Recent macroids on the Kikai‐jima shelf,Central Ryukyu Islands,Japan

Sandy and gravelly carbonate sediments found off Kikai‐jima, southern Japan, a coral reef‐related island shelf, represent the northernmost sub‐tropical, carbonate deposits in the Central Ryukyu Islands (Ryukyus). On the Kikai‐jima shelf, at water depths of 61 to 105 m, these sediments are characterized by macroid pavements. Since the abundance of very small and of exceptionally large macroids may indicate specific hydrodynamic controls regarding constraints on growth and taphonomy, the detailed analysis of recent and fossil macroid pavements is meaningful ecologically and environmentally. Macroids, ranging in size from ca 25 to 130 mm in diameter, are spheroidal and sub‐spheroidal in shape and consist mainly of the encrusting foraminifer Acervulina inhaerens and subordinate thin encrusting and lumpy coralline algae. Accessory components include bryozoans, serpulids and, to a lesser extent, encrusting arborescent foraminifera (Homotrema and Miniacina). Low sedimentation rates and occasional movement due to current action are indicated by sizes, shapes and growth‐forms of the studied macroids, the Entobia–Gastrochaenolites–Trypanites–Maeandropolydora ichnocoenosis and the ‘Bioerosion Index’ for coated grains (introduced herein). The deep‐water tidally induced current energy was sufficient to maintain multi‐directional growth (spheroidal shapes) of the larger macroids and to initiate macroid growth using the diverse biogenic remnants as nuclei. The asymmetrical inner arrangement suggests possible periods of stability for the macroids. The residence time of the coated grain in its original environment determines the size and morphology of the macroid and the selection of coating organisms. The composition of the coating community is mainly a consequence of component growth rates in relation to turnover time and residence time. Long‐term studies are needed to assess the spatial and temporal resolution of present‐day encrusting communities across biogeographic provinces and shelf to slope regions.     

U/Pb dating of detrital zircons from late Palaeozoic deposits of Bel’kovsky Island (New Siberian Islands): critical testing of Arctic tectonic models

Detrital zircon U/Pb ages provide new insights into the provenance of Upper Devonian–Permian clastic rocks of Bel’kovsky Island, within the New Siberian Islands archipelago. Based on these new data, we demonstrate that Upper Devonian–Carboniferous turbidites of Bel’kovsky Island were derived from Grenvillian, Sveconorwegian, and Timanian sources similar to those that fed Devonian–Carboniferous deposits of the Severnaya Zemlya archipelago and Wrangel Island and were probably located within Laurentia–Baltica. Detrital zircon ages from the lower Permian deposits of Bel’kovsky Island suggest a drastic change in provenance and show a strong affinity with the Uralian Orogen. Two possible models to interpret this shift in provenance are proposed. The first involves movement of these continental blocks from the continental margin of Laurentia–Baltica towards the Uralian Orogen during the late Carboniferous to Permian, while the second argues for long sediment transport across the Barents shelf.     

Probabilistic risk assessment of common booster biocides in surface waters of the harbours of Gran Canaria (Spain)

The presence of booster biocides in the aquatic environment has been associated with a risk to non-target species due to their proven toxicity. The aim of the present study was to determine the spatial and temporal distribution of common booster biocides in different harbours of the island of Gran Canaria (Spain) and evaluate, by means of a probabilistic risk assessment (PRA), the ecological risk posed by these compounds. With these objectives, a monitoring campaign was conducted between January 2008 and May 2009, collecting a total of 182 seawater samples. Four common booster biocides (TCMTB, diuron, Irgarol 1051 and dichlofluanid) were monitored. Diuron levels ranged between 2.3 and 203 ng/L and Irgarol 1051 between 2.4 and 146.5 ng/L. The ecological risk associated with these levels was always low, however, with probabilities of exceeding the 10th percentile of autotroph toxicity below 3.5%.     

Contemporary 14C radiocarbon levels of oxygenated polybrominated diphenyl ethers (O-PBDEs) isolated in sponge-cyanobacteria associations

Considerable debate surrounds the sources of oxygenated polybrominated diphenyl ethers (O-PBDEs) in wildlife as to whether they are naturally produced or result from anthropogenic industrial activities. Natural radiocarbon (¹⁴C) abundance has proven to be a powerful tool to address this problem as recently biosynthesized compounds contain contemporary (i.e. modern) amounts of atmospheric radiocarbon; whereas industrial chemicals, mostly produced from fossil fuels, contain no detectable ¹⁴C. However, few compounds isolated from organisms have been analyzed for their radiocarbon content. To provide a baseline, we analyzed the ¹⁴C content of four O-PBDEs. These compounds, 6-OH-BDE47, 2′-OH-BDE68, 2′,6-diOH-BDE159, and a recently identified compound, 2′-MeO-6-OH-BDE120, were isolated from the tropical marine sponges Dysidea granulosa and Lendenfeldia dendyi. The modern radiocarbon content of their chemical structures (i.e. diphenyl ethers, C₁₂H₂₂O) indicates that they are naturally produced. This adds to a growing baseline on, at least, the sources of these unusual compounds.     

