且整个操作流程短(一般不超过半天),较简便易行。 相似文献
12.
The characteristics and sources of natural gases from Ordovician weathered crust reservoirs in the Central Gas Field in the Ordos Basin 总被引:2,自引:2,他引:0
Xianqing Li Guoyi Hu Jian Li Dujie Hou Peng Dong Zhihong Song Yunfeng Yang 《中国地球化学学报》2008,27(2):109-120
The Central Gas Field is a famous large-sized gas field in the Ordos Basin of China. However, identification of main gas sources of the Ordovician reservoirs in this gas field remains puzzling. On the basis of a lot of geochemical data and geological research on natural gases, the characteristics and sources of natural gases from Ordovician weathered crust reservoirs in the Central Gas Field in the Ordos Basin were studied. The results indicated that natural gases from Ordovician weathered crust reservoirs in the Central Gas Field in the Ordos Basin have similar chemical and isotopic compositions to highly mature and over-mature dry gases. Both coal-derived gases and oil-type gases coexist in the Central Gas Field in the Ordos Basin. The former was derived mainly from Carboniferous-Permian coal measures and the latter from Lower Paleozoic marine carbonates. It is suggested that coal-derived gases occur in the eastern part of the Central Gas Field while oil-type gases may be produced mainly in the northern, western and southern parts of the Central Gas Field in the Ordos Basin. 相似文献
13.
14.
鄂尔多斯盆地靖边气田马五_(1+2)气藏储集单元研究 总被引:1,自引:0,他引:1
综合地震、地质、测井等信息,考虑沉积、成岩、地貌、生产动态等多因素,在沟槽识别和致密带研究基础上,通过井间干扰、油层压力变化和试井边界响应分析,按照局部、就近原则对靖边气田马五1+2气藏进行了储集单元划分。共划分出111个储集单元,其中独立型69个,复合型42个。这些储集单元的面积多介于10~50km2之间,单个储集单元的井数一般少于6口。在对气藏储层特征综合认识的基础上,确定流动单元划分思路与流程,并认为关键环节包括古沟槽识别、致密带研究、动静结合确定储集单元等3个方面。储集单元一方面受控于被致密岩相包围的有利成岩相带,宏观上与弱—中等充填泥粉晶白云岩相对应性好;另一方面又受各级古沟槽夹持,在两个一级古沟槽之间往往共生多个储集单元,而这些储集单元边界又严格地受二级或三级沟槽切割控制。 相似文献
15.
塔河油田2区三叠系油藏是西北分公司开发较早的碎屑岩油藏之一,开发层系有上油组、中油组,油柱高度在15~20m,储层为辫状三角洲相辫状三角洲前缘亚相水下分流河道、河口坝、分流间湾微相沉积,非均质性严重。本区上油组砂体厚度40~0m,中油组25~35m,分布较稳定,物性为中孔、中高渗储层,原油属低粘度轻质油。但2区三叠系油藏实钻变化大,见水快、产量递减快、含水上升快、采出程度低,开发效果较差,经过多次调整虽有一定程度改善,仍存在一些问题。本文认为2区三叠系油藏开发效果较差的原因之一是对本区油藏类型的认识上存在问题即2区三叠系油藏是以断裂控制的断块油藏而非背斜油藏,并延伸分析正在投入开发评价的S96-T901井区、TK232-T453井区及T206-T208井区等都为断块(断背斜)油藏。应用断块油藏的观点对塔河地区三叠系油藏勘探开发有重要指导意义。 相似文献
16.
Richard Dallier Jean-Gabriel Cuby Jean Czarny Jacques Baudrand 《Experimental Astronomy》1994,3(1-4):183-184
ISIS IR is the first attempt to use fibre optics for near infrared spectroscopy (1.8m). It is a field spectrograph (2D spectroscopy), and can work at various resolving powers (up to 25000). It can be transported anywhere, and soon it will be used at CFHT with one NICMOS 3-based camera.Département d'Astrophysique Extragalactique et de Cosmologie 相似文献
17.