Cenozoic temperate and sub‐tropical carbonate sedimentation on an oceanic volcano – Chatham Islands,New Zealand

The Chatham Islands, at the eastern end of the Chatham Rise in the South‐west Pacific, are the emergent part of a Late Cretaceous to Cenozoic stratovolcano complex that is variably covered with limestones and fossiliferous tuffs. Most of these deposits accumulated in relatively shallow, high‐energy, tide‐influenced palaeoenvironments with deposition punctuated by periods of deeper‐water pelagic accumulation. Carbonate components in these neritic deposits are biogenic and dominated by molluscs and bryozoans – a heterozoan assemblage. The widespread Middle to Late Eocene Matanginui Limestone contains local photozoan elements such as large benthonic foraminifera (especially Asterocyclina) and calcareous green algae, reflecting the general Palaeogene sub‐tropical oceanographic setting. More localized Late Eocene to Oligocene deposits (Te One Limestone) as well as Pliocene carbonates (Onoua Limestone) are, however, wholly heterozoan and confirm a generally cooler‐water oceanographic setting, similar to today. Early sea floor diagenesis is interpreted to have removed most aragonite components (infaunal bivalves and epifaunal gastropods). Lack of aragonite resulted in the absence of intergranular calcite cementation during subaerial exposure, such that most carbonates are friable or unlithified. Cementation is, however, present at nodular hardground–firmground caps to metre‐scale cycles. Such cements are microcrystalline or micrometre‐thick isopachous circumgranular rinds with insufficient definitive attributes to pinpoint their environment of formation. The overall palaeoenvironment of deposition is interpreted as mesotrophic, resulting in part from upwelling about the Chatham volcanic massif and in part from nutrient element delivery from the adjacent volcanic terrane and coeval volcanism. Biotic diversity in tuffs is two to three times that in limestones, supporting the notion of especially high nutrient availability during periods of volcanism. These mid‐latitude deposits are strikingly different from their low‐latitude, tropical, photozoan counterparts in the volcanic island–coral reef ecosystem. Ground water seepage and fluvial runoff attenuate coral growth and promote microbial carbonate precipitation in these warm‐water settings. In contrast, nutrients from the same sources feed the system in the Chatham Islands cool‐water setting, promoting active heterozoan carbonate sedimentation.     

珠江口盆地东沙隆起的沉降史及其动力机制

根据东沙隆起及其周围钻井资料的一维构造沉降对比分析,结合前人在基底、盖层及断裂等方面的研究,将东沙隆起地区的构造演化分为5个阶段:自垩纪挤压阶段、古新世-早渐新世伸展断陷阶段、早渐新世末期抬升剥蚀阶段、晚渐新世-中新世快速的裂后沉降阶段、晚中新世以来断块升降阶段.认为下地壳高速层是促使早渐新世末期抬升剥蚀的重要因素,而...     

Choppy waters ahead in “a sea of peace cooperation and friendship”?: Slow progress towards the application of maritime joint development to the East China Sea

China and Japan’s June 2008 agreement in principle on maritime cooperation in the East China Sea raised hopes of a significant breakthrough in the parties' complex and long-standing disputes in the area. Subsequent progress towards the realisation of a legally binding, formal treaty on, for example, offshore petroleum joint development has been slow to materialise. In fact, the area under dispute appears to have become more rather than less extensive. This paper examines competing maritime and sovereignty claims in the East China Sea together with progress towards maritime cooperation in the context of overlapping jurisdictional claims. The paper identifies some of the key challenges that need to be overcome in realizing a functioning joint resource management regime in the East China Sea.     