The petroleum generation potential and effective oil window of humic coals related to coal composition and age 总被引:1,自引:0,他引:1
A worldwide data set of more than 500 humic coals from the major coal-forming geological periods has been used to analyse the evolution in the remaining (Hydrogen Index, HI) and total (Quality Index, QI) generation potentials with increasing thermal maturity and the ‘effective oil window’ (‘oil expulsion window’). All samples describe HI and QI bands that are broad at low maturities and that gradually narrow with increasing maturity. The oil generation potential is completely exhausted at a vitrinite reflectance of 2.0–2.2%Ro or Tmax of 500–510 °C. The initial large variation in the generation potential is related to the original depositional conditions, particularly the degree of marine influence and the formation of hydrogen-enriched vitrinite, as suggested by increased sulphur and hydrogen contents. During initial thermal maturation the HI increases to a maximum value, HImax. Similarly, QI increases to a maximum value, QImax. This increase in HI and QI is related to the formation of an additional generation potential in the coal structure. The decline in QI with further maturation is indicating onset of initial oil expulsion, which precedes efficient expulsion. Liquid petroleum generation from humic coals is thus a complex, three-phase process: (i) onset of petroleum generation, (ii) petroleum build-up in the coal, and (iii) initial oil expulsion followed by efficient oil expulsion (corresponding to the effective oil window). Efficient oil expulsion is indicated by a decline in the Bitumen Index (BI) when plotted against vitrinite reflectance or Tmax. This means that in humic coals the vitrinite reflectance or Tmax values at which onset of petroleum generation occurs cannot be used to establish the start of the effective oil window. The start of the effective oil window occurs within the vitrinite reflectance range 0.85–1.05%Ro or Tmax range 440–455 °C and the oil window extends to 1.5–2.0%Ro or 470–510 °C. For general use, an effective oil window is proposed to occur from 0.85 to 1.7%Ro or from 440 to 490 °C. Specific ranges for HImax and the effective oil window can be defined for Cenozoic, Jurassic, Permian, and Carboniferous coals. Cenozoic coals reach the highest HImax values (220–370 mg HC/g TOC), and for the most oil-prone Cenozoic coals the effective oil window may possibly range from 0.65 to 2.0%Ro or 430 to 510 °C. In contrast, the most oil-prone Jurassic, Permian and Carboniferous coals reach the expulsion threshold at a vitrinite reflectance of 0.85–0.9%Ro or Tmax of 440–445 °C. 相似文献
18.
青藏高原清水河多年冻土区铁路路基沉降变形特征研究 总被引:3,自引:1,他引:3
通过埋设在青藏铁路路基中两个断面内的6条沉降观测管3 a来的地基沉降变形资料,研究了高原多年冻土区铁路路基的沉降变形特征,分析了填筑铁路路基对下伏多年冻土融化变形的影响。研究表明,由于受到填筑路基时赋存在路基填料内的热量的影响,铁路路基下伏多年冻土上限在施工初期会有一个明显的下移沉降,铁路路基也随之有一个较大幅度的工后下沉变动,随着时间的推移,路基下降速率会逐渐下降,但在短时间内不会停止下来,而且由于太阳辐射和路基边坡形状的影响,路基向阳面与背阴面的变形有较大的差别,且在近南北向展布的路基上表现最为明显。 相似文献
19.
辽河盆地冷家油田沙河街组三段储层岩相古地理 总被引:2,自引:0,他引:2
辽河盆地在沙河街组三段早期水体较深,主要形成扇三角洲及盆底扇;沙三晚期水体较浅,发育湖泊砂体.依据沉积相分布规律,沙三早、中、晚3个时期可进一步分别划分出湖泊扩张和收缩阶段.盆地西部凹陷的冷家油田为东陡西缓的箕状洼陷.研究区内沙三段的古地理格局是决定相分布的关键因素,河流和湖泊能量相对强弱决定扇体沉积的规模.受相对湖平面变化的影响,纵向扇三角洲主要形成于湖泊扩张时期,并且有相带窄、过渡快、以粗碎屑沉积为主的特点.扇体沉积中主要发育前缘分流河道充填沉积,但位于河口前缘或侧缘的滩坝及前三角洲中的盆底扇局部也较发育. 相似文献
20.
M. Kern T. Preimesberger M. Allesch R. Pail J. Bouman R. Koop 《Journal of Geodesy》2005,78(9):509-519
The satellite missions CHAMP, GRACE, and GOCE mark the beginning of a new era in gravity field determination and modeling. They provide unique models of the global stationary gravity field and its variation in time. Due to inevitable measurement errors, sophisticated pre-processing steps have to be applied before further use of the satellite measurements. In the framework of the GOCE mission, this includes outlier detection, absolute calibration and validation of the SGG (satellite gravity gradiometry) measurements, and removal of temporal effects. In general, outliers are defined as observations that appear to be inconsistent with the remainder of the data set. One goal is to evaluate the effect of additive, innovative and bulk outliers on the estimates of the spherical harmonic coefficients. It can be shown that even a small number of undetected outliers (<0.2 of all data points) can have an adverse effect on the coefficient estimates. Consequently, concepts for the identification and removal of outliers have to be developed. Novel outlier detection algorithms are derived and statistical methods are presented that may be used for this purpose. The methods aim at high outlier identification rates as well as small failure rates. A combined algorithm, based on wavelets and a statistical method, shows best performance with an identification rate of about 99%. To further reduce the influence of undetected outliers, an outlier detection algorithm is implemented inside the gravity field solver (the Quick-Look Gravity Field Analysis tool was used). This results in spherical harmonic coefficient estimates that are of similar quality to those obtained without outliers in the input data. 相似文献