南极南设得兰群岛中-新生代火山作用与地质环境

本文对采自南设得兰群岛的乔治王岛、纳尔逊岛、利文斯顿岛、欺骗岛和南极半岛的火山岩和火山灰进行了岩石化学和Sr、Nd同位素分析，Ar-Ar和K－Ar年龄测定。研究表明，南设得兰群岛火山岩属于玄武岩－安山岩－英安岩岩石组合，安们的Sr、Nd同位素比值非常接近，^87Sr/^86Sr比值普遍比较低，为0．703297－0．703507；^143Nd/^144Nd比值普遍比较高，为0．512835－0．513779，二者呈负相关，εNd-^87Sr/^86Sr相关图显示岩浆来源于亏损地幔。火山岩形成时代集中于96Ma、91Ma、78Ma、60Ma和35Ma等时段。35Ma之后，火山活动长时间消沉，直到晚中新世和第四纪才时有发生；这一漫长的历史时期，正是南极大陆冰盖逐渐形成之时。是气候变冷抑制了火山活动？还是火山活动的减弱和停止导致气候变冷？尚待进一步研究；但冷期火山活动减弱或停止，暧期火山活动活跃和增强，这一对应关系是存在的。火山作用的时空分布及岩石地球化学特征暗示，南设得兰群岛处于一个岛弧的地质环境，早期群岛基本上与南极半岛连在一起，在德雷克板块的俯冲下，群岛逐渐与半岛分离，形成布兰斯菲尔德海峡（裂谷），在弧后扩张和裂谷作用下产生新的火山活动。     

The application of lead isotope ratios in the Antarctic macroalga Iridaea cordata as a contaminant monitoring tool

Lead (Pb) isotope ratios were measured in the marine macroalga Iridaea cordata collected from four locations in the Windmill Islands, East Antarctica. Based on the masses of thalli collected, samples analysed in this study were likely to be a mixture of one and two year old thalli. For a sample of thalli of various ages (<12 months to 2 years old) from the same site there was no apparent variation in Pb concentration or Pb isotope ratio with thallus mass/age, indicating that contaminant sources had been constant over the lifetime of the thalli sampled. I.cordata samples close to the Thala Valley waste disposal site (Brown Bay Inner) near the Australian Station, Casey, displayed isotopic signatures (²⁰⁸Pb/²⁰⁴Pb 35.99; ²⁰⁶Pb/²⁰⁷Pb 1.066; n = 3; average values shown) trending towards that possessed by major Australian Pb sources (Broken Hill and Mt Isa, ²⁰⁸Pb/²⁰⁴Pb 35.60; ²⁰⁶Pb/²⁰⁷Pb 1.041) suggesting that these samples had been exposed to anthropogenic Pb originating from the Thala Valley waste disposal site. Material collected hundreds of metres from the tip location at Brown Bay Outer had isotopic values (²⁰⁸Pb/²⁰⁴Pb 36.32; ²⁰⁶Pb/²⁰⁷Pb 1.088; n = 10) intermediate between Brown Bay Inner and sites further from the contaminant source at Sparkes Bay and Wilkes (²⁰⁸Pb/²⁰⁴Pb 36.46; ²⁰⁶Pb/²⁰⁷Pb 1.094; n = 4) showing that contaminant transport was predominantly restricted to Brown Bay Inner. This study demonstrates that the isotope ratios of Pb in marine macroalgae can provide valuable information as to the origin and extent of heavy metal flux in a marine environment.     

Coeval strombolian and vulcanian-type explosive eruptions at Panarea (Aeolian Islands,Southern Italy)

In this paper, we document the evolution of the emergent Panarea dome in the Aeolian islands (Southern Italy), placing particular emphasis on the reconstruction of the explosive events that occurred during the final stage of its evolution. Two main pyroclastic successions exposing fall deposits with different compositions have been studied into detail: the andesitic Palisi succession and the basaltic Punta Falcone succession. The close-in-time deposition of the two successions, the dispersal area and grain-size distribution of the deposits account for their attribution to vents located in the western sector of the present island and erupting almost contemporaneously. Vents could have been aligned along NNE-trending regional fracture systems controlling the western flank of the dome and possibly its collapse. Laboratory analyses have been devoted to the characterization of the products of the two successions that have been ascribed to vulcanian- and to strombolian-type eruptions respectively. The vulcanian eruption started with a vent-clearing phase that occurred by sudden decompression of a pressurized magma producing ballistic bombs and a surge blast and the development of a vulcanian plume. Vulcanian activity was almost contemporaneous to strombolian-type fall-out eruptions. The coeval occurrence of basaltic and andesitic eruptions from close vents and the presence of magmatic basaltic enclaves in the final dacitic lava lobe of the dome allow us to speculate that the intrusion of a basaltic dyke played a major role in triggering explosive eruptions. The final explosive episodes may have been caused by extensional tectonics fracturing the roof of a zoned shallow magma chamber or by the intrusion of a new basaltic magma into a more acidic and shallow reservoir. Intrusion most likely occurred through the injection of dykes along the western cliff of the present Panarea Island inducing the collapse of the western sector of the dome.